Tetracyclohexylstannane
C24H44Sn
tetracyclohexylstannane
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Identification
- CAS Number
- 1449-55-4
- EC Number
- 215-910-5
- UN Number
- 3077
- Index Number
- 050-012-00-5
- PubChem CID
- 74056
Physical-chemical properties
- Molecular Formula
- C24H44Sn
- Molar Mass
- 451.30 g/mol
- IUPAC Name
- tetracyclohexylstannane
Chemical Identifiers
- InChI
- InChI=1S/4C6H11.Sn/c4*1-2-4-6-5-3-1;/h4*1H,2-6H2;
- InChI Key
- JUISPCSEIXBMNI-UHFFFAOYSA-N
Overview
Tetracyclohexylstannane (CAS 1449-55-4) is an organotin compound characterized by four cyclohexyl groups bonded to a central tin atom, exhibiting moderate toxicity and significant environmental hazard properties. This specialized organotin chemical, with the molecular formula C24H44Sn and a molecular weight of 451.3 g/mol, represents a distinct class of organometallic compounds where tin serves as the central metal atom surrounded by four cyclohexyl substituents. The compound's structure provides unique chemical properties that make it valuable in specific industrial applications, though its toxicological profile requires careful handling protocols. From a safety perspective, tetracyclohexylstannane carries multiple acute toxicity classifications (Acute Tox. 4) across different exposure routes, necessitating appropriate personal protective equipment and engineering controls during handling. The compound poses significant environmental concerns, classified as both Aquatic Acute 1 and Aquatic Chronic 1, indicating high toxicity to aquatic organisms with long-lasting effects. These hazard classifications are reflected in its GHS07 and GHS09 pictograms and "Warning" signal word. Transportation falls under ADR Class 9 (miscellaneous dangerous substances), requiring specialized shipping procedures. In industrial applications, tetracyclohexylstannane finds primary use as a catalyst in polymerization reactions, particularly in the production of polyurethane foams and elastomers where its organotin structure provides excellent catalytic activity. The compound also serves as an intermediate in the synthesis of other specialized organotin compounds and as a stabilizer in certain polymer formulations. Like related compounds such as fluoro(trihexyl)stannane, it belongs to the broader family of alkyltin compounds that exhibit similar catalytic properties but with distinct reactivity profiles based on their specific substituent groups. OYSI maintains reliable supply chains for tetracyclohexylstannane to support European industrial customers requiring this specialized organotin compound for their manufacturing processes.
Safety & Classification
Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Tetracyclohexylstannan |
| Marine Pollutant | No |
Frequently Asked Questions
What is tetracyclohexylstannane?
Tetracyclohexylstannane is an organotin compound with the molecular formula C24H44Sn and CAS number 1449-55-4. This chemical substance has a molecular weight of 451.3 g/mol and belongs to the family of tetraalkyltin compounds. It is classified as moderately toxic (Acute Tox. 4) and poses environmental hazards to aquatic life. The compound displays GHS07 and GHS09 pictograms, indicating health and environmental warnings respectively.
What are the physicochemical properties of tetracyclohexylstannane?
Tetracyclohexylstannane is a solid organometallic compound at room temperature with a molecular weight of 451.3 g/mol. As an organotin derivative with four cyclohexyl groups attached to a central tin atom, it typically exhibits low water solubility due to its highly hydrophobic cyclohexyl substituents. The compound's physical appearance and specific properties like melting point and density require specialized analytical characterization due to its complex molecular structure.
What is tetracyclohexylstannane used for?
Tetracyclohexylstannane serves primarily as a specialized organotin reagent in research and industrial applications. It is commonly used as a catalyst or intermediate in organic synthesis reactions, particularly in polymer chemistry and materials science. The compound may also function as a precursor for other organotin derivatives or as a specialized additive in certain chemical processes requiring tin-based compounds with specific steric properties provided by the cyclohexyl groups.
How to handle tetracyclohexylstannane safely?
Tetracyclohexylstannane requires careful handling due to its Acute Tox. 4 classification across multiple exposure routes. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and appropriate respiratory protection when handling powders or in poorly ventilated areas. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin and eye contact, and ensure thorough washing after handling to prevent accidental ingestion.
How to store tetracyclohexylstannane correctly?
Tetracyclohexylstannane should be stored in a cool, dry, well-ventilated area away from incompatible materials and ignition sources. Use tightly sealed, chemically compatible containers to prevent contamination and exposure. Storage areas should be equipped with appropriate spill containment measures due to the compound's environmental hazards (Aquatic Acute 1, Aquatic Chronic 1). Implement restricted access protocols and maintain proper inventory management to ensure safe handling and regulatory compliance.
What to do in case of contact with tetracyclohexylstannane?
Immediate action is required upon contact with tetracyclohexylstannane due to its toxicity classification. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek medical attention. Always consult safety data sheets for specific first aid measures.
How to dispose of tetracyclohexylstannane appropriately?
Tetracyclohexylstannane waste must be disposed of as hazardous waste according to local and European regulations due to its toxicity and environmental impact classifications. The compound cannot be disposed of through regular waste streams and requires specialized hazardous waste management services. Container disposal should follow local regulations, with proper labeling and documentation throughout the disposal process. Consult local environmental authorities and certified waste disposal companies for compliant disposal procedures.
How to transport tetracyclohexylstannane?
Tetracyclohexylstannane is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. This classification requires specific packaging, labeling, and documentation according to European transport regulations. Shipments must include proper hazard labels, transport documents, and emergency response information. Only qualified carriers experienced in handling Class 9 materials should transport this substance, ensuring compliance with all applicable national and international transport regulations.
Is tetracyclohexylstannane subject to specific regulations?
Tetracyclohexylstannane is subject to European chemical regulations including REACH and CLP classifications. The compound is not currently listed as a Substance of Very High Concern (SVHC), but its toxicity and environmental hazard classifications require compliance with standard chemical safety regulations. Users must ensure proper risk assessments, safety data sheet distribution, and worker protection measures are implemented. Export/import activities may require additional documentation depending on destination countries and quantities involved.
Where to buy tetracyclohexylstannane in Europe?
Tetracyclohexylstannane is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides reliable supply chains for specialized organotin compounds like tetracyclohexylstannane to research institutions, industrial customers, and chemical manufacturers across Europe. As a professional chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for all shipments, supporting customers with technical expertise and safety data sheets for safe product use.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.