Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
C4H6MnN2S4
manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
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Identification
- CAS Number
- 12427-38-2
- EC Number
- 235-654-8
- UN Number
- 2210
- Index Number
- 006-077-00-7
- PubChem CID
- 3032581
Physical-chemical properties
- Molecular Formula
- C4H6MnN2S4
- Molar Mass
- 265.30 g/mol
- IUPAC Name
- manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
Chemical Identifiers
- InChI
- InChI=1S/C4H8N2S4.Mn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2
- InChI Key
- YKSNLCVSTHTHJA-UHFFFAOYSA-L
Overview
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate (CAS 12427-38-2) is an organometallic manganese complex containing dithiocarbamate ligands with industrial fungicidal properties. This specialized manganese-based compound represents an important class of organometallic fungicides widely utilized in industrial applications. The molecular structure features manganese in its +2 oxidation state coordinated with dithiocarbamate ligands, creating a stable complex with distinctive antifungal properties. With a molecular formula of C4H6MnN2S4 and molecular weight of 265.3 g/mol, this compound belongs to the ethylene bis-dithiocarbamate family of fungicides. The substance exhibits significant safety considerations requiring careful handling protocols. Classified under multiple hazard categories including reproductive toxicity (Category 2), acute toxicity (Category 4), eye irritation (Category 2), and skin sensitization (Category 1), it demands appropriate personal protective equipment and workplace safety measures. The compound also presents environmental concerns with acute and chronic aquatic toxicity classifications, necessitating controlled disposal procedures. Its ADR classification of 4.2 indicates potential for spontaneous combustion under certain conditions. Primary industrial applications include agricultural fungicide formulations, rubber vulcanization accelerators, and specialized antimicrobial treatments for industrial materials. The compound's efficacy against various fungal pathogens makes it valuable in crop protection formulations, while its chemical properties enable use in polymer processing applications. Similar to other dithiocarbamate compounds like sodium propan-2-yloxymethanedithioate, it functions through metal chelation mechanisms that disrupt cellular processes in target organisms. OYSI maintains reliable supply chains for this technical-grade manganese complex, supporting European industrial customers with consistent quality and regulatory compliance documentation.
Safety & Classification
Repr. 2; Acute Tox. 4 *; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2210 |
| ADR Class | 4.2 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Maneb |
| Marine Pollutant | No |
Frequently Asked Questions
What is manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is an organometallic compound containing manganese in its +2 oxidation state complexed with dithiocarbamate ligands. With the molecular formula C4H6MnN2S4 and CAS number 12427-38-2, this compound has a molecular weight of 265.3 g/mol. It belongs to the family of metal dithiocarbamates, which are characterized by their sulfur-containing coordination complexes with transition metals.
What are the physicochemical properties of manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is typically a solid compound at room temperature with a molecular weight of 265.3 g/mol. As a metal dithiocarbamate complex, it generally exhibits limited water solubility but may be soluble in organic solvents. The compound contains multiple sulfur atoms which contribute to its coordination chemistry and stability. Its physical appearance and exact solubility parameters depend on the specific crystalline form and purity of the material.
What is manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate used for?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is primarily used as a fungicide and biocide in industrial applications. Metal dithiocarbamate compounds like this are commonly employed in agricultural formulations, rubber vulcanization processes, and as antimicrobial agents. The compound may also find use in specialized chemical synthesis processes and as a precursor for other manganese-containing materials. Its applications are typically limited to professional and industrial settings due to its hazard classification.
How to handle manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate safely?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate requires careful handling due to its classification as Acute Tox. 4, Eye Irrit. 2, and Skin Sens. 1. Personal protective equipment should include chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid inhalation of dust or vapors, and ensure proper hygiene measures including thorough handwashing after handling.
How to store manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate correctly?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Given its ADR classification as Class 4.2 (substances liable to spontaneous combustion), storage areas must be designed to prevent spontaneous ignition risks. Keep containers tightly closed and protected from moisture. Storage facilities should comply with local fire prevention regulations and be equipped with appropriate fire suppression systems suitable for chemical fires.
What to do in case of contact with manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?
In case of skin contact with manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms develop or persist.
How to dispose of manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate appropriately?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate must be disposed of as hazardous waste through licensed waste management companies in accordance with local and EU regulations. Due to its aquatic toxicity classification (Aquatic Acute 1, Aquatic Chronic 1), prevent any release to sewers, waterways, or soil. Empty containers should also be treated as hazardous waste. Disposal methods may include high-temperature incineration at authorized facilities equipped with appropriate emission control systems.
How to transport manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is classified under ADR Class 4.2, Packing Group III, indicating it's a substance liable to spontaneous combustion with relatively lower risk. Transport requires appropriate UN-specification packaging designed for Class 4.2 materials. Vehicles must carry proper documentation, emergency response information, and appropriate fire extinguishing equipment. Drivers need ADR certification for dangerous goods transport, and the shipment must be properly labeled with relevant hazard placards and markings.
Is manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate subject to specific regulations?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is subject to EU CLP regulation due to its hazard classifications including reproductive toxicity (Repr. 2) and environmental hazards. While not currently listed as a SVHC under REACH, it requires proper classification, labeling, and safety data sheets. The compound may be subject to additional restrictions under biocide regulations if used for antimicrobial purposes. Users must comply with occupational exposure limits and environmental discharge restrictions in their respective countries.
Where to buy manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate in Europe?
Manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate is available through OYSI, a specialized European distributor of industrial chemicals. As a professional chemical supplier, OYSI can provide this compound with proper documentation, safety data sheets, and regulatory compliance support. Due to the compound's hazardous nature and specialized applications, procurement is typically limited to qualified industrial users with appropriate handling facilities and expertise. Contact OYSI directly for availability, specifications, and regulatory guidance for your specific application.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.