Tris(N,N-dimethylcarbamodithioate);iron(3+)

C9H18FeN3S6

tris(N,N-dimethylcarbamodithioate);iron(3+)

CAS14484-64-1
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
14484-64-1
EC Number
238-484-2
UN Number
2757
Index Number
006-051-00-5
PubChem CID
26710

Physical-chemical properties

Molecular Formula
C9H18FeN3S6
Molar Mass
416.50 g/mol
IUPAC Name
tris(N,N-dimethylcarbamodithioate);iron(3+)

Chemical Identifiers

InChI
InChI=1S/3C3H7NS2.Fe/c3*1-4(2)3(5)6;/h3*1-2H3,(H,5,6);/q;;;+3/p-3
InChI Key
WHDGWKAJBYRJJL-UHFFFAOYSA-K

Overview

Tris(N,N-dimethylcarbamodithioate);iron(3+) (CAS 14484-64-1) is an organometallic iron complex with dithiocarbamate ligands used primarily as an industrial catalyst and chemical intermediate. This iron(III) coordination compound features three N,N-dimethylcarbamodithioate ligands coordinated to a central iron atom, resulting in a molecular formula of C9H18FeN3S6 and molecular weight of 416.5 g/mol. The compound belongs to the dithiocarbamate metal complex family, which are characterized by their sulfur-nitrogen chelating properties and diverse industrial applications. Also known by its EC number 238-484-2, this organometallic substance exhibits typical properties of transition metal complexes while incorporating the unique reactivity of dithiocarbamate functional groups. From a safety perspective, tris(N,N-dimethylcarbamodithioate);iron(3+) is classified with several hazard categories requiring careful handling. The compound presents moderate health risks including skin and eye irritation (Skin Irrit. 2, Eye Irrit. 2) and specific target organ toxicity following single exposure (STOT SE 3). Environmental considerations are significant, as the substance poses acute and chronic aquatic toxicity (Aquatic Acute 1, Aquatic Chronic 1), necessitating proper containment and disposal protocols. The compound carries GHS07 and GHS09 pictograms with a "Warning" signal word, and is classified under ADR class 6.1 for transportation purposes. Industrial applications typically include catalytic processes in organic synthesis, rubber vulcanization acceleration, and specialized chemical manufacturing. The compound's iron center and dithiocarbamate ligands make it valuable in processes requiring controlled metal-catalyzed reactions, similar to applications found with other organometallic compounds like certain biphenyl derivatives in specialized chemical transformations. OYSI maintains reliable supply chains for tris(N,N-dimethylcarbamodithioate);iron(3+) to support European industrial customers requiring this specialized organometallic compound.

Safety & Classification

Warning
Classification:

STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2757
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameFerbam (ISO)
Marine PollutantNo

Frequently Asked Questions

What is tris(N,N-dimethylcarbamodithioate);iron(3+)?

Tris(N,N-dimethylcarbamodithioate);iron(3+) is an organometallic iron compound with the molecular formula C9H18FeN3S6 and CAS number 14484-64-1. This chemical substance has a molecular weight of 416.5 g/mol and contains iron in its +3 oxidation state coordinated with three dimethylcarbamodithioate ligands. It is classified as a hazardous substance requiring proper handling and safety precautions due to its potential health and environmental effects.

What are the physicochemical properties of tris(N,N-dimethylcarbamodithioate);iron(3+)?

Tris(N,N-dimethylcarbamodithioate);iron(3+) is a solid organometallic compound at room temperature with a molecular weight of 416.5 g/mol. The substance contains iron coordinated with sulfur-containing organic ligands, giving it characteristic properties typical of iron-sulfur complexes. Its exact physical appearance, solubility, and other specific physicochemical parameters should be confirmed through technical data sheets as these can vary depending on the specific preparation method and purity grade.

What is tris(N,N-dimethylcarbamodithioate);iron(3+) used for?

Tris(N,N-dimethylcarbamodithioate);iron(3+) is primarily used as a catalyst in various chemical processes and industrial applications. Its iron-sulfur coordination structure makes it valuable in organometallic chemistry and catalytic reactions. The compound may also find applications in research settings for studying iron coordination complexes and their reactivity. Specific industrial uses include specialized chemical synthesis processes where iron-based catalysts with particular coordination environments are required.

How to handle tris(N,N-dimethylcarbamodithioate);iron(3+) safely?

Tris(N,N-dimethylcarbamodithioate);iron(3+) requires careful handling due to its classification as skin and eye irritant (STOT SE 3, Skin Irrit. 2, Eye Irrit. 2). Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods. Avoid direct skin and eye contact, and prevent inhalation of dust or vapors. Always wash hands thoroughly after handling and follow established laboratory safety protocols.

How to store tris(N,N-dimethylcarbamodithioate);iron(3+) correctly?

Tris(N,N-dimethylcarbamodithioate);iron(3+) should be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly closed and protected from moisture and direct sunlight. Due to its aquatic toxicity classification, ensure storage areas have appropriate containment measures to prevent environmental release. Store away from oxidizing agents and acids. Maintain proper inventory records and ensure storage areas meet local regulatory requirements for hazardous chemical storage.

What to do in case of contact with tris(N,N-dimethylcarbamodithioate);iron(3+)?

Immediate first aid measures for tris(N,N-dimethylcarbamodithioate);iron(3+) exposure include: For skin contact, immediately wash with plenty of soap and water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. If ingested, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms persist or worsen.

How to dispose of tris(N,N-dimethylcarbamodithioate);iron(3+) appropriately?

Tris(N,N-dimethylcarbamodithioate);iron(3+) must be disposed of as hazardous waste according to local and national regulations. Due to its aquatic toxicity classification (Aquatic Acute 1, Aquatic Chronic 1), it cannot be disposed of in regular waste streams or discharged to water systems. Contact licensed hazardous waste disposal companies for proper collection and treatment. Ensure waste containers are properly labeled and documented according to regulatory requirements. Never attempt to neutralize or treat the waste without proper expertise and authorization.

How to transport tris(N,N-dimethylcarbamodithioate);iron(3+)?

Tris(N,N-dimethylcarbamodithioate);iron(3+) is classified under ADR Class 6.1 (Toxic substances), Packing Group II, indicating moderate toxicity requiring specific transport precautions. Shipments must use appropriate UN-specification packaging and proper hazardous goods documentation. Transport vehicles require appropriate placarding and emergency response information. Only trained personnel should handle the transportation, and carriers must comply with ADR regulations for toxic substances. Ensure proper labeling with GHS07 and GHS09 pictograms during transport.

Is tris(N,N-dimethylcarbamodithioate);iron(3+) subject to specific regulations?

Tris(N,N-dimethylcarbamodithioate);iron(3+) is subject to various European chemical regulations including REACH registration requirements and CLP classification rules. It carries the signal word 'Warning' with specific hazard classifications for health and environmental effects. While not currently listed as a SVHC (Substance of Very High Concern), it must comply with standard chemical safety regulations. Users must maintain safety data sheets, implement appropriate risk management measures, and ensure compliance with occupational exposure limits and environmental protection requirements.

Where to buy tris(N,N-dimethylcarbamodithioate);iron(3+) in Europe?

Tris(N,N-dimethylcarbamodithioate);iron(3+) is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this organometallic compound to industrial customers, research institutions, and chemical manufacturers across Europe. As an established chemical distributor, OYSI ensures proper handling, documentation, and compliance with European chemical regulations. Contact OYSI directly for availability, technical specifications, and pricing information for tris(N,N-dimethylcarbamodithioate);iron(3+) to meet your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.