Nickel(2+) diperchlorate
Cl2NiO8
nickel(2+) diperchlorate
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Identification
- CAS Number
- 13637-71-3
- EC Number
- 237-124-1
- UN Number
- 3085
- Index Number
- 028-016-00-3
- PubChem CID
- 26158
Physical-chemical properties
- Molecular Formula
- Cl2NiO8
- Molar Mass
- 257.59 g/mol
- IUPAC Name
- nickel(2+) diperchlorate
Chemical Identifiers
- InChI
- InChI=1S/2ClHO4.Ni/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
- InChI Key
- ZLQBNKOPBDZKDP-UHFFFAOYSA-L
Overview
Nickel(2+) diperchlorate (CAS 13637-71-3) is an inorganic oxidizing salt with strong corrosive properties and significant health hazards. This chemical compound, also known by its EC number 237-124-1, represents a highly hazardous nickel-based perchlorate with the molecular formula Cl2NiO8 and a molar mass of 257.59 g/mol. As a member of the perchlorate family, it shares oxidizing characteristics with other metal perchlorates but presents unique toxicological concerns due to its nickel content. The substance exhibits multiple classification hazards including carcinogenicity (Category 1A), mutagenicity (Category 2), and reproductive toxicity (Category 1B), making it one of the most strictly regulated compounds in industrial chemistry. The compound's safety profile demands extreme caution, as indicated by its "Danger" signal word and multiple GHS pictograms including GHS08 (health hazard), GHS05 (corrosion), and GHS09 (environmental hazard). Its classification as ADR Class 5.1 identifies it as an oxidizing substance requiring specialized transport protocols. The material presents respiratory and skin sensitization risks alongside severe target organ toxicity following repeated exposure. Industrial applications of nickel(2+) diperchlorate are primarily limited to specialized electroplating processes and as a catalyst precursor in controlled manufacturing environments. It may also serve in analytical chemistry applications where its unique oxidizing properties are specifically required. Unlike related chromium compounds such as trioxochromium, which find broader industrial use, nickel diperchlorate applications remain highly specialized due to its extreme hazard classification. OYSI maintains availability of this regulated substance for qualified industrial customers meeting strict safety and regulatory compliance requirements.
Safety & Classification
Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Skin Corr. 1B; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing genetic defects.
Causes damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3085 |
| ADR Class | 5.1 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Nickel(II)-perchlorat |
| Marine Pollutant | No |
Frequently Asked Questions
What is nickel(2+) diperchlorate?
Nickel(2+) diperchlorate is an inorganic salt with the chemical formula Cl2NiO8 and CAS number 13637-71-3. This compound consists of a nickel ion in the +2 oxidation state combined with two perchlorate anions. With a molecular weight of 257.59 g/mol, it belongs to the perchlorate family of compounds and is classified as highly hazardous due to its carcinogenic, mutagenic, and reproductive toxicity properties.
What are the physicochemical properties of nickel(2+) diperchlorate?
Nickel(2+) diperchlorate is typically a crystalline solid at room temperature with characteristic green coloration due to the presence of nickel(II) ions. The compound is highly soluble in water and polar solvents. It exhibits oxidizing properties due to the perchlorate groups and has a molecular weight of 257.59 g/mol. The substance is hygroscopic and should be protected from moisture to maintain its stability.
What is nickel(2+) diperchlorate used for?
Nickel(2+) diperchlorate is primarily used as an oxidizing agent in specialized chemical synthesis and analytical chemistry applications. It serves as a nickel source in electroplating processes and catalyst preparation. The compound finds applications in research laboratories for specific chemical reactions requiring both nickel ions and oxidizing properties. Due to its hazardous nature, its use is restricted to professional and industrial settings with appropriate safety measures.
How to handle nickel(2+) diperchlorate safely?
Nickel(2+) diperchlorate requires strict safety protocols including wearing full personal protective equipment: respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted in well-ventilated areas or under fume hoods due to its carcinogenic and respiratory sensitizing properties. Avoid skin contact and inhalation. Personnel should be trained in handling carcinogenic substances and emergency procedures before working with this compound.
How to store nickel(2+) diperchlorate correctly?
Nickel(2+) diperchlorate must be stored in a cool, dry, well-ventilated area away from incompatible materials such as combustible substances, reducing agents, and organic compounds. As a Class 5.1 oxidizing substance, it should be segregated from flammable materials. Use appropriate containers resistant to corrosion and ensure proper labeling. Storage areas should have restricted access and emergency response equipment readily available.
What to do in case of contact with nickel(2+) diperchlorate?
Nickel(2+) diperchlorate contact requires immediate emergency response. For skin contact, remove contaminated clothing and flush with copious amounts of water for at least 15 minutes, then seek medical attention. If inhaled, move to fresh air immediately and seek medical help. For eye contact, rinse thoroughly with water for 15 minutes and get immediate medical attention. Never induce vomiting if ingested. Always seek professional medical advice promptly.
How to dispose of nickel(2+) diperchlorate appropriately?
Nickel(2+) diperchlorate disposal must comply with local and international hazardous waste regulations due to its classification as carcinogenic and environmentally hazardous. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment facilities. Contact authorized waste management companies experienced in handling oxidizing and carcinogenic materials. Neutralization or treatment may be required before final disposal to minimize environmental impact.
How to transport nickel(2+) diperchlorate?
Nickel(2+) diperchlorate is classified under ADR Class 5.1 (oxidizing substances) Packing Group II, requiring specialized transport procedures. It must be packaged in approved containers with proper hazard labels and documentation. Transport vehicles need appropriate placarding and emergency response information. Only trained personnel should handle the transport, and specific routing restrictions may apply. Segregation from incompatible materials during transport is mandatory.
Is nickel(2+) diperchlorate subject to special regulations?
Nickel(2+) diperchlorate is subject to extensive regulatory oversight under REACH, CLP, and national chemical safety regulations due to its classification as Carcinogenic 1A, Mutagenic 2, and Reproductive toxicant 1B. It requires safety data sheets, exposure assessments, and risk management measures. Workplace exposure limits apply, and its use may be restricted in certain applications. Users must comply with occupational health and environmental protection requirements.
Where to buy nickel(2+) diperchlorate in Europe?
Nickel(2+) diperchlorate is available through OYSI, a specialized European distributor of technical chemicals. As a controlled substance due to its hazardous classification, purchase requires verification of legitimate use and compliance with safety regulations. OYSI provides proper documentation, safety data sheets, and technical support for professional customers. Contact OYSI directly to discuss availability, packaging options, and regulatory compliance requirements for your specific application.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.