Molecular bromine

Br2

molecular bromine

CAS7726-95-6
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for Molecular bromine

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
7726-95-6
EC Number
231-778-1
UN Number
1744
Index Number
035-001-00-5
PubChem CID
24408

Physical-chemical properties

Molecular Formula
Br2
Molar Mass
159.81 g/mol
IUPAC Name
molecular bromine

Chemical Identifiers

InChI
InChI=1S/Br2/c1-2
InChI Key
GDTBXPJZTBHREO-UHFFFAOYSA-N

Overview

Molecular bromine (CAS 7726-95-6) is a diatomic halogen element with highly corrosive properties and strong oxidizing characteristics. This reddish-brown liquid represents one of the most reactive elements in industrial chemistry, existing naturally as diatomic molecules (Br2) at room temperature. Molecular bromine exhibits exceptional chemical reactivity, readily forming compounds with most organic and inorganic substances through halogenation reactions. Its distinctive deep red-brown color and characteristic sharp, penetrating odor make it easily identifiable in laboratory and industrial settings. The substance presents significant safety considerations due to its classification as Acute Tox. 2 and Skin Corr. 1A under GHS standards. Direct contact causes severe chemical burns and tissue damage, while inhalation poses serious respiratory hazards. The aquatic toxicity classification (Aquatic Acute 1) reflects its environmental impact, requiring careful handling and disposal protocols. Transportation falls under ADR Class 8 as a corrosive material, necessitating specialized packaging and documentation. Industrial applications leverage bromine's powerful reactivity and antimicrobial properties. The pharmaceutical sector utilizes molecular bromine in synthesizing brominated organic compounds and active pharmaceutical ingredients. Water treatment facilities employ it as an effective biocide and disinfectant, particularly in cooling tower systems and swimming pool maintenance. The flame retardant industry represents another major application, where bromine derivatives provide fire suppression properties in plastics and textiles. Unlike specialized compounds such as 2-chloro-5-(chloromethyl)-1,3-thiazole used in pharmaceutical synthesis, molecular bromine serves as a fundamental building block for numerous brominated derivatives across multiple industries. OYSI provides molecular bromine to industrial customers throughout Europe, supporting applications in chemical manufacturing, water treatment, and specialty chemical production with comprehensive technical documentation and safety support.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Skin Corr. 1A; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1744
ADR Class8
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameBrom
Marine PollutantNo

Frequently Asked Questions

What is molecular bromine?

Molecular bromine is a highly reactive halogen element existing as a diatomic molecule (Br2) with CAS number 7726-95-6. This chemical compound has a molecular weight of 159.81 g/mol and appears as a dark reddish-brown liquid at room temperature. It is classified as a corrosive substance with acute toxicity properties, making it essential for various industrial applications while requiring careful handling due to its hazardous nature.

What are the physicochemical properties of molecular bromine?

Molecular bromine is a dense, dark reddish-brown liquid at room temperature with a characteristic sharp, penetrating odor. It readily evaporates to form toxic orange-red vapors and has high density compared to water. The substance is moderately soluble in water, forming hydrobromic and hypobromous acids, and highly soluble in organic solvents. Its corrosive nature and volatility make it reactive with most organic materials and metals.

What is molecular bromine used for?

Molecular bromine serves as a key intermediate in pharmaceutical synthesis, flame retardant production, and agricultural chemical manufacturing. It is widely used in the production of brominated compounds for various industrial applications, including water treatment as a disinfectant and sanitizer. Additionally, it finds application in analytical chemistry as a reagent for organic synthesis and in the manufacturing of photographic chemicals and drilling fluids.

How to handle molecular bromine safely?

Molecular bromine requires strict safety protocols including full personal protective equipment: chemical-resistant gloves, eye protection, and respiratory protection in well-ventilated areas. Work should be conducted in fume hoods due to toxic vapor emission. Avoid contact with skin, eyes, and clothing as it causes severe chemical burns. Emergency eyewash and shower facilities must be readily accessible, and personnel should be trained in proper handling procedures before use.

How to store molecular bromine correctly?

Molecular bromine must be stored in tightly sealed, corrosion-resistant containers in cool, dry, well-ventilated areas away from direct sunlight and heat sources. Keep separate from organic materials, metals, and reducing agents due to incompatibility risks. Storage areas should have appropriate containment systems and be equipped with emergency spill control measures. Regular container inspection is essential due to the corrosive nature of bromine vapors.

What to do in case of contact with molecular bromine?

Immediate action is critical for molecular bromine exposure. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical attention. If inhaled, move to fresh air immediately and seek medical care. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult emergency services for serious exposures.

How to dispose of molecular bromine appropriately?

Molecular bromine disposal must comply with local and European waste regulations as hazardous chemical waste. It cannot be disposed of through regular waste streams due to its corrosive and toxic properties. Contact licensed hazardous waste disposal companies for proper treatment and neutralization. Small quantities may be neutralized under controlled conditions by qualified personnel using appropriate reducing agents, but professional disposal is recommended for safety and regulatory compliance.

How to transport molecular bromine?

Molecular bromine is classified as ADR Class 8 (corrosive substances), Packing Group I, indicating high danger level during transport. It requires specialized corrosion-resistant packaging and appropriate hazard labeling including GHS pictograms GHS06, GHS05, and GHS09. Transportation must follow strict ADR regulations with proper documentation, trained personnel, and emergency response procedures. Only authorized carriers with appropriate equipment and certification should handle bromine shipments.

Is molecular bromine subject to particular regulations?

Molecular bromine is subject to comprehensive European chemical regulations including REACH registration and CLP classification requirements. It carries the signal word 'Danger' and is classified as Acute Tox. 2, Skin Corr. 1A, and Aquatic Acute 1 under CLP regulation. While not currently listed as SVHC, it requires proper safety data sheets, risk assessments, and compliance with occupational exposure limits. Industrial users must implement appropriate risk management measures.

Where to buy molecular bromine in Europe?

Molecular bromine is available through OYSI, a specialized European distributor of industrial chemicals. As a professional chemical supplier, OYSI provides molecular bromine with proper documentation, safety data sheets, and regulatory compliance for industrial customers. Given the hazardous nature and regulatory requirements of bromine, purchasing from established distributors like OYSI ensures proper handling, packaging, and legal compliance throughout the supply chain for European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.