Pentyl formate

C6H12O2

pentyl formate

CAS638-49-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
638-49-3
EC Number
211-340-6
UN Number
1109
Index Number
607-696-00-0
PubChem CID
12529

Physical-chemical properties

Molecular Formula
C6H12O2
Molar Mass
116.16 g/mol
IUPAC Name
pentyl formate

Chemical Identifiers

InChI
InChI=1S/C6H12O2/c1-2-3-4-5-8-6-7/h6H,2-5H2,1H3
InChI Key
DIQMPQMYFZXDAX-UHFFFAOYSA-N

Overview

Pentyl formate (CAS 638-49-3) is an aliphatic ester compound characterized by its fruity aroma and moderate flammability properties. This organic ester, with the molecular formula C6H12O2 and EC number 211-340-6, represents a valuable chemical intermediate in various industrial applications. Pentyl formate belongs to the formate ester family, sharing structural similarities with other industrial compounds such as methyl 2-hydroxypropanoate, though it exhibits distinct volatility and solubility characteristics that make it particularly suitable for specific technical applications. The compound presents as a colorless liquid with a molecular weight of 116.16 g/mol, demonstrating typical ester properties including moderate polarity and characteristic fruity odor notes. From a safety perspective, pentyl formate is classified under GHS regulations with warning pictograms GHS02 and GHS07, indicating flammable liquid category 3, eye irritation category 2, and specific target organ toxicity (single exposure) category 3. Its ADR classification as class 3 material requires appropriate handling protocols for transportation and storage. Industrial applications of pentyl formate primarily include its use as a solvent in coating formulations, where its controlled evaporation rate and compatibility with various resin systems prove advantageous. The compound also serves as a chemical intermediate in organic synthesis processes and finds application in specialty formulations requiring specific solvency characteristics. Unlike related ketone compounds such as 5-methylheptan-3-one, pentyl formate offers unique ester functionality that enables specific reaction pathways in synthetic chemistry. OYSI maintains technical-grade pentyl formate in its European distribution network, supporting industrial customers with reliable supply and comprehensive safety documentation for this specialized chemical intermediate.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; STOT SE 3; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H335

May cause respiratory irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1109
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Namen-Amylformiat
Marine PollutantNo

Frequently Asked Questions

What is pentyl formate?

Pentyl formate is an organic ester compound with the molecular formula C6H12O2 and CAS number 638-49-3. It belongs to the formate ester family, formed by the condensation of formic acid and pentyl alcohol. With a molecular weight of 116.16 g/mol, this colorless liquid is classified as a flammable substance and mild irritant under GHS regulations, requiring careful handling in industrial applications.

What are the physicochemical properties of pentyl formate?

Pentyl formate is a colorless liquid at room temperature with a characteristic fruity, banana-like odor typical of formate esters. It has limited solubility in water but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound has a relatively low boiling point and high volatility, contributing to its flammable nature and classification as Flam. Liq. 3.

What is pentyl formate used for?

Pentyl formate is primarily used as a flavoring agent in the food and beverage industry due to its pleasant fruity aroma. It serves as a solvent in various industrial processes, particularly in the production of lacquers, paints, and coatings. Additionally, it finds application in the fragrance industry for perfumes and cosmetics, and as an intermediate in organic synthesis reactions.

How to handle pentyl formate safely?

Pentyl formate requires careful handling due to its flammable nature and irritant properties. Workers should wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation and avoid ignition sources. Handle away from heat, sparks, and open flames. The compound may cause eye irritation and narcotic effects, requiring immediate attention in case of exposure.

How to store pentyl formate correctly?

Pentyl formate should be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use appropriate containers made of compatible materials and ensure proper labeling with GHS02 and GHS07 pictograms. Store separately from oxidizing agents and strong bases. Maintain storage temperature below 25°C and implement proper fire prevention measures in storage areas.

What to do in case of contact with pentyl formate?

Pentyl formate exposure requires immediate first aid measures. In case of eye contact, flush immediately with plenty of water for at least 15 minutes and seek medical attention due to its Eye Irrit. 2 classification. For skin contact, wash thoroughly with soap and water. If inhaled, move to fresh air immediately as it may cause narcotic effects (STOT SE 3). Remove contaminated clothing and seek medical advice if symptoms persist.

How to dispose of pentyl formate properly?

Pentyl formate disposal must comply with local and European waste regulations as a flammable and hazardous substance. It cannot be disposed of in regular waste streams or poured down drains. Contact licensed waste disposal companies for proper treatment, which may include incineration at authorized facilities. Small quantities should be collected in appropriate containers and labeled clearly for hazardous waste pickup.

How to transport pentyl formate?

Pentyl formate is classified under ADR as Class 3 (flammable liquids), Packing Group III for transportation purposes. It requires appropriate packaging, labeling, and documentation according to dangerous goods regulations. Transport vehicles must be equipped with proper safety equipment and drivers need ADR certification. Packages must display the flammable liquid hazard label and proper shipping name during transport across European roads.

Is pentyl formate subject to specific regulations?

Pentyl formate is regulated under European REACH and CLP regulations, requiring proper registration, classification, and labeling. It displays Warning signal word with GHS02 and GHS07 pictograms due to its flammable and irritant properties. The substance is not classified as SVHC (Substance of Very High Concern), but still requires compliance with occupational safety standards and proper risk assessment in workplace environments.

Where to buy pentyl formate in Europe?

Pentyl formate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply of pentyl formate with proper documentation, safety data sheets, and regulatory compliance for industrial customers across Europe. As a professional chemical distributor, OYSI ensures quality standards and proper packaging for safe delivery to various industries requiring this specialty ester compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.