Molecular chlorine

Cl2

molecular chlorine

CAS7782-50-5
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7782-50-5
EC Number
231-959-5
UN Number
1017
Index Number
017-001-00-7
PubChem CID
24526

Physical-chemical properties

Molecular Formula
Cl2
Molar Mass
70.90 g/mol
IUPAC Name
molecular chlorine

Chemical Identifiers

InChI
InChI=1S/Cl2/c1-2
InChI Key
KZBUYRJDOAKODT-UHFFFAOYSA-N

Overview

Molecular chlorine (CAS 7782-50-5) is a diatomic halogen gas with strong oxidizing properties and high reactivity. This essential industrial chemical exists as a greenish-yellow gas under standard conditions, characterized by its distinctive pungent odor and powerful chemical reactivity. As a member of the halogen family, molecular chlorine demonstrates exceptional oxidizing capabilities, making it invaluable across numerous industrial processes. The compound's diatomic structure (Cl2) contributes to its high chemical activity and tendency to readily participate in substitution and addition reactions. From a safety perspective, molecular chlorine requires careful handling due to its classification as an oxidizing gas with acute toxicity properties. The substance can cause respiratory irritation and poses significant risks to aquatic environments, necessitating proper containment and safety protocols during storage and use. Its pressurized gas nature adds additional handling considerations for industrial applications. The primary industrial applications of molecular chlorine include water treatment and disinfection processes, where its biocidal properties effectively eliminate pathogens and contaminants. The chemical industry extensively utilizes molecular chlorine in the production of chlorinated compounds, including PVC plastics, solvents, and various organic chemicals. Additionally, it serves as a bleaching agent in paper and textile manufacturing processes. While molecular chlorine differs significantly from related industrial chemicals such as bromomethane in terms of physical state and specific applications, both compounds share halogen-based reactivity that makes them valuable in specialized industrial processes. Unlike sulfuryl difluoride, which primarily serves as a fumigant, molecular chlorine's versatility extends across multiple industrial sectors. OYSI provides reliable access to high-quality molecular chlorine for European industrial customers, ensuring consistent supply for critical manufacturing and treatment applications.

Safety & Classification

Danger
Classification:

Ox. Gas 1; Press. Gas; Acute Tox. 3 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H270

May cause or intensify fire; oxidiser.

H331

Toxic if inhaled.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1017
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameChlor, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is molecular chlorine?

Molecular chlorine is a diatomic halogen gas with the chemical formula Cl2 and CAS number 7782-50-5. It is a highly reactive oxidizing agent with a molecular weight of 70.9 g/mol. This greenish-yellow gas is widely used in industrial applications due to its strong oxidizing and disinfecting properties. Chlorine exists naturally as a diatomic molecule and is one of the most important industrial chemicals globally.

What are the physicochemical properties of molecular chlorine?

Molecular chlorine is a greenish-yellow gas at room temperature with a characteristic pungent, irritating odor. It has a density approximately 2.5 times that of air, causing it to accumulate in low-lying areas. Chlorine is moderately soluble in water, forming hypochlorous and hydrochloric acids. It liquefies under pressure and has a boiling point of -34°C. The gas is highly corrosive and reactive with most organic materials.

What is molecular chlorine used for?

Molecular chlorine serves multiple industrial purposes, primarily as a disinfectant in water treatment plants and swimming pools. It is extensively used in the production of PVC plastics, bleaching agents, and various chlorinated organic compounds. The chemical industry utilizes chlorine for manufacturing pharmaceuticals, pesticides, and solvents. Additionally, it plays a crucial role in pulp and paper bleaching processes and metal processing applications.

How to handle molecular chlorine safely?

Safe handling of molecular chlorine requires appropriate personal protective equipment including gas-tight chemical suits, self-contained breathing apparatus, and chemical-resistant gloves. Work must be conducted in well-ventilated areas or under fume hoods due to its acute toxicity. Emergency eyewash stations and safety showers should be readily accessible. Personnel should be trained in emergency procedures and gas detection systems should be installed to monitor chlorine concentrations.

How to store molecular chlorine correctly?

Molecular chlorine must be stored in specialized pressure vessels designed for corrosive gases, kept in cool, dry, well-ventilated areas away from direct sunlight. Storage areas should be separated from incompatible materials such as ammonia, hydrogen, and organic substances. Cylinders should be secured upright and protected from physical damage. Regular inspection of storage containers and leak detection systems are essential for safe storage.

What to do in case of contact with molecular chlorine?

Immediate evacuation from the exposure area to fresh air is crucial in case of chlorine contact. For skin contact, remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for 15-20 minutes. Seek immediate medical attention for all exposures, especially inhalation cases, as chlorine can cause severe respiratory irritation and chemical burns.

How to dispose of molecular chlorine properly?

Disposal of molecular chlorine must comply with local and national hazardous waste regulations due to its classification as dangerous goods. Small quantities can be neutralized using appropriate alkaline solutions under controlled conditions by trained personnel. Large quantities require specialized waste management companies licensed to handle toxic gases. Empty containers should be returned to suppliers or disposed of through authorized channels following proper decontamination procedures.

How to transport molecular chlorine?

Molecular chlorine is classified as ADR Class 2 dangerous goods, requiring specialized transport procedures and documentation. It must be transported in approved pressure vessels with proper labeling including hazard pictograms GHS03, GHS04, GHS06, and GHS09. Vehicles must carry appropriate emergency equipment and drivers need specific dangerous goods training. Transport should follow designated routes and comply with quantity limitations for tunnel restrictions.

Is molecular chlorine subject to specific regulations?

Molecular chlorine is subject to extensive regulations including REACH registration, CLP classification, and various national chemical safety laws. It carries the signal word 'Danger' with multiple hazard classes including oxidizing gas, acute toxicity, and environmental hazards. Industrial users must implement risk management measures and maintain safety data sheets. The substance requires special permits for storage and use in many jurisdictions due to its toxicity profile.

Where to buy molecular chlorine in Europe?

OYSI serves as a reliable European distributor for molecular chlorine, providing quality chemical products to industrial customers across the continent. As a specialized chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for chlorine shipments. Contact OYSI directly for availability, technical specifications, and delivery options tailored to your industrial requirements while maintaining the highest safety and quality standards throughout the supply chain.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.