Aluminum phosphorus(3-)
AlP
aluminum phosphorus(3-)
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Identification
- CAS Number
- 20859-73-8
- EC Number
- 244-088-0
- UN Number
- 1397
- Index Number
- 015-004-00-8
- PubChem CID
- 16126812
Physical-chemical properties
- Molecular Formula
- AlP
- Molar Mass
- 57.96 g/mol
- IUPAC Name
- aluminum phosphorus(3-)
Chemical Identifiers
- InChI
- InChI=1S/Al.P/q+3;-3
- InChI Key
- PGCGUUGEUBFBPP-UHFFFAOYSA-N
Overview
Aluminum phosphorus(3-) (CAS 20859-73-8) is an inorganic binary compound with highly reactive properties and significant toxicity hazards. This crystalline compound, with the molecular formula AlP and a molecular weight of 57.9553 g/mol, represents one of the most hazardous phosphide compounds used in industrial applications. Aluminum phosphorus(3-) exhibits extreme reactivity with water and moisture, generating highly toxic phosphine gas upon contact. This water-reactive characteristic, combined with its acute toxicity profile, classifies it under multiple GHS hazard categories including Water-react. 1, Acute Tox. 1, 2, and 3, requiring stringent safety protocols during handling and storage. The compound belongs to the metal phosphide family, sharing structural similarities with other reactive phosphides such as trimagnesium bis(phosphorus(3-)) and tricalcium bis(phosphorus(3-)), though aluminum phosphorus(3-) demonstrates particularly intense reactivity patterns. Its ADR classification as Class 4.3 (substances which, in contact with water, emit flammable gases) underscores the critical safety considerations required for transportation and storage. Primary industrial applications include its use as a fumigant in agricultural pest control, particularly for grain storage facilities, where its phosphine-generating properties provide effective rodenticide and insecticide action. The compound also serves specialized roles in semiconductor manufacturing processes and as a reducing agent in specific metallurgical applications. Additionally, it functions in certain chemical synthesis reactions where controlled phosphine generation is required. The compound's dangerous nature demands specialized handling expertise, appropriate containment systems, and comprehensive safety protocols. OYSI maintains technical-grade aluminum phosphorus(3-) availability for qualified industrial customers with appropriate safety infrastructure and regulatory compliance capabilities.
Safety & Classification
Water-react. 1; Acute Tox. 1; Acute Tox. 3; Acute Tox. 2; Aquatic Acute 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1397 |
| ADR Class | 4.3 |
| Packing Group | I |
| Tunnel Code | E |
| Proper Shipping Name | Aluminiumphosphid |
| Marine Pollutant | No |
Frequently Asked Questions
What is aluminum phosphorus(3-)?
Aluminum phosphorus(3-) is an inorganic compound with the chemical formula AlP and CAS number 20859-73-8. This binary compound consists of aluminum and phosphorus atoms in a 1:1 ratio, with a molecular weight of 57.9553 g/mol. It is classified as an extremely hazardous substance due to its water-reactive properties and high toxicity levels, requiring specialized handling and storage procedures in industrial applications.
What are the physicochemical properties of aluminum phosphorus(3-)?
Aluminum phosphorus(3-) is a solid crystalline compound that exhibits extreme reactivity with water, releasing toxic phosphine gas upon contact. The compound is classified as Water-react. 1, indicating its vigorous reaction with moisture. Its molecular structure consists of aluminum and phosphorus atoms arranged in a zinc blende crystal lattice. The compound's high reactivity makes it incompatible with water, acids, and oxidizing agents.
What is aluminum phosphorus(3-) used for?
Aluminum phosphorus(3-) is primarily used as a fumigant in agricultural applications for pest control in stored grains and commodities. The compound releases phosphine gas when it reacts with moisture, which acts as a powerful insecticide and rodenticide. It is also utilized in semiconductor manufacturing processes and as a precursor for other phosphorus-containing compounds in specialized industrial applications requiring controlled phosphine generation.
How to handle aluminum phosphorus(3-) safely?
Aluminum phosphorus(3-) requires extreme safety precautions including full respiratory protection, chemical-resistant gloves, and protective clothing. Work must be conducted in well-ventilated areas or under fume hoods due to toxic gas generation. Personnel should be trained in emergency procedures and have access to emergency eyewash and shower facilities. The compound must be kept strictly away from water, moisture, and incompatible materials during handling operations.
How to store aluminum phosphorus(3-) correctly?
Aluminum phosphorus(3-) must be stored in a cool, dry environment completely isolated from water and moisture sources. Storage areas require excellent ventilation and should be equipped with gas detection systems for phosphine. The compound should be kept in tightly sealed, moisture-proof containers away from acids, oxidizing agents, and heat sources. Access should be restricted to trained personnel only, with appropriate emergency response equipment readily available.
What to do in case of contact with aluminum phosphorus(3-)?
Immediate evacuation from the exposure area is critical due to potential phosphine gas release. For skin contact, remove contaminated clothing and flush affected areas with large amounts of water. In case of inhalation exposure, move the person to fresh air immediately and seek urgent medical attention. Eye contact requires immediate irrigation with water for at least 15 minutes. All exposure incidents require immediate professional medical evaluation and treatment.
How to dispose of aluminum phosphorus(3-) appropriately?
Aluminum phosphorus(3-) disposal requires specialized hazardous waste handling procedures due to its extreme toxicity and reactivity classifications. The material must be disposed of through licensed hazardous waste contractors experienced with water-reactive substances. Incineration or chemical neutralization should only be performed by qualified professionals in appropriate facilities. All disposal activities must comply with local, national, and EU hazardous waste regulations and transportation requirements.
How to transport aluminum phosphorus(3-)?
Aluminum phosphorus(3-) is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases) with Packing Group I designation. Transportation requires specialized packaging that prevents moisture ingress and appropriate hazard labeling including GHS02, GHS06, and GHS09 pictograms. Vehicles must carry emergency response information and drivers require hazardous materials transportation certification. Shipments must comply with all ADR dangerous goods regulations.
Is aluminum phosphorus(3-) subject to specific regulations?
Aluminum phosphorus(3-) is subject to stringent regulations under REACH, CLP, and dangerous goods legislation due to its extreme hazard classifications including Acute Toxicity categories 1, 2, and 3. The compound requires safety data sheets, hazard communication, and may face restrictions on use and distribution. While not currently listed as an SVHC, its high toxicity and environmental hazard classifications require compliance with occupational exposure limits and environmental protection measures.
Where to buy aluminum phosphorus(3-) in Europe?
Aluminum phosphorus(3-) is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous materials handling. OYSI provides comprehensive regulatory support, proper documentation, and ensures compliant packaging and transportation for this highly regulated substance. Due to the extreme hazard classifications and regulatory requirements, procurement requires verification of end-use applications and appropriate handling capabilities by qualified industrial users only.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.