Potassium boranuide

BH4K

potassium boranuide

CAS13762-51-1

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Identification

CAS Number
13762-51-1
EC Number
237-360-5
UN Number
1870
PubChem CID
4192641

Physical-chemical properties

Molecular Formula
BH4K
Molar Mass
53.94 g/mol
IUPAC Name
potassium boranuide

Chemical Identifiers

InChI
InChI=1S/BH4.K/h1H4;/q-1;+1
InChI Key
ICRGAIPBTSPUEX-UHFFFAOYSA-N

Overview

Potassium boranuide (CAS 13762-51-1) is an inorganic borohydride compound with strong reducing properties and water-reactive characteristics. This chemical compound, with the molecular formula BH4K and a molecular weight of 53.94 g/mol, represents an important member of the alkali metal borohydride family. Potassium boranuide appears as a white crystalline solid that demonstrates significant reactivity with water and protic solvents, releasing hydrogen gas upon contact. The compound's classification under ADR Class 4.3 indicates its water-reactive nature, requiring careful handling and storage under anhydrous conditions to maintain stability and prevent unwanted reactions. The reducing capabilities of potassium boranuide make it particularly valuable in synthetic chemistry applications. Its reactivity profile differs from related compounds like sodium borohydride, offering chemists alternative selectivity and reaction conditions for specific transformations. The compound must be stored in moisture-free environments, typically under inert atmosphere conditions, to prevent decomposition and maintain its chemical integrity. Key industrial applications include its use as a reducing agent in pharmaceutical intermediate synthesis, where its selective reduction properties enable the formation of specific functional groups. The compound also finds application in metal processing operations, particularly in electroless plating processes where controlled hydrogen generation is beneficial. Additionally, potassium boranuide serves as a hydrogen source in specialized chemical reactions and materials science research. Like other borohydrides including alumane compounds, potassium boranuide requires specialized handling protocols due to its reactive nature. Proper safety equipment and storage facilities are essential for safe utilization in industrial processes. OYSI supplies potassium boranuide to support various industrial and research applications across European markets.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1870
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameKaliumborhydrid
Marine PollutantNo

Frequently Asked Questions

What is potassium boranuide?

Potassium boranuide is an inorganic chemical compound with the molecular formula BH4K and CAS number 13762-51-1. This borohydride salt consists of potassium cations and tetrahedral borohydride anions, making it a member of the alkali metal borohydrides family. With a molecular weight of 53.94 g/mol, it serves as an important reducing agent in various chemical applications and synthetic processes.

What are the physicochemical properties of potassium boranuide?

Potassium boranuide is typically a white crystalline solid at room temperature with high hygroscopic properties, readily absorbing moisture from air. It demonstrates excellent solubility in polar solvents, particularly water and alcohols, forming clear solutions. The compound is generally odorless but may decompose upon exposure to moisture or acids, releasing hydrogen gas. Its ionic structure contributes to its stability under dry conditions.

What is potassium boranuide used for?

Potassium boranuide serves primarily as a selective reducing agent in organic synthesis, particularly for converting aldehydes, ketones, and other carbonyl compounds to alcohols. It finds applications in pharmaceutical manufacturing, fine chemical synthesis, and research laboratories. The compound is also utilized in metal processing for reducing metal salts and in specialized analytical procedures where mild reducing conditions are required.

How to handle potassium boranuide safely?

Potassium boranuide requires careful handling using appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation of any dust or decomposition products. Avoid contact with acids, oxidizing agents, and moisture during handling. Use non-sparking tools and ensure proper grounding to prevent static discharge.

How to store potassium boranuide correctly?

Potassium boranuide must be stored in tightly sealed containers in a cool, dry environment away from moisture, heat sources, and incompatible materials. Keep containers in a well-ventilated area, separated from acids, oxidizing agents, and halogenated compounds. Storage areas should be equipped with appropriate fire suppression systems and maintained at stable temperatures to prevent decomposition and ensure product stability.

What to do in case of contact with potassium boranuide?

Skin contact with potassium boranuide requires immediate removal of contaminated clothing and thorough washing of affected areas with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical care.

How to dispose of potassium boranuide properly?

Potassium boranuide disposal must comply with local and national hazardous waste regulations as it is classified as dangerous goods. The compound should be collected in appropriate containers and disposed of through licensed chemical waste management companies. Never dispose of it in regular waste streams or pour it down drains. Consider neutralization procedures under controlled conditions before final disposal when permitted by regulations.

How to transport potassium boranuide?

Potassium boranuide is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating high danger level. Transportation requires UN-approved packaging, proper labeling with Class 4.3 hazard labels, and appropriate shipping documentation. Only authorized carriers trained in dangerous goods transport should handle shipments, following strict ADR regulations for safe transport across European roads.

Is potassium boranuide subject to specific regulations?

Potassium boranuide is regulated under European REACH legislation requiring registration for commercial use, though it is not classified as a Substance of Very High Concern (SVHC). The compound must comply with CLP regulation for classification, labeling, and packaging. As a dangerous good under ADR Class 4.3, it requires specific transport documentation and handling procedures. Users must follow applicable workplace safety regulations.

Where to buy potassium boranuide in Europe?

Potassium boranuide is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across Europe. OYSI provides reliable supply chains and technical support for this reducing agent. Due to its classification as dangerous goods (ADR 4.3), purchase requires proper documentation and compliance with transport regulations. Contact OYSI for availability, specifications, and delivery arrangements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.