Azanium hydroxide

H5NO

azanium hydroxide

CAS1336-21-6
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1336-21-6
EC Number
215-647-6
UN Number
3318
Index Number
007-001-01-2
PubChem CID
14923

Physical-chemical properties

Molecular Formula
H5NO
Molar Mass
35.05 g/mol
IUPAC Name
azanium hydroxide

Chemical Identifiers

InChI
InChI=1S/H3N.H2O/h1H3;1H2
InChI Key
VHUUQVKOLVNVRT-UHFFFAOYSA-N

Overview

Azanium hydroxide (CAS 1336-21-6) is an inorganic alkaline compound with strong corrosive properties and high water solubility. This chemical substance, also known by its IUPAC designation azanium hydroxide, represents a fundamental alkaline compound widely utilized across numerous industrial sectors. With the molecular formula H5NO and a molecular weight of 35.046 g/mol, this substance exhibits characteristic properties that make it particularly valuable for various technical applications requiring strong alkaline conditions. The compound is classified under European regulation EC number 215-647-6 and carries significant safety considerations due to its corrosive nature. Safety protocols classify it as Skin Corr. 1B and Aquatic Acute 1, requiring careful handling procedures and appropriate protective equipment during use. The substance displays the GHS05 and GHS09 pictograms, indicating both corrosive properties and environmental hazards, with "Danger" as the signal word. Transportation regulations classify it under ADR Class 2, reflecting its hazardous nature during shipping and storage. Industrial applications of azanium hydroxide span multiple sectors, including chemical manufacturing processes where it serves as a pH adjustment agent and neutralization compound. The substance also finds significant use in water treatment applications, where its alkaline properties help control acidity levels and facilitate precipitation reactions. Additionally, it plays a crucial role in certain cleaning and degreasing formulations within industrial maintenance operations. Like related alkaline compounds such as ammonia, azanium hydroxide requires specialized handling expertise and appropriate safety infrastructure. Its strong basic properties make it an essential component in processes requiring precise pH control and chemical neutralization. OYSI maintains reliable supply chains for azanium hydroxide, ensuring consistent availability for European industrial customers requiring this technical chemical compound.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3318
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameAmmoniaklösung, in Wasser, mit einer Dichte < 0,88 kg/l bei 15 °C, Konz. > 50 %
Marine PollutantNo

Frequently Asked Questions

What is azanium hydroxide?

Azanium hydroxide is an inorganic chemical compound with the molecular formula H5NO and CAS number 1336-21-6. This substance has a molecular weight of 35.046 g/mol and is commonly known as ammonium hydroxide or aqueous ammonia. It is classified as a corrosive substance with significant hazard properties, requiring careful handling and appropriate safety measures in industrial and laboratory applications.

What are the physicochemical properties of azanium hydroxide?

Azanium hydroxide is typically a colorless to pale yellow aqueous solution with a characteristic pungent ammonia odor. It is highly soluble in water and exists as a basic solution with high pH values. The substance is corrosive and reactive, particularly with acids and certain metals. Its volatility releases ammonia gas, which contributes to its distinctive smell and requires proper ventilation during handling.

What is azanium hydroxide used for?

Azanium hydroxide serves multiple industrial purposes including cleaning and degreasing operations, metal surface treatment, and as a pH adjustment agent in various chemical processes. It is commonly used in manufacturing fertilizers, pharmaceuticals, and textiles. The substance also finds applications in water treatment processes and as a laboratory reagent for analytical procedures and chemical synthesis reactions.

How to handle azanium hydroxide safely?

Azanium hydroxide requires strict safety protocols due to its corrosive nature (Skin Corr. 1B classification). Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation of ammonia vapors. Handle containers carefully to prevent spills and ensure immediate access to eyewash stations and emergency showers.

How to store azanium hydroxide correctly?

Azanium hydroxide should be stored in tightly sealed, corrosion-resistant containers in cool, dry, and well-ventilated areas away from direct sunlight and heat sources. Keep separate from acids, oxidizing agents, and incompatible materials to prevent dangerous reactions. Storage areas must have appropriate containment systems for potential spills and should be accessible only to trained personnel with proper safety equipment.

What to do in case of contact with azanium hydroxide?

Immediate action is required for any contact with azanium hydroxide. For skin contact, rinse immediately with plenty of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, flush with water for at least 20 minutes and seek immediate medical attention. If inhaled, move to fresh air immediately. Remove the person from exposure and seek medical help if breathing difficulties occur.

How to dispose of azanium hydroxide appropriately?

Azanium hydroxide disposal must comply with local and national environmental regulations as it poses aquatic toxicity risks (Aquatic Acute 1). Neutralization with appropriate acids under controlled conditions may be required before disposal. Contact licensed waste management companies for proper treatment and disposal. Never discharge directly into sewers, waterways, or soil without proper treatment and regulatory approval.

How to transport azanium hydroxide?

Azanium hydroxide is classified under ADR Class 2 for transportation, indicating it is considered a gas or gas-related substance due to its ammonia content. Transport requires appropriate packaging, labeling with GHS05 and GHS09 pictograms, and documentation indicating its corrosive and environmentally hazardous properties. Only authorized carriers with proper training and equipment should handle transportation of this substance.

Is azanium hydroxide subject to specific regulations?

Azanium hydroxide is regulated under various European legislation including REACH and CLP regulations. It is not classified as a Substance of Very High Concern (SVHC), but its corrosive properties and environmental impact require compliance with safety data sheet requirements, proper labeling, and notification procedures. Industrial users must implement appropriate risk management measures and worker protection protocols.

Where to buy azanium hydroxide in Europe?

Azanium hydroxide is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality chemical products with proper documentation, safety data sheets, and regulatory compliance support. Contact OYSI directly for availability, specifications, and delivery options to meet your specific industrial or laboratory requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.