Silver 2,4,6-trinitrophenolate

C6H2AgN3O7

silver 2,4,6-trinitrophenolate

CAS146-84-9
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
146-84-9
EC Number
205-682-5
UN Number
Index Number
609-010-00-5
PubChem CID
8976

Physical-chemical properties

Molecular Formula
C6H2AgN3O7
Molar Mass
335.96 g/mol
IUPAC Name
silver 2,4,6-trinitrophenolate

Chemical Identifiers

InChI
InChI=1S/C6H3N3O7.Ag/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h1-2,10H;/q;+1/p-1
InChI Key
TYTYIUANSACAEM-UHFFFAOYSA-M

Overview

Silver 2,4,6-trinitrophenolate (CAS 146-84-9) is an explosive silver salt compound with extreme shock and friction sensitivity properties. This highly hazardous chemical substance represents a class of metal picrate compounds known for their exceptional explosive characteristics and extreme handling sensitivity. With the molecular formula C6H2AgN3O7 and a molecular weight of 335.96 g/mol, silver 2,4,6-trinitrophenolate exhibits the characteristic properties of both heavy metal salts and nitroaromatic explosives. The compound is classified under multiple acute toxicity categories and carries an unstable explosive designation, requiring specialized storage and handling protocols under strictly controlled conditions. The substance displays typical properties of silver-based explosive compounds, including high sensitivity to mechanical shock, friction, heat, and electrostatic discharge. Its classification under GHS pictograms GHS01 (explosive) and GHS06 (toxic) reflects the dual hazard nature requiring comprehensive safety measures. Unlike related nitroaromatic compounds such as 2-methyl-1,3,5-trinitrobenzene, silver picrate presents additional toxicological concerns due to its heavy metal content. The compound shares structural similarities with other trinitrophenyl derivatives like 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline in terms of explosive potential. Industrial applications are extremely limited due to safety constraints, but the compound may find specialized use in pyrotechnic formulations, as a chemical intermediate in controlled synthesis reactions, or in specialized research applications requiring precise explosive characteristics. All applications require extensive safety protocols and regulatory compliance. OYSI maintains availability of silver 2,4,6-trinitrophenolate through specialized supply channels with comprehensive safety documentation and regulatory support for qualified industrial customers.

Safety & Classification

Danger
Classification:

Unst. Expl.; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H200

Unstable explosive.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate is an explosive organometallic compound with the molecular formula C6H2AgN3O7 and CAS number 146-84-9. This substance is the silver salt of picric acid (2,4,6-trinitrophenol), classified as an unstable explosive with acute toxicity properties. It has a molecular weight of 335.96 g/mol and presents significant safety hazards requiring specialized handling and storage protocols.

What are the physicochemical properties of silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate is typically a yellow to orange crystalline solid that is highly sensitive to heat, friction, and impact due to its explosive nature. As an organometallic compound containing silver and nitro groups, it exhibits limited water solubility and is particularly unstable when dry. The compound decomposes readily under various conditions, making it extremely hazardous to handle without proper precautions.

What is silver 2,4,6-trinitrophenolate used for?

Silver 2,4,6-trinitrophenolate is primarily used in specialized research applications and as an intermediate in certain chemical syntheses. Due to its explosive and toxic nature, its commercial applications are extremely limited and restricted to controlled laboratory environments. The compound may be used in analytical chemistry for specific detection methods or in academic research studying explosive compounds and organometallic chemistry under strict safety protocols.

How to handle silver 2,4,6-trinitrophenolate safely?

Silver 2,4,6-trinitrophenolate must be handled with extreme caution using appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work should be conducted in a fume hood away from heat sources, sparks, and friction. Only trained personnel should handle this material, using non-sparking tools and maintaining the compound in a moist state when possible to reduce explosion risk.

How to store silver 2,4,6-trinitrophenolate correctly?

Silver 2,4,6-trinitrophenolate must be stored in a cool, dry place away from heat sources, direct sunlight, and incompatible materials such as strong acids, bases, and reducing agents. The compound should be kept in appropriate explosive-rated containers, preferably slightly moistened to reduce sensitivity. Storage areas must be well-ventilated, temperature-controlled, and comply with local regulations for explosive materials storage.

What to do in case of contact with silver 2,4,6-trinitrophenolate?

Immediate medical attention is required for any contact with silver 2,4,6-trinitrophenolate due to its acute toxicity. For skin contact, remove contaminated clothing and flush affected areas with plenty of water for at least 15 minutes. If inhaled, move the person to fresh air immediately. For eye contact, flush with water continuously. Never induce vomiting if ingested. Contact emergency services and provide the safety data sheet to medical personnel.

How to dispose of silver 2,4,6-trinitrophenolate appropriately?

Silver 2,4,6-trinitrophenolate disposal must be handled by specialized hazardous waste disposal companies experienced with explosive materials. The compound cannot be disposed of through normal waste streams due to its explosive and toxic nature. Disposal must comply with local, national, and international regulations for explosive waste. Contact certified waste management professionals who can safely neutralize and dispose of the material using appropriate detonation or chemical treatment methods.

How to transport silver 2,4,6-trinitrophenolate?

Silver 2,4,6-trinitrophenolate transport requires compliance with dangerous goods regulations as an explosive material. Special packaging, labeling with GHS01 and GHS06 pictograms, and documentation are mandatory. Only authorized carriers experienced in explosive materials transport should handle shipments. The compound must be properly classified, packaged according to regulatory requirements, and accompanied by appropriate safety documentation including emergency response information.

Is silver 2,4,6-trinitrophenolate subject to specific regulations?

Silver 2,4,6-trinitrophenolate is subject to strict regulations under REACH, CLP, and explosive materials legislation. The compound is classified as unstable explosive and acutely toxic, requiring compliance with hazardous substances regulations. Users must ensure proper registration, authorization for handling explosive materials, and adherence to workplace safety directives. Import, export, and use may require special permits depending on jurisdiction and intended application.

Where to buy silver 2,4,6-trinitrophenolate in Europe?

Silver 2,4,6-trinitrophenolate is available through specialized chemical distributors like OYSI, which supplies laboratory chemicals across Europe. Due to its explosive and toxic nature, purchase requires compliance with regulatory requirements and may need special authorization. OYSI can provide guidance on regulatory compliance, proper documentation, and safe handling procedures. Contact OYSI directly to discuss availability, regulatory requirements, and appropriate packaging for your specific research needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.