Fluoro(trihexyl)stannane
C18H39FSn
fluoro(trihexyl)stannane
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Identification
- CAS Number
- 20153-50-8
- EC Number
- 243-547-2
- UN Number
- 3077
- Index Number
- 050-010-00-4
- PubChem CID
- 88383
Physical-chemical properties
- Molecular Formula
- C18H39FSn
- Molar Mass
- 393.20 g/mol
- IUPAC Name
- fluoro(trihexyl)stannane
Chemical Identifiers
- InChI
- InChI=1S/3C6H13.FH.Sn/c3*1-3-5-6-4-2;;/h3*1,3-6H2,2H3;1H;/q;;;;+1/p-1
- InChI Key
- VIQZOBIMPYFTNZ-UHFFFAOYSA-M
Overview
Fluoro(trihexyl)stannane (CAS 20153-50-8) is an organotin compound characterized by its fluorine-tin bond and three hexyl substituents on the tin center. This specialized organotin chemical, with the molecular formula C18H39FSn and molecular weight of 393.2 g/mol, represents an important class of organometallic compounds used in various industrial applications. The compound features a central tin atom bonded to one fluorine atom and three hexyl chains, creating a structure that combines the unique properties of organotin chemistry with fluorine functionality. Its EC number 243-547-2 identifies it within European chemical regulations. From a safety perspective, fluoro(trihexyl)stannane carries significant hazard classifications, including Acute Toxicity Category 4 across multiple exposure routes and severe aquatic toxicity (Aquatic Acute 1, Aquatic Chronic 1). The compound displays GHS07 and GHS09 pictograms with a "Warning" signal word, indicating both health hazards and environmental dangers. Its ADR Class 9 classification designates it as a miscellaneous dangerous substance requiring careful handling and transport protocols. The compound belongs to a broader family of organotin chemicals, sharing structural similarities with compounds like tetracyclohexylstannane, though it differs in its alkyl substituents and the presence of the fluorine atom. This fluorine incorporation often enhances specific catalytic or chemical properties compared to purely hydrocarbon-substituted tin compounds. Primary industrial applications include use as a catalyst in organic synthesis reactions, particularly in processes requiring selective fluorination or organotin-mediated transformations. The compound also finds application in specialized polymer chemistry and as an intermediate in the synthesis of other fluorinated organotin derivatives. OYSI maintains availability of fluoro(trihexyl)stannane for qualified industrial customers requiring this specialized organometallic compound for their technical applications.
Safety & Classification
Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Fluortrihexylstannan |
| Marine Pollutant | No |
Frequently Asked Questions
What is fluoro(trihexyl)stannane?
Fluoro(trihexyl)stannane is an organotin compound with the molecular formula C18H39FSn and CAS number 20153-50-8. This chemical substance has a molecular weight of 393.2 g/mol and belongs to the family of fluorinated tin compounds. It is characterized by a tin atom bonded to three hexyl groups and one fluorine atom, making it a specialized organometallic compound used in various industrial applications.
What are the physicochemical properties of fluoro(trihexyl)stannane?
Fluoro(trihexyl)stannane is an organometallic compound that typically appears as a liquid or low-melting solid at room temperature due to its long alkyl chains. The presence of three hexyl groups provides significant hydrophobic character, making it poorly soluble in water but soluble in organic solvents. Its molecular structure features a central tin atom with fluorine substitution, which influences its reactivity and stability properties.
What is fluoro(trihexyl)stannane used for?
Fluoro(trihexyl)stannane is primarily used as a specialized reagent in organic synthesis and as an intermediate in the production of other organotin compounds. Its applications include use in polymer chemistry, as a catalyst in certain chemical reactions, and in the synthesis of fluorinated materials. The compound's unique combination of tin, fluorine, and long alkyl chains makes it valuable for specific industrial processes requiring organometallic functionality.
How to handle fluoro(trihexyl)stannane safely?
Fluoro(trihexyl)stannane requires careful handling due to its Acute Tox. 4 classification and aquatic toxicity. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation exposure. The substance carries a Warning signal word and GHS07 pictogram, indicating moderate hazard levels requiring standard laboratory safety precautions.
How to store fluoro(trihexyl)stannane correctly?
Fluoro(trihexyl)stannane should be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly closed and protected from moisture and extreme temperatures. Store away from oxidizing agents and acids. Due to its aquatic toxicity (GHS09 pictogram), ensure storage areas have appropriate containment measures to prevent environmental release. Regular inspection of container integrity is recommended for this organometallic compound.
What to do in case of contact with fluoro(trihexyl)stannane?
In case of skin contact with fluoro(trihexyl)stannane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes. If inhaled, move to fresh air immediately. Given its Acute Tox. 4 classification, seek medical attention if symptoms develop or in case of significant exposure. Do not induce vomiting if ingested.
How to dispose of fluoro(trihexyl)stannane properly?
Fluoro(trihexyl)stannane must be disposed of as hazardous waste due to its toxicity and environmental hazard classification. Contact licensed waste disposal companies specializing in organometallic compounds. Never dispose of this substance down drains or in regular waste streams due to its aquatic toxicity (Aquatic Acute 1, Aquatic Chronic 1). Follow local and national regulations for hazardous waste disposal, and maintain proper documentation of disposal activities.
How to transport fluoro(trihexyl)stannane?
Fluoro(trihexyl)stannane is classified under ADR Class 9 (Miscellaneous dangerous substances), Packing Group III, indicating moderate transport hazard. It requires appropriate packaging according to ADR regulations and proper hazard labeling during transport. Use UN-approved packaging and ensure vehicles are properly placarded. Transport documentation must include the correct shipping name, UN number, and hazard class information according to dangerous goods transport regulations.
Is fluoro(trihexyl)stannane subject to specific regulations?
Fluoro(trihexyl)stannane is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification for hazard communication. It is not currently listed as a Substance of Very High Concern (SVHC). The compound must comply with workplace exposure limits and environmental protection measures due to its toxicity profile. Users must ensure proper risk assessment and implementation of appropriate risk management measures.
Where to buy fluoro(trihexyl)stannane in Europe?
Fluoro(trihexyl)stannane is available through OYSI, a specialized European distributor of technical chemicals and organometallic compounds. OYSI provides this substance to industrial customers with proper technical documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures quality standards and proper handling procedures for specialized compounds like fluoro(trihexyl)stannane throughout Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.