1,4-dichlorobenzene
C6H4Cl2
Consulting for 1,4-dichlorobenzene
Our experts support you with application, dosage, and compliance.
Identification
- CAS Number
- 106-46-7
- EC Number
- 203-400-5
- UN Number
- 3077
- Index Number
- 602-035-00-2
- PubChem CID
- 4685
Physical-chemical properties
- Molecular Formula
- C6H4Cl2
- Molar Mass
- 147.00 g/mol
- IUPAC Name
- 1,4-dichlorobenzene
Chemical Identifiers
- InChI
- InChI=1S/C6H4Cl2/c7-5-1-2-6(8)4-3-5/h1-4H
- InChI Key
- OCJBOOLMMGQPQU-UHFFFAOYSA-N
Overview
1,4-dichlorobenzene (CAS 106-46-7) is an aromatic organochlorine compound with strong chemical stability and distinctive odor properties. This chlorinated benzene derivative, also known as para-dichlorobenzene, represents one of the most commercially significant isomers in the dichlorobenzene family. With its molecular formula C6H4Cl2 and molecular weight of 147 g/mol, this crystalline solid exhibits excellent thermal stability and low water solubility, making it valuable across multiple industrial applications. The compound's symmetrical structure, where two chlorine atoms occupy opposite positions on the benzene ring, contributes to its unique physical and chemical characteristics. From a safety perspective, 1,4-dichlorobenzene requires careful handling due to its classification as a potential carcinogen (Carc. 2) and eye irritant (Eye Irrit. 2). The substance also presents significant environmental concerns, classified as acutely and chronically toxic to aquatic life (Aquatic Acute 1; Aquatic Chronic 1). These hazard classifications necessitate appropriate personal protective equipment and environmental containment measures during handling and storage. Industrial applications primarily include its use as a chemical intermediate in polymer production, particularly in the manufacture of polyphenylene sulfide resins and engineering plastics. The compound also serves as a precursor for agricultural chemicals and specialty chemicals synthesis. While structurally different from complex molecules like 1-(4-chlorophenyl)-4,4-dimethyl-3-(1,2,4-triazol-1-ylmethyl)pentan-3-ol, both compounds demonstrate the versatility of chlorinated aromatics in industrial chemistry. Transportation regulations classify 1,4-dichlorobenzene under ADR Class 9, reflecting its miscellaneous dangerous goods status. OYSI maintains reliable supply chains for this essential industrial chemical, ensuring consistent availability for European customers requiring high-purity dichlorobenzene for their manufacturing processes.
Safety & Classification
Carc. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | 1,4-Dichlorbenzen, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,4-dichlorobenzene?
1,4-dichlorobenzene is an aromatic organochlorine compound with the molecular formula C6H4Cl2 and CAS number 106-46-7. It consists of a benzene ring with two chlorine atoms positioned at opposite ends (para-position). This white crystalline solid has a distinctive sweet odor and a molecular weight of 147 g/mol. It is classified as a Category 2 carcinogen and poses risks to aquatic environments.
What are the physicochemical properties of 1,4-dichlorobenzene?
1,4-dichlorobenzene is a white crystalline solid at room temperature with a characteristic sweet, mothball-like odor. It has a melting point of 53°C and boiling point of 174°C. The compound is poorly soluble in water but readily dissolves in organic solvents such as alcohol, ether, and benzene. It has a density of 1.458 g/cm³ and exhibits volatility at ambient temperatures.
What is 1,4-dichlorobenzene used for?
1,4-dichlorobenzene is primarily used as a chemical intermediate in the production of polyphenylene sulfide resins and other specialty polymers. It serves as a precursor for pharmaceuticals, agrochemicals, and dyes. The compound is also utilized as a fumigant and moth repellent, though these applications are increasingly restricted due to health concerns. Industrial applications include its use as a process solvent and deodorizer.
How to handle 1,4-dichlorobenzene safely?
1,4-dichlorobenzene requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when ventilation is inadequate. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Avoid skin and eye contact, and prevent ingestion. Use non-sparking tools and ensure proper grounding to prevent static electricity buildup during handling operations.
How to store 1,4-dichlorobenzene correctly?
1,4-dichlorobenzene should be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Keep containers tightly sealed to prevent vapor release and contamination. Store away from strong oxidizing agents, acids, and bases. Maintain storage temperatures below 25°C and ensure adequate separation from incompatible materials. Use appropriate containment measures to prevent environmental release.
What to do in case of contact with 1,4-dichlorobenzene?
In case of skin contact with 1,4-dichlorobenzene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes while keeping eyelids open. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention, providing the safety data sheet to medical personnel.
How to dispose of 1,4-dichlorobenzene properly?
1,4-dichlorobenzene must be disposed of as hazardous waste through licensed waste management companies in accordance with local, national, and EU regulations. The substance cannot be disposed of in regular waste streams or sewage systems due to its environmental hazard classification. Incineration at authorized high-temperature facilities is typically the preferred disposal method. Always consult local environmental authorities for specific disposal requirements and approved disposal facilities.
How to transport 1,4-dichlorobenzene?
1,4-dichlorobenzene is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. It requires proper packaging in UN-approved containers with appropriate labeling including the Class 9 hazard label. Transport vehicles must carry proper documentation and emergency response information. Drivers require ADR training for Class 9 substances, and specific routing and parking restrictions may apply depending on local regulations.
Is 1,4-dichlorobenzene subject to specific regulations?
1,4-dichlorobenzene is subject to comprehensive EU regulations including REACH registration requirements and CLP classification as Carcinogenic Category 2, Eye Irritant 2, and Aquatic hazard. It may be subject to restrictions under REACH Annex XVII depending on intended use. The substance requires safety data sheets and appropriate hazard communication. Users must comply with occupational exposure limits and environmental discharge restrictions established by member states.
Where to buy 1,4-dichlorobenzene in Europe?
1,4-dichlorobenzene is available through OYSI, a European distributor of specialty chemicals serving industrial customers across Europe. OYSI provides technical-grade 1,4-dichlorobenzene with full regulatory compliance including REACH registration, safety data sheets, and proper packaging. As an established chemical distributor, OYSI ensures reliable supply chains and technical support for industrial applications requiring this specialized aromatic compound.
Services for 1,4-dichlorobenzene
Order 1,4-dichlorobenzene
Fast delivery across Europe
SDS Service
Request Safety Data Sheet for 1,4-dichlorobenzene
Technical Consulting
Application advice for 1,4-dichlorobenzene
REACH Safety Data Sheet
REACH Compliance Service
Digital Product Passport
EU-compliant product documentation
ADR Consulting for 1,4-dichlorobenzene
1,4-dichlorobenzene is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.