Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate

C4H6MnN2S4

manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate

CAS12427-38-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
12427-38-2
EC Number
235-654-8
UN Number
2210
Index Number
006-077-00-7
PubChem CID
3032581

Physical-chemical properties

Molecular Formula
C4H6MnN2S4
Molar Mass
265.30 g/mol
IUPAC Name
manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate

Chemical Identifiers

InChI
InChI=1S/C4H8N2S4.Mn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2
InChI Key
YKSNLCVSTHTHJA-UHFFFAOYSA-L

Overview

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate (CAS 12427-38-2) is an organometallic manganese complex featuring dithiocarbamate ligands with significant industrial applications. This specialized manganese dithiocarbamate compound represents an important class of organometallic chemicals widely utilized in industrial processes. With the molecular formula C4H6MnN2S4 and a molecular weight of 265.3 g/mol, this substance combines manganese(II) ions with ethylene bisdithiocarbamate ligands, creating a stable coordination complex with distinctive chemical properties. The compound exhibits several critical safety characteristics that require careful handling protocols. Classified as Repr. 2 and Acute Tox. 4, it presents reproductive toxicity concerns and acute toxicity risks. Additionally, it demonstrates eye irritation potential (Eye Irrit. 2) and skin sensitization properties (Skin Sens. 1), necessitating appropriate personal protective equipment during handling. Environmental considerations are particularly important, as the substance carries Aquatic Acute 1 and Aquatic Chronic 1 classifications, indicating high toxicity to aquatic organisms. The ADR Class 4.2 designation reflects its potential fire hazard properties under certain conditions. Industrial applications for this manganese dithiocarbamate primarily include its use as a fungicide in agricultural formulations, where it provides effective disease control for various crops. The compound also serves as a catalyst or catalyst precursor in polymerization processes and rubber vulcanization applications. Like other dithiocarbamate compounds such as sodium propan-2-yloxymethanedithioate, it demonstrates chelating properties that make it valuable in metal extraction and purification processes. OYSI maintains reliable supply chains for this specialized manganese compound, ensuring consistent availability for European industrial customers requiring high-quality organometallic chemicals for their technical applications.

Safety & Classification

Warning
Classification:

Repr. 2; Acute Tox. 4 *; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H332

Harmful if inhaled.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2210
ADR Class4.2
Packing GroupIII
Tunnel CodeE
Proper Shipping NameManeb
Marine PollutantNo

Frequently Asked Questions

What is manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is an organometallic compound with CAS number 12427-38-2 and molecular formula C4H6MnN2S4. This manganese-based dithiocarbamate complex has a molecular weight of 265.3 g/mol and contains sulfur-rich functional groups. It is classified as a hazardous substance with multiple safety concerns including reproductive toxicity, acute toxicity, and environmental hazards.

What are the physicochemical properties of manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is a solid compound with a molecular weight of 265.3 g/mol and formula C4H6MnN2S4. As a manganese dithiocarbamate complex, it typically appears as a colored solid due to the presence of the transition metal. The compound contains multiple sulfur atoms which influence its chemical reactivity and coordination properties. Specific physical properties such as melting point and solubility require laboratory testing.

What is manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate used for?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is primarily used in industrial applications as a catalyst or chemical intermediate. Dithiocarbamate complexes like this compound are commonly employed in polymer chemistry, as vulcanization accelerators in rubber manufacturing, and as precursors for advanced materials. The manganese center provides catalytic activity for various organic transformations, making it valuable in specialty chemical synthesis and materials science applications.

How to handle manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate safely?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate requires careful handling due to its hazard classifications including reproductive toxicity (Repr. 2) and acute toxicity (Acute Tox. 4). Use appropriate personal protective equipment including gloves, safety goggles, and respiratory protection. Work in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin and eye contact, and implement proper hygiene measures. The compound may cause skin sensitization, so minimize direct contact.

How to store manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate correctly?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from incompatible materials. As an ADR Class 4.2 substance (Group III), it requires storage conditions that prevent spontaneous combustion or heating. Keep away from sources of ignition, heat, and direct sunlight. Store separately from oxidizing agents and acids to prevent dangerous reactions.

What to do in case of contact with manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?

Immediate action is required upon contact with manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate due to its toxicity and irritant properties. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek medical attention immediately. Always consult safety data sheets for complete first aid procedures.

How to dispose of manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate properly?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate must be disposed of as hazardous waste according to local and national regulations due to its environmental hazard classification (Aquatic Acute 1, Aquatic Chronic 1). Contact licensed hazardous waste disposal companies for proper treatment and disposal. Do not discharge to sewers, soil, or water bodies. Contaminated packaging should also be treated as hazardous waste. Follow all applicable waste management regulations including proper labeling and documentation.

How to transport manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is classified under ADR Class 4.2, Group III, indicating it is a substance liable to spontaneous combustion with relatively lower risk level. Transportation requires appropriate UN-specification packaging and proper labeling with hazard placards. Drivers must hold ADR certification for dangerous goods transport. Vehicles should be equipped with appropriate safety equipment and emergency procedures. Ensure compliance with international dangerous goods regulations for road, rail, or sea transport.

Is manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate subject to special regulations?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is subject to REACH and CLP regulations in the European Union, requiring proper classification, labeling, and safety data sheets. While not currently listed as a Substance of Very High Concern (SVHC), its hazard profile including reproductive toxicity and environmental concerns means it requires careful regulatory compliance. Users must follow occupational exposure limits, implement risk management measures, and ensure proper worker protection under chemical safety legislation.

Where to buy manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate in Europe?

Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this specialty compound to industrial customers requiring high-quality chemical intermediates and catalysts. As a professional chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for hazardous substances. Contact OYSI directly for availability, technical specifications, and pricing information for your specific industrial applications.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.