Molecular bromine

Br2

molecular bromine

CAS7726-95-6
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7726-95-6
EC Number
231-778-1
UN Number
1744
Index Number
035-001-00-5
PubChem CID
24408

Physical-chemical properties

Molecular Formula
Br2
Molar Mass
159.81 g/mol
IUPAC Name
molecular bromine

Chemical Identifiers

InChI
InChI=1S/Br2/c1-2
InChI Key
GDTBXPJZTBHREO-UHFFFAOYSA-N

Overview

Molecular bromine (CAS 7726-95-6) is a diatomic halogen element with highly corrosive properties and strong oxidizing capabilities. This reddish-brown liquid represents one of only two elements that exist as liquids at room temperature, making it a unique and highly reactive chemical substance in industrial applications. Molecular bromine belongs to the halogen group and exhibits exceptional chemical reactivity due to its electron configuration, readily forming compounds with most organic and inorganic materials. The substance demonstrates significant volatility, producing dense, toxic vapors that require specialized handling procedures and containment systems. The safety profile of molecular bromine demands rigorous attention, as it carries acute toxicity classification (Acute Tox. 2) and severe skin corrosion properties (Skin Corr. 1A). Its aquatic toxicity classification (Aquatic Acute 1) reflects its environmental impact potential, necessitating careful waste management protocols. The substance's ADR Class 8 designation indicates its corrosive transport requirements, while GHS pictograms highlight multiple hazard categories including toxicity, corrosivity, and environmental dangers. Industrial applications of molecular bromine span various sectors, including flame retardant manufacturing where it serves as a key intermediate in brominated compound synthesis. The pharmaceutical industry utilizes molecular bromine in the production of certain therapeutic compounds, while the chemical synthesis sector employs it as an oxidizing agent and brominating reagent. Unlike specialized compounds such as 2-chloro-5-(chloromethyl)-1,3-thiazole used in specific synthetic pathways, molecular bromine offers broader reactivity patterns suitable for diverse chemical transformations. OYSI maintains reliable supply chains for molecular bromine, ensuring consistent availability for European industrial customers requiring this essential halogen compound.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Skin Corr. 1A; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1744
ADR Class8
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameBrom
Marine PollutantNo

Frequently Asked Questions

What is molecular bromine?

Molecular bromine is a diatomic halogen element with the chemical formula Br2 and CAS number 7726-95-6. It exists as a reddish-brown liquid at room temperature with a strong, pungent odor. With a molecular weight of 159.81 g/mol, bromine is highly reactive and corrosive. It is classified as acutely toxic, skin corrosive, and harmful to aquatic life, requiring careful handling in industrial applications.

What are the physicochemical properties of molecular bromine?

Molecular bromine is a dense, reddish-brown liquid at room temperature with a characteristic sharp, irritating odor. It readily vaporizes to form orange-brown fumes and is moderately soluble in water, forming hydrobromic and hypobromous acids. Bromine has a boiling point of 58.8°C and freezing point of -7.2°C. It is highly reactive with organic compounds and metals, making it corrosive to most materials.

What is molecular bromine used for?

Molecular bromine is primarily used in the production of flame retardants, pharmaceuticals, and agrochemicals. It serves as an intermediate in manufacturing organobromine compounds and is utilized in water treatment applications as a disinfectant. The chemical industry employs bromine in the synthesis of dyes, photographic chemicals, and drilling fluids. It also finds applications in analytical chemistry and as a catalyst in certain organic reactions.

How to handle molecular bromine safely?

Molecular bromine requires strict safety measures due to its corrosive and toxic nature. Always wear chemical-resistant gloves, protective clothing, eye protection, and respiratory equipment when handling. Work in well-ventilated areas or under fume hoods to avoid vapor inhalation. Use appropriate tools and containers made of compatible materials. Emergency eyewash stations and safety showers should be readily accessible. Never handle bromine without proper training and safety protocols.

How to store molecular bromine correctly?

Molecular bromine must be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from direct sunlight. Keep away from incompatible materials such as metals, organic compounds, and reducing agents. Storage areas should be equipped with appropriate containment systems and fire suppression equipment. Maintain temperatures below 25°C and ensure containers are properly labeled with hazard information.

What to do in case of contact with molecular bromine?

Immediate action is crucial in case of bromine contact. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. If inhaled, move person to fresh air immediately and seek medical attention. For eye contact, rinse thoroughly with water for at least 15 minutes. Never induce vomiting if ingested. Seek immediate medical attention in all cases of exposure.

How to dispose of molecular bromine appropriately?

Molecular bromine disposal must comply with local and international hazardous waste regulations. Never discharge bromine into drains, soil, or waterways due to its environmental toxicity. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities can be neutralized by qualified personnel using appropriate reducing agents under controlled conditions. Always consult local environmental authorities for specific disposal requirements and regulations.

How to transport molecular bromine?

Molecular bromine is classified as ADR Class 8 (Corrosive substances), Packing Group I, indicating high danger level. Transportation requires UN-approved packaging designed for corrosive liquids and proper hazard labeling with corrosive pictograms. Vehicles must carry appropriate emergency equipment and documentation. Only trained personnel should handle bromine shipments, and transport must comply with international dangerous goods regulations including ADR for road transport in Europe.

Is molecular bromine subject to specific regulations?

Molecular bromine is subject to comprehensive chemical regulations including REACH registration in Europe and CLP classification requirements. It carries the signal word 'Danger' with pictograms GHS06, GHS05, and GHS09, indicating acute toxicity, corrosivity, and environmental hazards. While not listed as a SVHC substance, it requires safety data sheets, proper labeling, and compliance with occupational exposure limits. Transportation regulations also apply due to its corrosive classification.

Where to buy molecular bromine in Europe?

Molecular bromine is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial-grade bromine to professional users across European markets. Purchase requires proper documentation due to regulatory requirements and safety considerations. Buyers typically need to demonstrate legitimate industrial use and appropriate handling capabilities. Contact OYSI's technical team for product specifications, packaging options, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.