Naphthalen-1-amine
C10H9N
naphthalen-1-amine
Consulting for Naphthalen-1-amine
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Identification
- CAS Number
- 134-32-7
- EC Number
- 205-138-7
- UN Number
- 2077
- Index Number
- 612-020-00-2
- PubChem CID
- 8640
Physical-chemical properties
- Molecular Formula
- C10H9N
- Molar Mass
- 143.18 g/mol
- IUPAC Name
- naphthalen-1-amine
Chemical Identifiers
- InChI
- InChI=1S/C10H9N/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H,11H2
- InChI Key
- RUFPHBVGCFYCNW-UHFFFAOYSA-N
Overview
Naphthalen-1-amine (CAS 134-32-7) is an aromatic primary amine derived from naphthalene with significant industrial applications in dye and pharmaceutical manufacturing. This organic compound, also known as 1-naphthylamine, represents a crucial intermediate in various chemical synthesis processes. With the molecular formula C10H9N and a molecular weight of 143.18 g/mol, naphthalen-1-amine features a naphthalene ring system substituted with an amino group at the 1-position. This structural arrangement provides unique reactivity patterns that make it valuable in industrial chemistry, particularly in applications requiring aromatic amine functionality. The compound exhibits moderate acute toxicity (Acute Tox. 4) and poses environmental concerns with chronic aquatic toxicity (Aquatic Chronic 2), requiring careful handling protocols in industrial settings. Its GHS07 and GHS09 pictograms indicate both health hazards and environmental risks, while the ADR classification 6.1 designates it as a toxic substance for transportation purposes. These safety considerations necessitate appropriate personal protective equipment and environmental controls during handling and processing. Primary industrial applications include the production of azo dyes, where naphthalen-1-amine serves as a coupling component or diazonium salt precursor. The pharmaceutical industry utilizes this compound as an intermediate in drug synthesis, while the chemical manufacturing sector employs it in producing various specialty chemicals. Unlike related compounds such as (3-methylphenyl) N-methylcarbamate, which finds use in different applications, naphthalen-1-amine's aromatic structure provides distinct advantages in synthetic pathways requiring naphthalene-based intermediates. OYSI maintains reliable supply chains for naphthalen-1-amine, ensuring consistent availability for European industrial customers requiring this essential chemical intermediate.
Safety & Classification
Acute Tox. 4 *; Aquatic Chronic 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2077 |
| ADR Class | 6.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | alpha-Naphthylamin, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is naphthalen-1-amine?
Naphthalen-1-amine is an aromatic amine compound with the chemical formula C10H9N and CAS number 134-32-7. It consists of a naphthalene ring system with an amino group (-NH2) attached at the 1-position. This organic compound has a molecular weight of 143.18 g/mol and appears as crystalline solid. It is classified as moderately toxic and poses environmental hazards to aquatic life.
What are the physicochemical properties of naphthalen-1-amine?
Naphthalen-1-amine is a crystalline solid at room temperature with a characteristic aromatic odor. It typically appears as white to pale yellow crystals that may darken upon exposure to light and air. The compound has limited water solubility but dissolves readily in organic solvents such as ethanol, ether, and benzene. It has a melting point around 50°C and exhibits basic properties due to the amino group.
What is naphthalen-1-amine used for?
Naphthalen-1-amine is primarily used as an intermediate in the production of dyes, pigments, and pharmaceuticals. It serves as a building block for synthesizing various azo dyes and other colorants used in textile and printing industries. The compound is also utilized in the manufacture of antioxidants, rubber chemicals, and specialty organic compounds. Additionally, it finds applications in research and development for chemical synthesis purposes.
How to handle naphthalen-1-amine safely?
Naphthalen-1-amine requires careful handling due to its Acute Tox. 4 classification. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation. Prevent skin and eye contact, and avoid ingestion. Use non-sparking tools and equipment. Wash hands thoroughly after handling and before eating or drinking.
How to store naphthalen-1-amine correctly?
Naphthalen-1-amine should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep away from oxidizing agents, acids, and incompatible materials. Store in original containers with proper labeling and ensure containers are kept upright. Maintain storage temperature below 25°C and protect from moisture. Implement appropriate fire prevention measures in storage areas.
What to do in case of contact with naphthalen-1-amine?
In case of skin contact with naphthalen-1-amine, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes and seek medical attention. If inhaled, move to fresh air and seek medical help if symptoms persist. In case of ingestion, do not induce vomiting and seek immediate medical attention.
How to dispose of naphthalen-1-amine properly?
Naphthalen-1-amine must be disposed of in accordance with local, national, and international environmental regulations. The compound should be treated as hazardous waste due to its toxicity and environmental impact on aquatic systems. Contact licensed waste disposal companies for proper treatment and disposal. Never discharge into sewers, water bodies, or soil. Small quantities may require incineration at authorized facilities under controlled conditions.
How to transport naphthalen-1-amine?
Naphthalen-1-amine is classified under ADR Class 6.1 (Toxic substances) Packing Group III for transportation. It requires proper packaging in UN-approved containers with appropriate labeling including GHS07 and GHS09 pictograms and 'Warning' signal word. Transport documents must include the correct shipping name and UN number. Vehicles must comply with ADR requirements for toxic substances, including proper segregation from incompatible materials.
Is naphthalen-1-amine subject to specific regulations?
Naphthalen-1-amine is subject to various European regulations including REACH registration requirements and CLP classification as Acute Tox. 4 and Aquatic Chronic 2. It is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational exposure limits, environmental discharge restrictions, and proper risk assessment procedures. Industrial users may need authorization for certain applications depending on tonnage and use patterns.
Where to buy naphthalen-1-amine in Europe?
Naphthalen-1-amine is available through OYSI, a leading European distributor of specialty chemicals. OYSI provides high-quality naphthalen-1-amine with proper documentation including safety data sheets, certificates of analysis, and regulatory compliance information. As a trusted supplier across Europe, OYSI ensures reliable delivery and technical support for industrial and research applications while maintaining strict quality and safety standards.
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Naphthalen-1-amine is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.