Nickel(2+) sulfite

NiO3S

nickel(2+) sulfite

CAS7757-95-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7757-95-1
EC Number
231-827-7
UN Number
3077
Index Number
028-055-00-6
PubChem CID
14029754

Physical-chemical properties

Molecular Formula
NiO3S
Molar Mass
138.76 g/mol
IUPAC Name
nickel(2+) sulfite

Chemical Identifiers

InChI
InChI=1S/Ni.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
InChI Key
LONQOCRNVIZRSA-UHFFFAOYSA-L

Overview

Nickel(2+) sulfite (CAS 7757-95-1) is an inorganic nickel salt compound with significant industrial applications and notable safety considerations due to its carcinogenic properties. This chemical compound, also identified by EC number 231-827-7, consists of nickel in its divalent oxidation state combined with sulfite ions, resulting in the molecular formula NiO3S and a molecular weight of 138.76 g/mol. As a member of the nickel compound family, it shares certain characteristics with related substances such as nickel(2+) dicyanide, though each exhibits distinct properties and applications based on their specific chemical structures. The compound presents significant safety challenges, classified under multiple hazard categories including carcinogenicity (Carc. 1A), specific target organ toxicity with repeated exposure (STOT RE 1), and both respiratory and skin sensitization (Resp. Sens. 1, Skin Sens. 1). Additionally, it poses environmental risks with acute and chronic aquatic toxicity classifications. These properties necessitate the "Danger" signal word and require GHS08 (health hazard) and GHS09 (environmental hazard) pictograms on safety documentation. For transportation purposes, nickel(2+) sulfite falls under ADR class 9 miscellaneous dangerous substances. Industrial applications of this compound primarily include catalytic processes, electroplating operations, and specialized chemical synthesis where nickel's catalytic properties are essential. It also finds use in certain metallurgical applications and as an intermediate in the production of other nickel-containing compounds. OYSI maintains availability of nickel(2+) sulfite for qualified industrial customers, ensuring proper handling protocols and regulatory compliance throughout the European market.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-sulfit
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) sulfite?

Nickel(2+) sulfite is an inorganic chemical compound with the molecular formula NiO3S and CAS number 7757-95-1. This nickel salt has a molecular weight of 138.76 g/mol and is classified as a highly hazardous substance due to its carcinogenic properties, respiratory and skin sensitization potential, and environmental toxicity. It is regulated under multiple safety classifications including Category 1A carcinogen status.

What are the physicochemical properties of nickel(2+) sulfite?

Nickel(2+) sulfite is typically a solid crystalline compound at room temperature. As a nickel salt, it generally exhibits characteristic coloration ranging from green to yellow-green, though specific physical properties may vary depending on hydration state and crystalline form. The compound has limited water solubility and should be handled as a fine powder or crystalline material with appropriate dust control measures.

What is nickel(2+) sulfite used for?

Nickel(2+) sulfite is primarily used in specialized industrial applications including electroplating processes, catalyst preparation, and chemical synthesis operations. Due to its hazardous classification as a Category 1A carcinogen, its use is strictly controlled and limited to professional industrial settings where appropriate safety measures can be implemented. Applications typically involve metal surface treatment and specialized chemical manufacturing processes.

How to handle nickel(2+) sulfite safely?

Nickel(2+) sulfite requires strict safety protocols due to its carcinogenic and sensitizing properties. Essential personal protective equipment includes respiratory protection (P3 filters), chemical-resistant gloves, protective clothing, and eye protection. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid inhalation, skin contact, and dust generation. Only trained personnel should handle this substance following established occupational safety procedures.

How to store nickel(2+) sulfite correctly?

Nickel(2+) sulfite must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be restricted to authorized personnel only, with appropriate warning signage indicating carcinogenic hazards. Containers should be clearly labeled and stored away from oxidizing agents, acids, and heat sources. Regular inspection of containers for integrity is essential to prevent contamination or exposure.

What to do in case of contact with nickel(2+) sulfite?

Immediate action is required for any contact with nickel(2+) sulfite. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15 minutes. If inhaled, move to fresh air immediately. Seek medical attention promptly in all cases, informing healthcare providers of the carcinogenic nature of the substance.

How to dispose of nickel(2+) sulfite appropriately?

Nickel(2+) sulfite disposal must comply with hazardous waste regulations due to its carcinogenic and environmentally toxic properties. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies experienced in handling carcinogenic materials. All disposal activities must follow local, national, and EU waste regulations, with proper documentation and tracking throughout the disposal process.

How to transport nickel(2+) sulfite?

Nickel(2+) sulfite is classified under ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. Transport requires appropriate UN-specification packaging, proper labeling with GHS08 and GHS09 pictograms, and accompanying transport documentation. Vehicles must comply with ADR requirements for Class 9 substances. Only qualified personnel familiar with dangerous goods transport regulations should handle shipping arrangements.

Is nickel(2+) sulfite subject to specific regulations?

Nickel(2+) sulfite is subject to extensive regulatory oversight under multiple frameworks including REACH, CLP Regulation, and occupational safety directives. As a Category 1A carcinogen, it faces strict workplace exposure limits and may require authorization for certain uses. The substance also falls under environmental protection regulations due to its aquatic toxicity classification. Companies must ensure full compliance with notification, classification, and risk assessment requirements.

Where to buy nickel(2+) sulfite in Europe?

Nickel(2+) sulfite is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous substances. Due to the strict regulatory requirements and safety considerations associated with this carcinogenic compound, procurement should only be conducted through qualified suppliers who can provide proper documentation, safety data sheets, and ensure compliance with all applicable regulations for professional industrial use.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.