1,1'-biphenyl

C12H10

CAS92-52-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
92-52-4
EC Number
202-163-5
UN Number
3077
Index Number
601-042-00-8
PubChem CID
7095

Physical-chemical properties

Molecular Formula
C12H10
Molar Mass
154.21 g/mol
IUPAC Name
1,1'-biphenyl

Chemical Identifiers

InChI
InChI=1S/C12H10/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H
InChI Key
ZUOUZKKEUPVFJK-UHFFFAOYSA-N

Overview

1,1'-biphenyl (CAS 92-52-4) is an aromatic hydrocarbon compound consisting of two benzene rings connected by a single carbon-carbon bond, widely used as an industrial intermediate and heat transfer medium. This organic compound, with the molecular formula C12H10 and a molecular weight of 154.21 g/mol, represents a fundamental structure in aromatic chemistry. Biphenyl appears as colorless to pale yellow crystals or flakes with a characteristic pleasant odor, exhibiting excellent thermal stability and chemical resistance properties that make it valuable across multiple industrial applications. From a safety perspective, 1,1'-biphenyl requires careful handling due to its classification under several hazard categories. The compound carries a Warning signal word and is associated with GHS07 and GHS09 pictograms, indicating potential health and environmental concerns. It is classified as a skin and eye irritant (Skin Irrit. 2; Eye Irrit. 2), can cause specific target organ toxicity following single exposure (STOT SE 3), and poses significant risks to aquatic environments with both acute and chronic toxicity classifications (Aquatic Acute 1; Aquatic Chronic 1). Under ADR transportation regulations, it falls under Class 9 as a miscellaneous dangerous substance. Industrial applications of biphenyl leverage its thermal stability and chemical properties. It serves as an important intermediate in the synthesis of various chemicals and pharmaceuticals, functions as a heat transfer fluid in high-temperature applications, and acts as a fungicide in certain formulations. The compound shares some structural similarities with other industrial chemicals, though it differs significantly from specialized compounds like 6-methylheptyl prop-2-enoate or complex metal coordination compounds such as tris(N,N-dimethylcarbamodithioate);iron(3+). OYSI provides high-quality 1,1'-biphenyl to meet diverse industrial requirements across European markets.

Safety & Classification

Warning
Classification:

STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameDiphenyl, fest
Marine PollutantNo

Frequently Asked Questions

What is 1,1'-biphenyl?

1,1'-biphenyl is an organic aromatic hydrocarbon consisting of two benzene rings connected by a single bond. With the molecular formula C12H10 and CAS number 92-52-4, this compound has a molecular weight of 154.21 g/mol. It appears as white to pale yellow crystalline flakes or powder with a distinctive pleasant, aromatic odor. Biphenyl is classified as a polycyclic aromatic hydrocarbon and serves as an important industrial chemical intermediate.

What are the physico-chemical properties of 1,1'-biphenyl?

1,1'-biphenyl is a solid at room temperature, appearing as white to pale yellow crystalline flakes with a characteristic aromatic odor. It has a melting point of approximately 69-70°C and a boiling point of 255°C. The compound is practically insoluble in water but readily soluble in organic solvents such as alcohol, ether, and benzene. It has a density of about 1.04 g/cm³ and exhibits good thermal stability under normal conditions.

What is 1,1'-biphenyl used for?

1,1'-biphenyl is primarily used as a heat transfer medium in industrial applications, particularly in closed-loop heating systems. It serves as an important intermediate in the synthesis of pharmaceuticals, agrochemicals, and dyes. The compound is also utilized in the production of polychlorinated biphenyls (PCBs) substitutes, optical brighteners, and as a fungicide for citrus fruits. Additionally, it finds application in the manufacture of plastics and as a solvent in various chemical processes.

How to handle 1,1'-biphenyl safely?

1,1'-biphenyl should be handled with appropriate personal protective equipment including safety goggles, gloves, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use local exhaust ventilation to avoid inhalation of vapors or dust. The compound can cause skin and eye irritation and may affect the central nervous system. Always wash hands thoroughly after handling and avoid eating, drinking, or smoking in work areas where the substance is present.

How to store 1,1'-biphenyl correctly?

1,1'-biphenyl should be stored in tightly closed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers sealed when not in use to prevent contamination and vapor release. Store away from incompatible materials such as strong oxidizing agents. The storage area should be equipped with appropriate spill containment measures and maintained at temperatures below 30°C to ensure product stability and prevent sublimation.

What to do in case of contact with 1,1'-biphenyl?

In case of skin contact with 1,1'-biphenyl, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and keep them at rest. If ingested, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms persist.

How to dispose of 1,1'-biphenyl appropriately?

1,1'-biphenyl must be disposed of in accordance with local, national, and international environmental regulations. The substance is classified as hazardous to the aquatic environment, so it cannot be discharged into waterways or sewage systems. Disposal should be carried out through licensed waste management companies capable of handling hazardous chemical waste. Incineration at authorized facilities under controlled conditions is typically the preferred disposal method. Always consult local environmental authorities for specific requirements.

How to transport 1,1'-biphenyl?

1,1'-biphenyl is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. It must be packaged in appropriate UN-specification containers and labeled with the corresponding hazard labels. Transport documents must include the proper shipping name, UN number, and hazard class. Vehicles transporting this substance should carry appropriate emergency equipment and drivers must be trained in hazardous materials handling. Ensure compliance with all applicable transport regulations.

Is 1,1'-biphenyl subject to specific regulations?

1,1'-biphenyl is subject to various regulatory frameworks including REACH registration in the European Union, where it must be registered for manufacture or import above certain tonnage thresholds. The substance is classified under CLP regulation with harmonized classification including skin irritation, eye irritation, and aquatic toxicity. While not currently listed as an SVHC, it requires safety data sheets and appropriate hazard communication. Specific use restrictions may apply depending on the application and jurisdiction.

Where to buy 1,1'-biphenyl in Europe?

1,1'-biphenyl is available through OYSI, a leading European distributor of specialty chemicals and industrial raw materials. OYSI provides high-quality 1,1'-biphenyl with full regulatory compliance including safety data sheets and REACH registration support. As a trusted chemical supplier across Europe, OYSI ensures reliable supply chain management and technical support for industrial customers. Contact OYSI directly for product specifications, availability, and pricing information tailored to your specific requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.