Tetrachlorostannane
Cl4Sn
tetrachlorostannane
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Identification
- CAS Number
- 7646-78-8
- EC Number
- 231-588-9
- UN Number
- 1827
- Index Number
- 050-001-00-5
- PubChem CID
- 24287
Physical-chemical properties
- Molecular Formula
- Cl4Sn
- Molar Mass
- 260.50 g/mol
- IUPAC Name
- tetrachlorostannane
Chemical Identifiers
- InChI
- InChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
- InChI Key
- HPGGPRDJHPYFRM-UHFFFAOYSA-J
Overview
Tetrachlorostannane (CAS 7646-78-8) is an inorganic tin compound with four chlorine atoms exhibiting strong corrosive properties and high reactivity. This organotin compound, also known by its molecular formula SnCl4, represents one of the most important tin halides in industrial chemistry. As a tetrahedral molecular structure, tetrachlorostannane demonstrates exceptional Lewis acid behavior, making it highly valuable in various chemical processes. The compound appears as a colorless to pale yellow fuming liquid at room temperature, with a characteristic pungent odor due to its hydrolytic instability in moist air. The substance's corrosive nature, classified under Skin Corr. 1B according to GHS classification, demands careful handling protocols. Its strong affinity for water results in the formation of hydrochloric acid and tin oxychlorides, contributing to its hazardous profile. Transport regulations classify it under ADR Class 8 (corrosive substances), reflecting its potential to cause severe skin burns and eye damage upon contact. Industrial applications primarily center around its role as a precursor in tin chemistry and as a Lewis acid catalyst in organic synthesis. The compound serves as an essential intermediate in the production of organotin compounds and finds significant use in the semiconductor industry for chemical vapor deposition processes. Additionally, tetrachlorostannane functions as a catalyst in various polymerization reactions, similar to how trichlorostibane operates in antimony-based catalytic systems. From a chemical safety perspective, the compound requires storage in anhydrous conditions and appropriate corrosion-resistant containers. Its aquatic chronic toxicity classification (Aquatic Chronic 3) necessitates environmental protection measures during handling and disposal. OYSI maintains reliable supply chains for tetrachlorostannane, ensuring consistent availability for industrial customers across European markets.
Safety & Classification
Skin Corr. 1B; Aquatic Chronic 3
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1827 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Zinntetrachlorid, wasserfrei |
| Marine Pollutant | No |
Frequently Asked Questions
What is tetrachlorostannane?
Tetrachlorostannane is an inorganic tin compound with the molecular formula Cl4Sn and CAS number 7646-78-8. This chemical substance has a molecular weight of 260.5 g/mol and is classified as a corrosive material. It belongs to the family of tin halides and is characterized by its high reactivity and corrosive properties, making it hazardous to handle without proper safety measures.
What are the physicochemical properties of tetrachlorostannane?
Tetrachlorostannane is typically a colorless to pale yellow liquid at room temperature with a pungent, irritating odor. It has a molecular weight of 260.5 g/mol and reacts violently with water, producing hydrochloric acid and tin compounds. The substance is highly corrosive and exhibits strong oxidizing properties, making it incompatible with many organic materials and metals.
What is tetrachlorostannane used for?
Tetrachlorostannane is primarily used as a precursor in the synthesis of organotin compounds and as a catalyst in various chemical reactions. It serves as an intermediate in the production of tin-based materials and is utilized in specialized industrial processes requiring tin halide chemistry. The compound is also employed in research applications and in the manufacturing of certain electronic components.
How to handle tetrachlorostannane safely?
Tetrachlorostannane must be handled with extreme caution due to its corrosive nature (Skin Corr. 1B classification). Essential protective equipment includes chemical-resistant gloves, safety goggles, face shields, and acid-resistant clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation of vapors. All handling procedures must comply with the GHS05 pictogram warnings indicating corrosive hazards.
How to store tetrachlorostannane correctly?
Tetrachlorostannane must be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from moisture and incompatible materials. Storage areas should be equipped with appropriate containment systems and emergency equipment. The substance must be kept away from water, alcohols, and organic materials to prevent violent reactions and should be stored according to local chemical storage regulations.
What to do in case of contact with tetrachlorostannane?
Immediate action is required for any contact with tetrachlorostannane due to its corrosive properties. For skin contact, immediately flush with large amounts of water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse continuously with water and seek immediate medical attention. In case of inhalation, move to fresh air immediately and consult a physician if respiratory irritation occurs.
How to dispose of tetrachlorostannane properly?
Tetrachlorostannane disposal must comply with local and international hazardous waste regulations due to its corrosive and environmentally harmful properties (Aquatic Chronic 3). The substance should never be poured down drains or released into the environment. Disposal must be carried out by licensed waste management companies specialized in handling corrosive chemicals, following appropriate neutralization and treatment procedures.
How to transport tetrachlorostannane?
Tetrachlorostannane is classified as ADR Class 8 (corrosive substances) with Packing Group II, indicating moderate danger level during transport. Transportation requires appropriate UN-specification packaging designed for corrosive liquids, proper labeling with corrosive hazard symbols, and compliance with ADR regulations. Drivers and handlers must be trained in hazardous materials transport and emergency response procedures.
Is tetrachlorostannane subject to specific regulations?
Tetrachlorostannane is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification as a corrosive substance (Skin Corr. 1B). It is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational safety regulations, environmental protection laws, and proper classification and labeling requirements under GHS standards.
Where to buy tetrachlorostannane in Europe?
Tetrachlorostannane is available through OYSI, a specialized European distributor of technical chemicals. As an established chemical supplier, OYSI can provide this corrosive compound to qualified industrial and research customers with appropriate handling capabilities. Due to the hazardous nature of this substance, purchases typically require verification of proper storage facilities and safety protocols.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.