Nickel(2+) sulfite

NiO3S

nickel(2+) sulfite

CAS7757-95-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7757-95-1
EC Number
231-827-7
UN Number
3077
Index Number
028-055-00-6
PubChem CID
14029754

Physical-chemical properties

Molecular Formula
NiO3S
Molar Mass
138.76 g/mol
IUPAC Name
nickel(2+) sulfite

Chemical Identifiers

InChI
InChI=1S/Ni.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
InChI Key
LONQOCRNVIZRSA-UHFFFAOYSA-L

Overview

Nickel(2+) sulfite (CAS 7757-95-1) is an inorganic nickel compound with significant industrial applications and notable health hazards requiring careful handling protocols. This chemical substance, also known by its EC number 231-827-7 and molecular formula NiO3S, represents a critical component in various industrial processes where nickel chemistry plays an essential role. With a molecular weight of 138.76 g/mol, nickel(2+) sulfite exhibits properties characteristic of transition metal sulfites, combining the catalytic potential of nickel with the reducing capabilities of sulfite ions. The compound presents serious safety considerations, classified under multiple hazard categories including carcinogenicity (Carc. 1A), specific target organ toxicity (STOT RE 1), and both respiratory and skin sensitization (Resp. Sens. 1; Skin Sens. 1). The GHS08 and GHS09 pictograms indicate significant health hazards and environmental dangers, requiring stringent handling procedures and protective equipment. Its classification as ADR Class 9 miscellaneous dangerous goods necessitates specialized transport protocols. Industrial applications of nickel(2+) sulfite primarily include electroplating processes, where it serves as a nickel source for surface coating applications, and as an intermediate in the production of other nickel compounds. The chemical industry also utilizes this compound in specialized catalytic processes and as a precursor for advanced materials synthesis. Like other nickel compounds such as nickel(2+) dicyanide, it requires careful environmental management due to its aquatic toxicity classification. OYSI maintains availability of nickel(2+) sulfite through our European distribution network, ensuring compliance with all relevant chemical regulations and safety standards for professional industrial customers.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-sulfit
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) sulfite?

Nickel(2+) sulfite is an inorganic chemical compound with the molecular formula NiO3S and CAS number 7757-95-1. This nickel salt has a molecular weight of 138.76 g/mol and is classified as a highly hazardous substance. It is categorized as a Category 1A carcinogen and causes specific target organ toxicity through repeated exposure. The compound also acts as a respiratory and skin sensitizer, posing significant health risks upon exposure.

What are the physicochemical properties of nickel(2+) sulfite?

Nickel(2+) sulfite is typically a solid crystalline compound at room temperature with characteristic properties of nickel salts. The substance exhibits the typical coloration associated with nickel compounds, often appearing as a colored crystalline solid. Its molecular formula NiO3S indicates the presence of nickel in the +2 oxidation state bound to a sulfite group. Specific physical properties such as melting point, density, and solubility depend on the hydration state and crystal structure.

What is nickel(2+) sulfite used for?

Nickel(2+) sulfite is primarily used in specialized industrial applications where nickel compounds are required. It serves as a precursor in the synthesis of other nickel compounds and may be employed in electroplating processes, catalyst preparation, and specialized chemical manufacturing. Due to its hazardous classification as a carcinogen and sensitizer, its use is strictly controlled and limited to professional applications with appropriate safety measures and regulatory compliance.

How to handle nickel(2+) sulfite safely?

Nickel(2+) sulfite requires extreme caution during handling due to its carcinogenic and sensitizing properties. Personnel must wear appropriate personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems. Skin and eye contact must be avoided at all costs, and strict hygiene measures should be implemented to prevent cross-contamination and accidental exposure.

How to store nickel(2+) sulfite correctly?

Nickel(2+) sulfite must be stored in a secure, well-ventilated area away from incompatible materials and moisture sources. The storage area should be restricted to authorized personnel only due to the substance's carcinogenic properties. Containers must be properly labeled and sealed to prevent exposure and contamination. Storage temperatures should remain stable, and the area should be equipped with appropriate spill containment measures and emergency response equipment.

What to do in case of contact with nickel(2+) sulfite?

Immediate action is critical following contact with nickel(2+) sulfite due to its hazardous nature. For skin contact, remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Seek immediate medical attention in all cases of exposure, informing medical personnel of the substance's carcinogenic properties.

How to dispose of nickel(2+) sulfite properly?

Nickel(2+) sulfite must be disposed of as hazardous waste in accordance with local and European regulations due to its carcinogenic properties and environmental hazards. The substance cannot be discharged into sewage systems or the environment. Disposal must be carried out by licensed hazardous waste disposal companies following strict protocols. All contaminated materials, including packaging and protective equipment, must also be treated as hazardous waste and disposed of accordingly.

How to transport nickel(2+) sulfite?

Nickel(2+) sulfite is classified under ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transport purposes. Transportation requires appropriate packaging, labeling with GHS08 and GHS09 pictograms, and documentation indicating the 'Danger' signal word. Vehicles must comply with ADR regulations for Class 9 substances, and drivers must be trained in hazardous materials handling. Proper emergency response information must accompany shipments during transport.

Is nickel(2+) sulfite subject to special regulations?

Nickel(2+) sulfite is subject to extensive regulatory oversight under European legislation including REACH and CLP regulations due to its classification as a Category 1A carcinogen. Its use is restricted under various industrial safety directives, and employers must implement strict occupational exposure controls. The substance requires safety data sheets, hazard communication, and may be subject to authorization requirements. Environmental regulations also apply due to its aquatic toxicity classification.

Where to buy nickel(2+) sulfite in Europe?

Nickel(2+) sulfite is available through specialized chemical distributors in Europe, including OYSI, which provides high-quality chemicals to professional and industrial customers. Due to its hazardous classification, purchase is typically restricted to qualified businesses with appropriate handling capabilities and regulatory compliance. Buyers must demonstrate proper storage facilities, trained personnel, and compliance with occupational safety and environmental regulations before procurement is possible.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.