Tetrasodium;iron(2+);hexacyanide;decahydrate

C6H20FeN6Na4O10

tetrasodium;iron(2+);hexacyanide;decahydrate

CAS14434-22-1

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Identification

CAS Number
14434-22-1
EC Number
237-081-9
UN Number
1588
PubChem CID
6093374

Physical-chemical properties

Molecular Formula
C6H20FeN6Na4O10
Molar Mass
484.06 g/mol
IUPAC Name
tetrasodium;iron(2+);hexacyanide;decahydrate

Chemical Identifiers

InChI
InChI=1S/6CN.Fe.4Na.10H2O/c6*1-2;;;;;;;;;;;;;;;/h;;;;;;;;;;;10*1H2/q6*-1;+2;4*+1;;;;;;;;;;
InChI Key
JFSUDVTVQZUDOP-UHFFFAOYSA-N

Overview

Tetrasodium iron(2+) hexacyanide decahydrate (CAS 14434-22-1) is an inorganic coordination compound with distinctive blue coloration and analytical detection properties. This complex iron cyanide salt, also known as sodium ferrocyanide decahydrate, represents a fundamental coordination compound in industrial chemistry. With the molecular formula C6H20FeN6Na4O10 and a molecular weight of 484.06 g/mol, this crystalline material consists of iron(II) centers coordinated by six cyanide ligands, balanced by four sodium cations and stabilized by ten water molecules of crystallization. The compound exhibits the characteristic stability of ferrocyanide complexes, where the iron center remains in a low-spin state due to the strong field ligand environment created by the cyanide groups. From a safety perspective, tetrasodium iron(2+) hexacyanide decahydrate is classified under ADR Class 6.1, indicating its toxic nature, though it does not require specific GHS pictograms or signal words under standard handling conditions. The compound's toxicity profile differs significantly from simpler cyanide salts due to the stability of the coordination complex, which prevents easy release of free cyanide ions under normal conditions. Industrial applications primarily focus on analytical chemistry and manufacturing processes. The compound serves as a crucial reagent in analytical testing, particularly for metal ion detection and precipitation reactions. It finds extensive use in the production of pigments, where its iron cyanide framework contributes to color development. Additionally, the material functions as a processing aid in various chemical synthesis applications, often in contexts where controlled iron coordination is required, similar to applications involving compounds like 4-nitroaniline in specialized chemical processes. OYSI maintains reliable supply chains for tetrasodium iron(2+) hexacyanide decahydrate to support diverse European industrial requirements.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1588
ADR Class6.1
Packing Group
Tunnel Code
Proper Shipping NameNatriumhexacyanoferrat(II)-Decahydrat
Marine PollutantNo

Frequently Asked Questions

What is tetrasodium;iron(2+);hexacyanide;decahydrate?

Tetrasodium iron(2+) hexacyanide decahydrate is an inorganic chemical compound with the molecular formula C6H20FeN6Na4O10 and CAS number 14434-22-1. This compound, also known as sodium ferrocyanide decahydrate, consists of iron(II) coordinated with six cyanide ligands, balanced by four sodium ions, and contains ten molecules of water of crystallization. It has a molecular weight of 484.06 g/mol and appears as yellow crystalline powder.

What are the physicochemical properties of tetrasodium iron(2+) hexacyanide decahydrate?

Tetrasodium iron(2+) hexacyanide decahydrate is a yellow crystalline solid at room temperature with good water solubility. The compound is odorless and stable under normal conditions. Its decahydrate form indicates it contains ten water molecules per formula unit, making it relatively hygroscopic. The compound has a molecular weight of 484.06 g/mol and maintains its crystalline structure when properly stored away from heat and moisture.

What is tetrasodium iron(2+) hexacyanide decahydrate used for?

Tetrasodium iron(2+) hexacyanide decahydrate is primarily used as an anti-caking agent in food processing, particularly in salt production. It serves as a laboratory reagent for analytical chemistry applications and is employed in the manufacturing of pigments, specifically Prussian blue. The compound also finds use in metal surface treatment processes and as a source of ferrocyanide ions in various industrial chemical syntheses and water treatment applications.

How to handle tetrasodium iron(2+) hexacyanide decahydrate safely?

Tetrasodium iron(2+) hexacyanide decahydrate should be handled with standard laboratory safety precautions including wearing safety glasses, gloves, and protective clothing. Work in well-ventilated areas and avoid creating dust. Although this compound has no specific GHS pictograms or signal words, good chemical hygiene practices should be followed. Avoid contact with strong acids which could release toxic hydrogen cyanide gas. Wash hands thoroughly after handling and avoid eating, drinking, or smoking in work areas.

How to store tetrasodium iron(2+) hexacyanide decahydrate correctly?

Tetrasodium iron(2+) hexacyanide decahydrate should be stored in a cool, dry place in tightly sealed containers to prevent moisture absorption and decomposition. Keep away from heat sources, direct sunlight, and strong acids. Store in original packaging or compatible containers made of suitable materials. Maintain storage temperatures below 25°C and ensure good ventilation in storage areas. Keep separate from incompatible materials such as strong oxidizing agents and acids to prevent unwanted reactions.

What to do in case of contact with tetrasodium iron(2+) hexacyanide decahydrate?

In case of skin contact with tetrasodium iron(2+) hexacyanide decahydrate, immediately wash the affected area with plenty of soap and water for at least 15 minutes. For eye contact, flush eyes with clean water for 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. In case of ingestion, rinse mouth with water and seek medical attention. Although the compound has no specific hazard classification, always consult a physician if symptoms persist or if large amounts were involved.

How to dispose of tetrasodium iron(2+) hexacyanide decahydrate appropriately?

Tetrasodium iron(2+) hexacyanide decahydrate waste should be disposed of according to local and national environmental regulations. Contact licensed waste disposal companies for proper treatment and disposal. Do not discharge into sewers, waterways, or soil without proper treatment. Small laboratory quantities may be neutralized and treated according to institutional waste management protocols. Always check with local environmental authorities for specific disposal requirements and approved waste treatment facilities in your region.

How to transport tetrasodium iron(2+) hexacyanide decahydrate?

Tetrasodium iron(2+) hexacyanide decahydrate is classified under ADR transport regulations as Class 6.1 (toxic substances), requiring appropriate packaging and labeling for shipment. Use UN-approved packaging suitable for Class 6.1 materials and ensure proper documentation including safety data sheets. Vehicles must carry appropriate placards and emergency equipment. Drivers require ADR certification for transporting dangerous goods. Always comply with national and international transport regulations and consult current ADR guidelines for specific packaging and documentation requirements.

Is tetrasodium iron(2+) hexacyanide decahydrate subject to special regulations?

Tetrasodium iron(2+) hexacyanide decahydrate is subject to REACH regulation in Europe, requiring registration for import or manufacture above certain tonnages. It is not classified as a Substance of Very High Concern (SVHC). The compound falls under CLP regulation for classification and labeling, though it currently has no specific hazard classification. Food-grade applications are regulated under food additive legislation. Transportation is regulated under ADR as Class 6.1, and workplace exposure may be subject to occupational health regulations.

Where to buy tetrasodium iron(2+) hexacyanide decahydrate in Europe?

Tetrasodium iron(2+) hexacyanide decahydrate is available through OYSI, a European distributor of technical chemicals serving industrial and laboratory customers across Europe. OYSI provides quality chemical products with proper documentation including safety data sheets and certificates of analysis. As a specialized chemical distributor, OYSI ensures compliance with European regulations including REACH and ADR transport requirements. Contact OYSI directly for availability, specifications, and pricing information for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.