Molecular chlorine

Cl2

molecular chlorine

CAS7782-50-5
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7782-50-5
EC Number
231-959-5
UN Number
1017
Index Number
017-001-00-7
PubChem CID
24526

Physical-chemical properties

Molecular Formula
Cl2
Molar Mass
70.90 g/mol
IUPAC Name
molecular chlorine

Chemical Identifiers

InChI
InChI=1S/Cl2/c1-2
InChI Key
KZBUYRJDOAKODT-UHFFFAOYSA-N

Overview

Molecular chlorine (CAS 7782-50-5) is a diatomic halogen gas with strong oxidizing properties and characteristic greenish-yellow color. This highly reactive chemical compound consists of two chlorine atoms bonded together, forming one of the most important industrial gases in modern chemical manufacturing. At room temperature, molecular chlorine exists as a dense, toxic gas approximately 2.5 times heavier than air, with a distinctive sharp, suffocating odor detectable even at very low concentrations. The substance exhibits powerful oxidizing characteristics, making it both valuable for industrial processes and requiring strict safety protocols during handling and storage. Molecular chlorine presents significant health and environmental hazards, classified as acutely toxic by inhalation with potential to cause severe respiratory system damage. The gas is highly corrosive to skin and eyes, requiring specialized personal protective equipment and ventilation systems. Its oxidizing nature creates fire and explosion risks when in contact with combustible materials, while environmental releases can cause severe aquatic toxicity. Primary industrial applications include water treatment and disinfection processes, where molecular chlorine serves as a primary disinfectant in municipal water systems and swimming pool sanitization. The chemical industry extensively uses molecular chlorine for manufacturing organochlorine compounds, plastics production, and bleaching processes in paper and textile industries. Unlike related toxic gases such as sulfuryl difluoride used primarily for fumigation, molecular chlorine's versatility extends across multiple industrial sectors due to its strong reactivity and antimicrobial properties. OYSI provides molecular chlorine to qualified industrial customers throughout Europe, ensuring proper regulatory compliance and technical support for safe handling procedures.

Safety & Classification

Danger
Classification:

Ox. Gas 1; Press. Gas; Acute Tox. 3 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H270

May cause or intensify fire; oxidiser.

H331

Toxic if inhaled.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1017
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameChlor, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is molecular chlorine?

Molecular chlorine is a diatomic halogen gas with the chemical formula Cl2 and CAS number 7782-50-5. It consists of two chlorine atoms bonded together, forming a highly reactive oxidizing agent. With a molecular weight of 70.9 g/mol, chlorine is classified as a pressurized oxidizing gas with significant toxicity and irritant properties. It appears as a greenish-yellow gas with a distinctive pungent odor and is widely used in industrial applications requiring strong oxidizing or disinfecting properties.

What are the physicochemical properties of molecular chlorine?

Molecular chlorine is a greenish-yellow gas at room temperature with a characteristic sharp, pungent odor detectable at very low concentrations. It has a molecular weight of 70.9 g/mol and exists as a pressurized gas under normal storage conditions. Chlorine is moderately soluble in water, forming hypochlorous and hydrochloric acids. It is highly reactive, particularly as an oxidizing agent, and readily combines with organic materials and metals. The gas is denser than air and can accumulate in low-lying areas.

What is molecular chlorine used for?

Molecular chlorine is primarily used for water treatment and disinfection in municipal water supplies, swimming pools, and wastewater treatment facilities. It serves as a key intermediate in the production of various chemicals including PVC plastics, solvents, and pharmaceuticals. Industrial applications include pulp and paper bleaching, textile processing, and metal surface treatment. The chemical industry utilizes chlorine for manufacturing chlorinated compounds, while the food industry employs it for sanitization purposes in processing facilities.

How to handle molecular chlorine safely?

Molecular chlorine requires strict safety protocols due to its acute toxicity and corrosive properties. Personnel must wear appropriate respiratory protection, chemical-resistant clothing, and eye protection when handling. Work areas should be well-ventilated with emergency eyewash stations and safety showers readily available. Only trained personnel should handle chlorine cylinders using proper lifting equipment. Emergency response procedures and gas detection systems are essential. All handling should occur in designated areas away from incompatible materials, with emergency ventilation systems in place.

How to store molecular chlorine correctly?

Molecular chlorine must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Cylinders should be secured upright and protected from physical damage in dedicated gas storage areas. Storage locations must be separated from incompatible materials such as flammable substances, organic materials, and reducing agents. Temperature control is critical to prevent excessive pressure buildup. Storage areas require gas detection systems, emergency ventilation, and restricted access. Regular cylinder inspection and proper inventory rotation are essential safety practices.

What to do in case of contact with molecular chlorine?

Molecular chlorine exposure requires immediate emergency response due to its acute toxicity and irritant properties. For inhalation, move the person to fresh air immediately and seek medical attention. In case of eye contact, rinse thoroughly with water for at least 15 minutes and remove contact lenses if easily removable. For skin contact, remove contaminated clothing and wash affected areas with soap and water. Never induce vomiting if ingested. Call emergency services immediately for any significant exposure and provide medical personnel with the safety data sheet.

How to dispose of molecular chlorine appropriately?

Molecular chlorine disposal must comply with local environmental regulations and hazardous waste management requirements. Empty cylinders should be returned to the supplier for proper reconditioning and refilling. Small quantities can be neutralized using appropriate alkaline solutions under controlled conditions by qualified personnel. Large quantities require specialized hazardous waste disposal services. Never discharge chlorine directly into the environment, sewers, or water systems. All disposal activities must be documented and performed by licensed waste management companies following applicable environmental protection standards.

How to transport molecular chlorine?

Molecular chlorine is classified as ADR Class 2 dangerous goods, requiring specialized transport procedures and documentation. Cylinders must be properly secured, labeled, and transported in well-ventilated vehicles by trained drivers holding appropriate dangerous goods certifications. Transport documents, emergency response information, and safety data sheets must accompany shipments. Vehicles require appropriate hazard placarding and emergency equipment. Loading and unloading should only be performed by qualified personnel using proper handling equipment. Temperature control during transport is essential to prevent pressure buildup.

Is molecular chlorine subject to specific regulations?

Molecular chlorine is subject to comprehensive regulatory oversight under multiple frameworks including REACH registration requirements, CLP classification and labeling regulations, and industrial emissions directives. It falls under ADR transport regulations as a Class 2 dangerous good and requires workplace exposure monitoring under occupational health standards. Water treatment applications must comply with drinking water quality regulations. Industrial users must implement risk management measures and may require environmental permits. Some applications may have specific authorization requirements depending on local jurisdictions and usage volumes.

Where to buy molecular chlorine in Europe?

Molecular chlorine is available through OYSI, a European distributor specializing in technical chemical products. As an established chemical distributor, OYSI can provide molecular chlorine in various packaging formats suitable for different industrial applications. Professional customers can contact OYSI for technical specifications, safety documentation, and delivery arrangements across European markets. The company ensures compliance with all relevant regulations including REACH, CLP, and transport requirements. Pricing and availability information can be obtained through direct inquiry with OYSI's technical sales team.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.