Potassium bromate
BrKO3
potassium bromate
Consulting for Potassium bromate
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Identification
- CAS Number
- 7758-01-2
- EC Number
- 231-829-8
- UN Number
- 1484
- Index Number
- 035-003-00-6
- PubChem CID
- 23673461
Physical-chemical properties
- Molecular Formula
- BrKO3
- Molar Mass
- 167.00 g/mol
- IUPAC Name
- potassium bromate
Chemical Identifiers
- InChI
- InChI=1S/BrHO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
- InChI Key
- OCATYIAKPYKMPG-UHFFFAOYSA-M
Overview
Potassium bromate (CAS 7758-01-2) is an inorganic oxidizing salt with strong oxidative properties and significant toxicity concerns. This white crystalline compound serves as a powerful oxidizing agent in various industrial applications, though its use has become increasingly regulated due to serious health and safety considerations. With the molecular formula BrKO3 and a molecular weight of 167 g/mol, potassium bromate demonstrates high solubility in water and exhibits characteristic properties of bromate salts. The substance is classified under multiple hazard categories, including Oxidizing Solid Category 1, Carcinogen Category 1B, and Acute Toxicity Category 3, requiring careful handling protocols and specialized safety measures. The compound's oxidizing nature makes it chemically reactive with organic materials and reducing agents, potentially leading to fire or explosion hazards when improperly stored or handled. Its carcinogenic classification stems from extensive toxicological studies indicating potential cancer risks, particularly affecting the kidneys and thyroid. These safety concerns have led to strict regulatory oversight in many jurisdictions, with some countries implementing complete bans on certain applications. Industrially, potassium bromate finds application primarily in analytical chemistry as a volumetric standard, in certain specialized oxidation processes, and historically in flour treatment, though the latter use has been largely discontinued due to health concerns. Unlike related oxidizing compounds such as trioxochromium, potassium bromate offers specific advantages in controlled laboratory environments where precise oxidation reactions are required. OYSI provides potassium bromate to qualified industrial customers with comprehensive safety documentation and regulatory compliance support for legitimate technical applications.
Safety & Classification
Ox. Sol. 1; Carc. 1B; Acute Tox. 3 *
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1484 |
| ADR Class | 5.1 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Kaliumbromat |
| Marine Pollutant | No |
Frequently Asked Questions
What is potassium bromate?
Potassium bromate is an inorganic oxidizing compound with the chemical formula BrKO3 and CAS number 7758-01-2. This white crystalline salt has a molecular weight of 167 g/mol and serves primarily as a powerful oxidizing agent in various industrial applications. It is classified as a dangerous substance due to its oxidizing properties, acute toxicity, and carcinogenic potential, requiring careful handling and strict safety measures in professional environments.
What are the physicochemical properties of potassium bromate?
Potassium bromate is a white crystalline solid that is highly soluble in water, forming clear solutions. It is odorless and stable under normal conditions but decomposes when heated, releasing oxygen and forming potassium bromide. As a strong oxidizing agent, it readily reacts with organic materials and reducing substances. The compound has good thermal stability at room temperature but becomes increasingly reactive at elevated temperatures, making proper storage conditions essential.
What is potassium bromate used for?
Potassium bromate is primarily used as an oxidizing agent in analytical chemistry and laboratory applications. It serves as a reagent in volumetric analysis and redox titrations. In industrial settings, it functions as an oxidizer in various chemical processes and synthesis reactions. Due to its strong oxidizing properties, it is also employed in specialized manufacturing processes where controlled oxidation is required, though its use is restricted in many applications due to safety concerns.
How to handle potassium bromate safely?
Potassium bromate requires strict safety measures including wearing protective gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or under fume hoods to avoid inhalation of dust particles. Keep the substance away from heat sources, combustible materials, and reducing agents. Use non-sparking tools and ensure proper grounding to prevent static electricity buildup. Always wash hands thoroughly after handling and never eat, drink, or smoke in work areas.
How to store potassium bromate correctly?
Potassium bromate must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed and separate from incompatible materials such as organic compounds, reducing agents, and combustible substances. Storage areas should be equipped with appropriate fire suppression systems and emergency equipment. Ensure proper labeling and maintain inventory records. Store in original containers or approved alternatives, and regularly inspect containers for damage or deterioration.
What to do in case of contact with potassium bromate?
Potassium bromate exposure requires immediate action: for skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes while holding eyelids open. If inhaled, move the person to fresh air and monitor breathing. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any exposure and provide the safety data sheet to medical personnel.
How to dispose of potassium bromate properly?
Potassium bromate disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. Never dispose of it through regular waste streams or pour it down drains. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities can be neutralized by qualified personnel following approved procedures, but this should only be done by trained professionals. Maintain proper documentation of all disposal activities and ensure containers are properly labeled before disposal.
How to transport potassium bromate?
Potassium bromate is classified under ADR as Class 5.1 (Oxidizing substances) Packing Group II, requiring specialized transport procedures. It must be packaged in UN-approved containers with proper hazard labels and documentation. Transport vehicles need appropriate placarding and drivers require ADR certification. The substance cannot be transported with incompatible materials and requires proper segregation. Emergency response information must accompany shipments, and transport should follow designated routes when required by local regulations.
Is potassium bromate subject to specific regulations?
Potassium bromate is subject to strict European regulations under REACH and CLP due to its classification as Carcinogenic 1B, Acute Toxic 3, and Oxidizing Solid 1. It requires safety data sheets, proper labeling with danger pictograms (GHS03, GHS06, GHS08), and the signal word "Danger." Professional users must implement risk management measures and may need authorization for certain uses. Its use is restricted or banned in food applications in many countries due to carcinogenic properties.
Where to buy potassium bromate in Europe?
Potassium bromate is available through OYSI, a European distributor of technical chemicals serving industrial and professional customers. As a regulated substance, purchases typically require documentation of intended use and compliance with safety regulations. OYSI provides proper packaging, labeling, and documentation to ensure regulatory compliance throughout Europe. Professional buyers should verify local restrictions and requirements before ordering, as availability may vary by country due to regulatory limitations on this hazardous substance.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.