Potassium hydrogen selenite

HKO3Se

potassium hydrogen selenite

CAS10431-47-7

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Identification

CAS Number
10431-47-7
EC Number
233-909-8
UN Number
2630
Index Number
034-002-00-8
PubChem CID
23677934

Physical-chemical properties

Molecular Formula
HKO3Se
Molar Mass
167.08 g/mol
IUPAC Name
potassium hydrogen selenite

Chemical Identifiers

InChI
InChI=1S/K.H2O3Se/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-1
InChI Key
CRQUBUILMSLSHI-UHFFFAOYSA-M

Overview

Potassium hydrogen selenite (CAS 10431-47-7) is an inorganic selenium compound with oxidizing properties and moderate water solubility. This selenium-containing salt represents an important intermediate compound in selenium chemistry, combining potassium with selenious acid in a 1:1 stoichiometric ratio. With its molecular formula HKO3Se and molecular weight of 167.08 g/mol, potassium hydrogen selenite exhibits distinct chemical behavior compared to other selenium compounds. The compound's classification under ADR Class 6.1 reflects the inherent toxicity associated with selenium-containing materials, requiring careful handling protocols despite the absence of specific GHS pictogram requirements. Potassium hydrogen selenite demonstrates moderate solubility in water, forming slightly acidic solutions due to the presence of the hydrogen selenite ion. The compound exhibits typical properties of selenite salts, including susceptibility to reduction reactions and the ability to act as an oxidizing agent under specific conditions. Its crystalline structure and stability make it suitable for various technical applications where controlled selenium content is required. Industrial applications include its use as a selenium source in glass manufacturing, where it provides controlled decolorization and optical properties similar to other selenium compounds. The compound also finds application in specialized chemical synthesis processes and as an analytical reagent. In comparison to related nitro-aromatic compounds like 4-nitroaniline or 4-nitrophenol, potassium hydrogen selenite offers unique selenium-based chemistry for applications requiring inorganic selenium sources rather than organic nitrogen compounds. Safety protocols must emphasize protection against selenium exposure, including appropriate ventilation and personal protective equipment during handling and storage operations. OYSI maintains reliable supply chains for potassium hydrogen selenite to support European industrial customers requiring consistent quality selenium compounds.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2630
ADR Class6.1
Packing GroupI
Tunnel CodeC/E
Proper Shipping NameKaliumselenit
Marine PollutantNo

Frequently Asked Questions

What is potassium hydrogen selenite?

Potassium hydrogen selenite is an inorganic selenium compound with the chemical formula HKO3Se and CAS number 10431-47-7. This chemical has a molecular weight of 167.08 g/mol and belongs to the selenite family of compounds. It contains selenium in its +4 oxidation state combined with potassium and hydrogen. The compound is primarily used in specialized industrial applications and research settings where selenium compounds are required.

What are the physicochemical properties of potassium hydrogen selenite?

Potassium hydrogen selenite is typically a crystalline solid at room temperature with a molecular weight of 167.08 g/mol. The compound is generally water-soluble due to its ionic nature, forming clear solutions when dissolved. Like most selenite compounds, it appears as white to off-white crystals or powder. The substance is stable under normal conditions but should be protected from strong acids and reducing agents that could alter its chemical structure.

What is potassium hydrogen selenite used for?

Potassium hydrogen selenite is primarily used in analytical chemistry applications and as a selenium source in specialized industrial processes. It serves as a reagent in laboratory synthesis and research applications involving selenium chemistry. The compound may also be utilized in the production of other selenium compounds and in certain metallurgical processes where controlled selenium addition is required. Its applications are typically limited to professional and industrial settings due to selenium's specific properties.

How to handle potassium hydrogen selenite safely?

Potassium hydrogen selenite should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to prevent inhalation of dust particles. Avoid generating dust during handling and use proper weighing techniques. Wash hands thoroughly after handling and avoid eating, drinking, or smoking in work areas. Store away from incompatible materials and follow standard laboratory safety protocols for handling selenium compounds.

How to store potassium hydrogen selenite correctly?

Potassium hydrogen selenite should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from direct sunlight and heat sources. Keep containers properly labeled and store away from strong acids, reducing agents, and incompatible materials. The storage area should be secure and accessible only to trained personnel. Maintain stable temperature conditions and protect from moisture to prevent degradation. Regular inspection of container integrity is recommended to ensure proper containment.

What to do in case of contact with potassium hydrogen selenite?

In case of skin contact with potassium hydrogen selenite, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, rinse immediately with clean water for at least 15 minutes and seek medical attention. In case of inhalation, move to fresh air immediately. If ingested, rinse mouth with water and seek immediate medical attention. Do not induce vomiting unless directed by medical personnel. Always consult a physician in case of exposure.

How to dispose of potassium hydrogen selenite appropriately?

Potassium hydrogen selenite must be disposed of as hazardous chemical waste according to local and national regulations. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never dispose of selenium compounds through regular waste streams or sewage systems. Collect waste in appropriate containers, properly labeled with contents and hazard information. Small laboratory quantities should be accumulated and disposed of through institutional hazardous waste programs. Always follow local environmental regulations and waste management guidelines.

How to transport potassium hydrogen selenite?

Potassium hydrogen selenite is classified under ADR Class 6.1 (Toxic substances), Group I, indicating high toxicity for transport purposes. It must be packaged in UN-approved containers with proper labeling and documentation. Transport requires appropriate hazardous materials documentation and trained personnel. Vehicles must display proper placarding and emergency information. Ensure containers are securely fastened and protected from damage during transport. Follow all applicable dangerous goods regulations for road, rail, or air transport as required.

Is potassium hydrogen selenite subject to specific regulations?

Potassium hydrogen selenite is subject to various chemical safety regulations including REACH registration requirements in the European Union. It falls under CLP (Classification, Labelling and Packaging) regulations for hazard communication. The substance is not currently listed as a Substance of Very High Concern (SVHC) under REACH. However, as a selenium compound, it may be subject to specific national restrictions and workplace exposure limits. Always check current regulatory status and comply with local chemical safety legislation.

Where to buy potassium hydrogen selenite in Europe?

Potassium hydrogen selenite is available through OYSI, a European distributor of technical chemicals serving various industries across Europe. OYSI provides reliable supply chains and technical support for selenium compounds and other specialty chemicals. As a professional chemical distributor, OYSI ensures proper packaging, documentation, and regulatory compliance for hazardous materials. Contact OYSI directly for availability, specifications, and delivery options to your specific European location while ensuring all regulatory requirements are met.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.