Silver 2,4,6-trinitrophenolate

C6H2AgN3O7

silver 2,4,6-trinitrophenolate

CAS146-84-9
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
146-84-9
EC Number
205-682-5
UN Number
Index Number
609-010-00-5
PubChem CID
8976

Physical-chemical properties

Molecular Formula
C6H2AgN3O7
Molar Mass
335.96 g/mol
IUPAC Name
silver 2,4,6-trinitrophenolate

Chemical Identifiers

InChI
InChI=1S/C6H3N3O7.Ag/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h1-2,10H;/q;+1/p-1
InChI Key
TYTYIUANSACAEM-UHFFFAOYSA-M

Overview

Silver 2,4,6-trinitrophenolate (CAS 146-84-9) is an explosive silver salt compound with high instability and acute toxicity properties. This specialized organometallic compound, also known by its IUPAC designation silver 2,4,6-trinitrophenolate, represents a highly reactive explosive material with the molecular formula C6H2AgN3O7 and a molecular weight of 335.96 g/mol. The substance belongs to the family of nitrophenolate salts, where silver cations are coordinated with the trinitrophenolate anion, creating a compound with distinctive explosive characteristics. The compound exhibits critical safety considerations due to its classification as an unstable explosive (Unst. Expl.) combined with acute toxicity category 3 across multiple exposure routes. The GHS01 and GHS06 pictograms indicate both explosive and acute toxicity hazards, requiring extreme caution during handling, storage, and transportation. The "Danger" signal word emphasizes the severity of associated risks, particularly regarding shock sensitivity and potential detonation under various conditions. From a structural perspective, silver 2,4,6-trinitrophenolate shares chemical relationships with other nitroaromatic compounds such as 2-methyl-1,3,5-trinitrobenzene, though the silver coordination significantly alters its reactivity profile and applications. Unlike purely organic explosives, this silver-containing compound offers unique properties that make it valuable in specialized industrial applications. Primary industrial applications include use as a specialized explosive in mining operations, as a component in certain pyrotechnic formulations, and in research applications requiring controlled explosive reactions. The compound also finds application in specialized analytical chemistry procedures where its unique properties are advantageous. OYSI maintains strategic partnerships with certified manufacturers to ensure reliable availability of silver 2,4,6-trinitrophenolate for qualified industrial customers requiring this specialized explosive compound.

Safety & Classification

Danger
Classification:

Unst. Expl.; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H200

Unstable explosive.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate is an explosive organometallic compound with the molecular formula C6H2AgN3O7 and CAS number 146-84-9. This chemical substance consists of a silver cation bonded to the 2,4,6-trinitrophenolate anion (picrate ion). With a molecular weight of 335.96 g/mol, it belongs to the class of unstable explosives and presents significant acute toxicity hazards, requiring extreme caution in handling and storage.

What are the physicochemical properties of silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate is typically a crystalline solid at room temperature with characteristic yellow to orange coloration common to picrate compounds. The compound exhibits low solubility in water but may dissolve in certain organic solvents. Due to its explosive nature, it is highly sensitive to friction, impact, and heat. The presence of the nitro groups and silver ion contributes to its instability and explosive characteristics.

What is silver 2,4,6-trinitrophenolate used for?

Silver 2,4,6-trinitrophenolate is primarily used in specialized applications requiring controlled explosive properties, such as in pyrotechnics, detonators, and explosive research. It may also serve as a reagent in analytical chemistry for specific detection methods. Due to its extreme hazard profile and regulatory restrictions, its use is limited to professional applications with appropriate safety infrastructure and qualified personnel handling explosive materials.

How to handle silver 2,4,6-trinitrophenolate safely?

Silver 2,4,6-trinitrophenolate requires extreme safety precautions due to its unstable explosive and acute toxic properties. Personnel must wear full protective equipment including explosion-proof clothing, face shields, and respiratory protection. Handle only small quantities using non-sparking tools in designated explosion-proof areas. Avoid friction, impact, static electricity, and heat sources. Only trained professionals with explosive handling certification should manipulate this substance under controlled conditions.

How to store silver 2,4,6-trinitrophenolate correctly?

Silver 2,4,6-trinitrophenolate must be stored in explosion-proof facilities designed for unstable explosives, maintaining cool, dry conditions away from heat, ignition sources, and incompatible materials. Storage areas require specialized ventilation, grounding systems, and limited access. Keep away from reducing agents, combustible materials, and other chemicals. Quantities should be minimized, and storage must comply with local explosive storage regulations and licensing requirements.

What to do in case of contact with silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate exposure requires immediate emergency response due to its acute toxicity. For skin contact, remove contaminated clothing and flush with copious water for at least 15 minutes. In case of inhalation, move to fresh air and seek immediate medical attention. For eye contact, rinse thoroughly with water. Never induce vomiting if ingested. Contact emergency services immediately and provide safety data sheet information to medical personnel.

How to dispose of silver 2,4,6-trinitrophenolate appropriately?

Silver 2,4,6-trinitrophenolate disposal requires specialized explosive waste management procedures through licensed hazardous waste contractors. The material cannot be disposed of through normal waste streams due to its explosive and toxic properties. Disposal methods typically involve controlled detonation or specialized chemical treatment by qualified explosive disposal experts. All disposal activities must comply with local explosive waste regulations and environmental protection requirements.

How to transport silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate transport requires compliance with dangerous goods regulations as an explosive substance. Special packaging, labeling with GHS01 and GHS06 pictograms, and documentation are mandatory. Transportation must be performed by certified dangerous goods carriers using appropriate explosive-rated vehicles and routes. Quantities are typically restricted, and advance notifications to authorities may be required depending on local regulations.

Is silver 2,4,6-trinitrophenolate subject to specific regulations?

Silver 2,4,6-trinitrophenolate is subject to extensive regulations including explosive licensing requirements, CLP classification as unstable explosive and acute toxic substance, and REACH registration obligations. The compound requires special permits for acquisition, storage, and use in most jurisdictions. It is not classified as SVHC under REACH but faces restrictions under explosive precursor regulations and may require additional authorization depending on intended use and quantities.

Where to buy silver 2,4,6-trinitrophenolate in Europe?

Silver 2,4,6-trinitrophenolate is available through specialized chemical distributors like OYSI, which supplies dangerous goods to qualified European customers. Purchase requires proper licensing for explosive materials handling and compliance with local regulations. Due to its hazardous classification, availability is restricted to authorized users with appropriate safety infrastructure. Contact OYSI's technical team for specific requirements, documentation, and regulatory compliance support for this controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.