Azanium hydroxide

H5NO

azanium hydroxide

CAS1336-21-6
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1336-21-6
EC Number
215-647-6
UN Number
3318
Index Number
007-001-01-2
PubChem CID
14923

Physical-chemical properties

Molecular Formula
H5NO
Molar Mass
35.05 g/mol
IUPAC Name
azanium hydroxide

Chemical Identifiers

InChI
InChI=1S/H3N.H2O/h1H3;1H2
InChI Key
VHUUQVKOLVNVRT-UHFFFAOYSA-N

Overview

Azanium hydroxide (CAS 1336-21-6) is an inorganic alkaline compound with strong corrosive properties and high solubility in water. This chemical substance, also known by its EC number 215-647-6, represents a fundamental alkaline solution widely utilized across various industrial sectors. With its molecular formula H5NO and molecular weight of 35.046 g/mol, azanium hydroxide exhibits characteristic basic properties that make it valuable for numerous chemical processes and manufacturing applications. The compound's hazard classification as Skin Corr. 1B indicates its highly corrosive nature, requiring careful handling protocols and appropriate safety measures. The presence of both GHS05 (corrosion) and GHS09 (environmental hazard) pictograms, along with the "Danger" signal word, emphasizes the need for proper personal protective equipment and environmental precautions during handling and storage. Its classification as Aquatic Acute 1 highlights potential environmental risks, necessitating controlled disposal and containment procedures. As an ADR Class 2 substance, azanium hydroxide requires specialized transportation protocols to ensure safety during logistics operations. The compound shares certain industrial applications with related substances like ammonia, anhydrous, particularly in chemical synthesis and pH adjustment processes. Primary industrial applications include chemical manufacturing as a pH regulator and neutralizing agent, water treatment processes where alkaline conditions are required, and various synthesis reactions in pharmaceutical and specialty chemical production. The substance serves as an essential building block in numerous chemical processes requiring controlled alkaline environments. OYSI maintains reliable supply chains for azanium hydroxide, ensuring consistent availability for European industrial customers requiring this essential chemical compound.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3318
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameAmmoniaklösung, in Wasser, mit einer Dichte < 0,88 kg/l bei 15 °C, Konz. > 50 %
Marine PollutantNo

Frequently Asked Questions

What is azanium hydroxide?

Azanium hydroxide is an inorganic compound with the chemical formula H5NO and CAS number 1336-21-6. This substance has a molecular weight of 35.046 g/mol and is classified as a corrosive material that poses significant hazards to skin and aquatic environments. It is commonly known as ammonium hydroxide and exists as an alkaline solution. The compound is characterized by its strong basic properties and corrosive nature, requiring careful handling and storage protocols in industrial applications.

What are the physicochemical properties of azanium hydroxide?

Azanium hydroxide typically exists as a colorless aqueous solution with a characteristic pungent ammonia odor. The compound is highly soluble in water and exhibits strong alkaline properties with a high pH. It has a molecular formula of H5NO and a molecular weight of 35.046 g/mol. The solution is volatile at room temperature, releasing ammonia vapors, and demonstrates excellent miscibility with water and polar solvents while showing corrosive characteristics toward various materials.

What is azanium hydroxide used for?

Azanium hydroxide serves multiple industrial purposes including use as a cleaning agent, pH adjuster, and chemical intermediate in manufacturing processes. It is commonly employed in metal surface treatment, textile processing, and as a neutralizing agent in various chemical reactions. The compound also finds applications in laboratory settings for analytical procedures and in the production of other ammonium-based chemicals. Its strong alkaline properties make it valuable for industrial cleaning and etching operations.

How to handle azanium hydroxide safely?

Safe handling of azanium hydroxide requires appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its Skin Corr. 1B classification. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation of vapors. Avoid direct contact with skin, eyes, and clothing. Use corrosion-resistant equipment and containers. Ensure emergency eyewash stations and safety showers are readily accessible. Never mix with incompatible substances and follow proper spill containment procedures.

How to store azanium hydroxide correctly?

Proper storage of azanium hydroxide requires cool, dry, well-ventilated areas away from incompatible materials such as acids, metals, and oxidizing agents. Use corrosion-resistant containers with tight-fitting lids to prevent vapor escape and contamination. Store in secondary containment systems to manage potential spills. Keep containers upright and properly labeled with hazard information. Maintain storage temperatures within recommended ranges and regularly inspect containers for signs of corrosion or leakage. Separate from foodstuffs and feed materials.

What to do in case of contact with azanium hydroxide?

Immediate first aid for azanium hydroxide contact involves thorough rinsing with copious amounts of water for at least 15-20 minutes. For skin contact, remove contaminated clothing and flush affected areas extensively. In case of eye exposure, rinse eyes continuously while holding eyelids open. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any significant exposure, even if symptoms are not immediately apparent.

How to dispose of azanium hydroxide properly?

Proper disposal of azanium hydroxide must comply with local, national, and European waste regulations as it is classified under multiple hazard categories. The substance should be neutralized carefully with appropriate acids under controlled conditions before disposal. Use authorized waste management companies for collection and treatment. Never discharge directly into sewers, waterways, or soil due to its Aquatic Acute 1 classification. Container disposal requires triple rinsing and appropriate labeling as hazardous waste material.

How to transport azanium hydroxide?

Transportation of azanium hydroxide falls under ADR Class 2 regulations, requiring compliance with dangerous goods transport requirements. Use appropriate packaging that meets UN specification standards and is resistant to corrosion. Vehicles must display proper hazard placards and carry emergency response information. Drivers need dangerous goods training certification. Ensure proper documentation including safety data sheets and transport documents accompany shipments. Avoid transport during extreme weather conditions and follow designated routing requirements.

Is azanium hydroxide subject to specific regulations?

Azanium hydroxide is subject to various European regulations including REACH registration requirements and CLP classification as Skin Corr. 1B and Aquatic Acute 1. It requires appropriate hazard labeling with GHS05 and GHS09 pictograms and 'Danger' signal word. The substance is not currently listed as an SVHC (Substance of Very High Concern). Workplace exposure limits may apply, and users must comply with occupational health and safety regulations. Industrial users should verify compliance with sector-specific legislation.

Where to buy azanium hydroxide in Europe?

Azanium hydroxide is available through OYSI, a trusted European distributor of technical chemicals serving industrial customers across the continent. OYSI provides quality chemical products with proper documentation, safety data sheets, and regulatory compliance support. As a specialized chemical distributor, OYSI ensures reliable supply chains and technical expertise for industrial applications. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.