Tetrachlorostannane

Cl4Sn

tetrachlorostannane

CAS7646-78-8
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7646-78-8
EC Number
231-588-9
UN Number
1827
Index Number
050-001-00-5
PubChem CID
24287

Physical-chemical properties

Molecular Formula
Cl4Sn
Molar Mass
260.50 g/mol
IUPAC Name
tetrachlorostannane

Chemical Identifiers

InChI
InChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChI Key
HPGGPRDJHPYFRM-UHFFFAOYSA-J

Overview

Tetrachlorostannane (CAS 7646-78-8) is an inorganic tin compound with high reactivity and corrosive properties toward skin and materials. This chemical compound, also known by its IUPAC name tetrachlorostannane, represents a significant organotin chemical used across various industrial applications. With the molecular formula Cl4Sn and a molecular weight of 260.5 g/mol, tetrachlorostannane appears as a colorless to pale yellow liquid that demonstrates notable chemical reactivity. The compound belongs to the broader family of metal halides, sharing certain characteristics with related substances such as trichlorostibane and pentachloro-lambda5-phosphane in terms of their halogenated metal structures. The safety profile of tetrachlorostannane requires careful consideration due to its classification as Skin Corr. 1B, indicating severe skin corrosion potential, and Aquatic Chronic 3 for environmental concerns. The GHS05 pictogram and "Danger" signal word emphasize the corrosive nature of this substance, while its ADR Class 8 classification confirms its status as a corrosive material for transportation purposes. Proper handling protocols, including appropriate personal protective equipment and containment measures, are essential when working with this compound. Industrial applications of tetrachlorostannane primarily focus on its role as a precursor in tin chemistry and semiconductor manufacturing processes. The compound serves as an important intermediate in the production of organotin compounds and finds use in specialized coating applications. Additionally, tetrachlorostannane plays a role in certain catalytic processes where tin-based catalysts are required. OYSI maintains reliable supply chains for tetrachlorostannane, ensuring consistent availability for European industrial customers requiring this specialized chemical compound.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1827
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameZinntetrachlorid, wasserfrei
Marine PollutantNo

Frequently Asked Questions

What is tetrachlorostannane?

Tetrachlorostannane is an inorganic tin compound with the chemical formula Cl4Sn and CAS number 7646-78-8. This chemical substance has a molecular weight of 260.5 g/mol and belongs to the tin tetrachloride family. It is classified as a corrosive substance under GHS regulations, specifically Skin Corr. 1B, indicating severe skin corrosion properties. The compound also presents chronic aquatic toxicity (Aquatic Chronic 3) and requires careful handling due to its dangerous nature.

What are the physico-chemical properties of tetrachlorostannane?

Tetrachlorostannane typically appears as a colorless to pale yellow liquid at room temperature with a molecular formula of Cl4Sn. The compound has a distinctive pungent, acrid odor and readily hydrolyzes in the presence of moisture, forming hydrochloric acid and tin oxides. It has high reactivity with water and organic materials. The substance demonstrates high density and volatility, making proper ventilation essential during handling and storage operations.

What is tetrachlorostannane used for?

Tetrachlorostannane serves primarily as a chemical intermediate in various industrial processes, particularly in tin chemistry applications. It is commonly used in the production of organotin compounds, as a catalyst in certain chemical reactions, and in the preparation of tin-based materials. The compound finds applications in electronics manufacturing, glass coating processes, and as a precursor for specialized tin compounds used in research and development within the chemical industry.

How to handle tetrachlorostannane safely?

Tetrachlorostannane requires strict safety protocols due to its corrosive nature (Skin Corr. 1B classification). Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, face shields, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Emergency eyewash stations and safety showers must be readily accessible, and all handling should follow established chemical safety procedures.

How to store tetrachlorostannane correctly?

Tetrachlorostannane must be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from moisture and incompatible materials. The storage area should be equipped with appropriate containment measures and kept away from heat sources, oxidizing agents, and reactive metals. Secondary containment is recommended to prevent environmental contamination. Access should be restricted to trained personnel only, with proper labeling and safety data sheets readily available.

What to do in case of contact with tetrachlorostannane?

Immediate action is required for any contact with tetrachlorostannane due to its severe corrosive properties. For skin contact, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes while holding eyelids open. Seek immediate medical attention for all exposures. If inhaled, move to fresh air and seek medical care promptly.

How to dispose of tetrachlorostannane properly?

Tetrachlorostannane must be disposed of as hazardous waste in accordance with local, national, and international environmental regulations. The substance cannot be discharged into sewers, waterways, or regular waste streams due to its corrosive nature and aquatic toxicity. Disposal should only be conducted by licensed hazardous waste management companies following proper neutralization and treatment procedures. Contaminated containers require special handling and cannot be reused for other purposes.

How to transport tetrachlorostannane?

Tetrachlorostannane is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating high transport hazard requirements. Transportation must comply with international dangerous goods regulations including proper packaging, labeling with GHS05 pictogram, and documentation. Vehicles must carry appropriate emergency equipment and drivers require hazardous materials certification. The substance requires UN specification packaging and must be segregated from incompatible materials during transport.

Is tetrachlorostannane subject to specific regulations?

Tetrachlorostannane is subject to comprehensive chemical safety regulations including REACH registration requirements in Europe and CLP classification obligations. The substance carries a 'Danger' signal word and requires safety data sheets for all commercial transactions. While not currently listed as an SVHC (Substance of Very High Concern), its corrosive properties and environmental impact require compliance with occupational health standards and environmental protection measures across European jurisdictions.

Where to buy tetrachlorostannane in Europe?

Tetrachlorostannane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides this corrosive substance with full regulatory compliance, proper documentation, and technical support. As a professional chemical distributor, OYSI ensures adherence to ADR transport requirements and provides comprehensive safety data sheets. Contact OYSI directly for availability, specifications, and delivery arrangements to your European location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.