2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate

C15H20O6

CAS15625-89-5
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
15625-89-5
EC Number
239-701-3
UN Number
3532
Index Number
607-111-00-9
PubChem CID
27423

Physical-chemical properties

Molecular Formula
C15H20O6
Molar Mass
296.31 g/mol
IUPAC Name
2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C15H20O6/c1-5-12(16)19-9-15(8-4,10-20-13(17)6-2)11-21-14(18)7-3/h5-7H,1-3,8-11H2,4H3
InChI Key
DAKWPKUUDNSNPN-UHFFFAOYSA-N

Overview

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate (CAS 15625-89-5) is a triacrylate ester monomer with excellent crosslinking properties and high reactivity for UV-curing applications. This specialized acrylate compound, with molecular formula C15H20O6 and molecular weight 296.31 g/mol, represents a key component in advanced polymer chemistry and radiation-curing technologies. The molecule features three acrylate functional groups attached to a branched aliphatic backbone, providing exceptional crosslinking density when polymerized. Its EC number 239-701-3 identifies it within European chemical regulations as a substance requiring careful handling due to its reactive nature. The compound exhibits typical acrylate monomer characteristics including rapid photopolymerization under UV light and the ability to form highly crosslinked three-dimensional networks. Safety considerations are paramount when handling this material, as it carries multiple hazard classifications including skin and eye irritation, skin sensitization potential, and suspected carcinogenic properties (Category 2). The presence of GHS08, GHS07, and GHS09 pictograms indicates health hazards and environmental concerns, while its ADR classification 4.1 designates it as a flammable solid during transport. Primary industrial applications include UV-curable coatings, adhesives, and inks where high crosslink density and chemical resistance are required. The compound is particularly valued in automotive clearcoats, electronic component encapsulation, and decorative printing applications. Unlike simpler compounds such as naphthalene, this multifunctional acrylate offers superior performance in demanding coating applications requiring exceptional durability and chemical resistance. OYSI maintains reliable supply chains for this technical specialty chemical, ensuring consistent availability for European industrial customers requiring high-quality acrylate monomers.

Safety & Classification

Warning
Classification:

Carc. 2; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3532
ADR Class4.1
Packing GroupIII
Tunnel CodeD
Proper Shipping NameTrimethylolpropantriacrylat
Marine PollutantNo

Frequently Asked Questions

What is 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate is a multifunctional acrylate ester with the molecular formula C15H20O6 and CAS number 15625-89-5. This chemical compound has a molecular weight of 296.31 g/mol and belongs to the family of acrylic monomers. It is classified as a hazardous substance with potential carcinogenic properties (Category 2) and can cause skin and eye irritation as well as skin sensitization.

What are the physicochemical properties of 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate is typically a clear to pale yellow liquid at room temperature with a characteristic acrylic odor. As an acrylate ester, it exhibits moderate viscosity and has limited water solubility but good solubility in organic solvents. The compound contains multiple acrylate functional groups, making it highly reactive and prone to polymerization when exposed to heat, light, or initiators.

What is 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate used for?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate is primarily used as a crosslinking agent and multifunctional monomer in UV-curable coatings, adhesives, and printing inks. Its three acrylate groups enable rapid curing and provide excellent crosslink density, resulting in hard, durable finishes. It is particularly valuable in applications requiring high chemical resistance, scratch resistance, and mechanical properties such as automotive coatings and industrial protective finishes.

How to handle 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate safely?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate requires careful handling due to its irritating and potentially carcinogenic properties. Essential protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use respiratory protection to avoid inhalation. Avoid heat sources, sparks, and UV light that could initiate polymerization. Ensure emergency eyewash and shower facilities are readily accessible.

How to store 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate correctly?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed and store below 25°C to prevent premature polymerization. Add polymerization inhibitors if recommended by the manufacturer. Store separately from oxidizing agents, peroxides, and strong acids. Ensure storage areas are equipped with appropriate spill containment and fire suppression systems.

What to do in case of contact with 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate?

Immediate action is required in case of contact with 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate. For skin contact, remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move to fresh air immediately. Seek medical attention if irritation persists or develops.

How to dispose of 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate appropriately?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate disposal must comply with local and national hazardous waste regulations. The substance cannot be disposed of in regular waste streams due to its classification as hazardous material. Contact licensed hazardous waste disposal companies for proper treatment, which typically involves high-temperature incineration or specialized chemical treatment. Polymerize small quantities before disposal if permitted by local authorities. Never discharge into sewers or water systems.

How to transport 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate is classified under ADR Class 4.1 (Flammable solids) Packing Group III for transportation. It requires appropriate UN-specification packaging and proper labeling with hazard placards. Transport vehicles must carry appropriate emergency equipment and documentation including safety data sheets. Drivers need ADR training certification. Avoid transport during extreme temperatures and ensure packages are secured to prevent damage during transit.

Is 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate subject to specific regulations?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate is subject to comprehensive chemical regulations including REACH registration and CLP classification requirements in Europe. It is classified with GHS pictograms GHS07, GHS08, and GHS09, requiring appropriate labeling and safety data sheets. While not currently listed as an SVHC substance, its Carcinogen Category 2 classification subjects it to specific workplace exposure limits and risk management measures under occupational health regulations.

Where to buy 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate in Europe?

2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate is available through OYSI, a specialized European distributor of technical chemical products. OYSI provides reliable supply chains across Europe with proper regulatory compliance and technical support. As a professional chemical distributor, OYSI ensures products meet quality standards and provides comprehensive documentation including safety data sheets, certificates of analysis, and regulatory compliance information required for industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.