Disodium;hexafluorosilicon(2-)

F6Na2Si

disodium;hexafluorosilicon(2-)

CAS16893-85-9
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
16893-85-9
EC Number
240-934-8
UN Number
2674
Index Number
009-012-00-0
PubChem CID
28127

Physical-chemical properties

Molecular Formula
F6Na2Si
Molar Mass
188.06 g/mol
IUPAC Name
disodium;hexafluorosilicon(2-)

Chemical Identifiers

InChI
InChI=1S/F6Si.2Na/c1-7(2,3,4,5)6;;/q-2;2*+1
InChI Key
TWGUZEUZLCYTCG-UHFFFAOYSA-N

Overview

Disodium hexafluorosilicate (CAS 16893-85-9) is an inorganic fluorosilicate salt with high solubility and significant toxicological properties requiring careful handling protocols. This crystalline compound, also known by its IUPAC designation disodium;hexafluorosilicon(2-), represents a critical industrial chemical in the fluorosilicate family. With the molecular formula F6Na2Si and a molecular weight of 188.055 g/mol, this white crystalline solid demonstrates excellent water solubility, making it valuable for various aqueous applications. The compound's structure consists of a hexafluorosilicate anion paired with two sodium cations, creating a stable ionic framework that exhibits predictable chemical behavior under standard conditions. Safety considerations are paramount when handling disodium hexafluorosilicate, as evidenced by its classification under Acute Toxicity Category 3 across multiple exposure routes. The substance carries the GHS06 pictogram and "Danger" signal word, indicating serious health hazards that require appropriate personal protective equipment and ventilation systems. Its ADR Class 6.1 classification further emphasizes the need for specialized transport and storage protocols to ensure worker safety and regulatory compliance. Industrial applications include water fluoridation processes, where it serves as a controlled fluoride source, and specialized chemical synthesis where fluorosilicate chemistry is required. The compound also finds use in certain metal surface treatment applications, offering advantages over simpler fluoride compounds like azanium fluoride due to its enhanced stability and controlled release characteristics. Unlike more complex organic compounds such as 1,1-dichloro-1-nitroethane, disodium hexafluorosilicate provides straightforward inorganic chemistry with predictable reaction pathways. OYSI maintains reliable supply chains for disodium hexafluorosilicate, ensuring consistent availability for European industrial customers requiring this specialized fluorosilicate compound.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2674
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameNatriumfluorosilicat
Marine PollutantNo

Frequently Asked Questions

What is disodium hexafluorosilicate?

Disodium hexafluorosilicate is an inorganic chemical compound with the molecular formula F6Na2Si and CAS number 16893-85-9. This substance has a molecular weight of 188.055 g/mol and belongs to the fluorosilicate family. It is classified as a toxic substance under the GHS system with Acute Toxicity Category 3 classification across multiple exposure routes, requiring careful handling and appropriate safety measures in industrial applications.

What are the physicochemical properties of disodium hexafluorosilicate?

Disodium hexafluorosilicate is typically a white crystalline solid at room temperature with good water solubility. As a fluorosilicate compound, it contains six fluorine atoms bound to a silicon center with two sodium cations balancing the charge. The substance is stable under normal conditions but may release toxic fluoride compounds when heated or in contact with acids. Its ionic nature makes it highly soluble in polar solvents like water.

What is disodium hexafluorosilicate used for?

Disodium hexafluorosilicate is primarily used in industrial applications including water fluoridation processes, metal surface treatment, and as a component in specialized chemical formulations. It serves as a source of fluoride ions in various industrial processes and can be used in the production of other fluorine-containing compounds. The substance also finds applications in certain glass etching processes and specialized cleaning formulations where controlled fluoride release is required.

How to handle disodium hexafluorosilicate safely?

Disodium hexafluorosilicate requires careful handling due to its Acute Toxicity Category 3 classification and GHS06 pictogram designation. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when handling this substance. Work should be conducted in well-ventilated areas or under local exhaust ventilation. Avoid contact with skin, eyes, and respiratory system, and ensure emergency procedures are readily available.

How to store disodium hexafluorosilicate correctly?

Disodium hexafluorosilicate should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from incompatible materials. Keep containers away from heat sources and direct sunlight. The storage area should be equipped with appropriate spill containment measures and emergency equipment. Ensure proper labeling with hazard identification and maintain an inventory system. Store separately from strong acids and oxidizing agents to prevent dangerous reactions.

What to do in case of contact with disodium hexafluorosilicate?

In case of skin contact with disodium hexafluorosilicate, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician and provide the safety data sheet.

How to dispose of disodium hexafluorosilicate appropriately?

Disodium hexafluorosilicate must be disposed of as hazardous waste in accordance with local, national, and international regulations. Contact licensed waste disposal companies specialized in handling toxic chemical substances. Do not discharge into sewers, waterways, or soil. Contaminated packaging should also be treated as hazardous waste. Ensure proper documentation and tracking of waste disposal activities. Consider neutralization or treatment options where appropriate and legally permitted.

How to transport disodium hexafluorosilicate?

Disodium hexafluorosilicate is classified under ADR Class 6.1 (Toxic substances) Packing Group III for transportation purposes. It requires appropriate hazardous goods packaging, labeling, and documentation for road transport. Vehicles must carry proper placards and emergency response information. Drivers need ADR certification for Class 6.1 substances. Ensure compliance with international transport regulations including proper packaging instructions and quantity limitations for different transport modes.

Is disodium hexafluorosilicate subject to specific regulations?

Disodium hexafluorosilicate is subject to various regulatory frameworks including REACH registration requirements in Europe and CLP classification as Acute Tox. 3 with Danger signal word. The substance is not currently listed as a Substance of Very High Concern (SVHC). Compliance with occupational exposure limits, proper labeling according to GHS standards, and safety data sheet provisions are mandatory. Users must ensure regulatory compliance in their specific jurisdictions and applications.

Where to buy disodium hexafluorosilicate in Europe?

Disodium hexafluorosilicate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to industrial customers across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures quality standards and can provide technical support for industrial applications. Contact OYSI directly for availability, specifications, and delivery options to your location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.