Magnesium hydride

H2Mg

magnesium hydride

CAS7693-27-8

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Identification

CAS Number
7693-27-8
EC Number
231-705-3
UN Number
2010
PubChem CID
107663

Physical-chemical properties

Molecular Formula
H2Mg
Molar Mass
26.32 g/mol
IUPAC Name
magnesium hydride

Chemical Identifiers

InChI
InChI=1S/Mg.2H/q+2;2*-1
InChI Key
RHLWKNJTVXDVHU-UHFFFAOYSA-N

Overview

Magnesium hydride (CAS 7693-27-8) is an inorganic compound with high hydrogen storage capacity and strong reducing properties. This binary metal hydride represents a significant compound in advanced materials science and hydrogen storage technology. Magnesium hydride consists of magnesium cations and hydride anions arranged in a crystalline structure, forming a white to grayish solid under standard conditions. With its molecular formula H2Mg and molecular weight of 26.321 g/mol, this compound demonstrates exceptional theoretical hydrogen storage capacity of approximately 7.6% by weight, making it particularly valuable for hydrogen economy applications. The compound exhibits strong reducing characteristics and reacts vigorously with water, releasing hydrogen gas and forming magnesium hydroxide. This reaction classifies magnesium hydride under ADR Class 4.3 as a substance that emits flammable gases when in contact with water. Unlike more reactive alkali metal hydrides such as those formed with sodium or potassium, magnesium hydride offers improved stability while maintaining useful reactivity for industrial applications. Key industrial applications include hydrogen storage systems for fuel cell technologies, where reversible hydrogen absorption and desorption cycles are crucial. The compound also serves as a reducing agent in metallurgical processes and as a hydrogen source in specialized chemical syntheses. In materials science, magnesium hydride is investigated for lightweight hydrogen storage applications in automotive and aerospace sectors. Safety considerations require proper handling under inert atmosphere conditions and protection from moisture to prevent uncontrolled hydrogen evolution. Storage facilities must ensure adequate ventilation and appropriate fire safety measures. OYSI provides technical-grade magnesium hydride to support European industrial applications requiring reliable hydrogen storage and reduction capabilities.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2010
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameMagnesiumhydrid
Marine PollutantNo

Frequently Asked Questions

What is magnesium hydride?

Magnesium hydride is an inorganic chemical compound with the molecular formula H2Mg and CAS number 7693-27-8. This binary hydride consists of magnesium atoms bonded to hydrogen atoms, forming a crystalline solid with a molecular weight of 26.321 g/mol. It serves as an important reducing agent and hydrogen storage material in various industrial applications, particularly valued for its high hydrogen content and reactivity with water.

What are the physicochemical properties of magnesium hydride?

Magnesium hydride appears as a white to grayish crystalline powder with no characteristic odor. It has a density of approximately 1.45 g/cm³ and decomposes at temperatures above 280°C, releasing hydrogen gas. The compound is highly reactive with water and moisture, producing hydrogen gas and magnesium hydroxide. It is insoluble in most organic solvents but reacts vigorously with protic solvents and acids.

What is magnesium hydride used for?

Magnesium hydride is primarily used as a hydrogen storage material in fuel cell applications and renewable energy systems due to its high hydrogen content. It serves as a powerful reducing agent in metallurgical processes and organic synthesis reactions. Additional applications include its use in the production of other metal hydrides, as a desiccant for removing moisture from gas streams, and in specialized chemical research for hydrogen generation.

How to handle magnesium hydride safely?

Magnesium hydride requires careful handling due to its reactivity with moisture and potential for hydrogen gas generation. Essential safety measures include wearing appropriate personal protective equipment such as safety glasses, gloves, and protective clothing. Work should be conducted in well-ventilated areas or under inert atmosphere to prevent moisture contact. Avoid sources of ignition, ensure proper grounding of equipment, and have appropriate fire suppression systems available.

How to store magnesium hydride correctly?

Magnesium hydride must be stored in airtight, moisture-proof containers under inert atmosphere conditions, typically argon or nitrogen gas. Storage areas should be cool, dry, and well-ventilated, away from sources of heat, moisture, and incompatible materials such as oxidizing agents and acids. Containers should be clearly labeled and stored in designated chemical storage areas with appropriate fire detection and suppression systems installed.

What to do in case of contact with magnesium hydride?

In case of skin contact with magnesium hydride, immediately remove contaminated clothing and brush off excess material before flushing with plenty of water. For eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific emergency procedures.

How to dispose of magnesium hydride appropriately?

Magnesium hydride disposal must comply with local and national waste regulations as it is classified as hazardous waste. The material should be carefully neutralized by controlled reaction with water under professional supervision, producing hydrogen gas and magnesium hydroxide. This process must be conducted in appropriate facilities with proper ventilation and safety measures. Contact certified waste disposal companies for proper handling and disposal according to environmental regulations.

How to transport magnesium hydride?

Magnesium hydride is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating high danger level. Transportation requires appropriate dangerous goods packaging, labeling, and documentation according to ADR regulations. Vehicles must be equipped with proper safety equipment, and drivers must hold valid dangerous goods transport certification. Special precautions against moisture exposure during transport are essential.

Is magnesium hydride subject to particular regulations?

Magnesium hydride is subject to various chemical safety regulations including REACH registration requirements for manufacturing and import within the European Union. Transportation is regulated under ADR dangerous goods regulations due to its Class 4.3 classification. Workplace exposure limits and safety measures are governed by occupational health and safety regulations. Users must comply with CLP regulation requirements for classification, labeling, and packaging of chemical substances.

Where to buy magnesium hydride in Europe?

Magnesium hydride is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides high-quality magnesium hydride with proper documentation, safety data sheets, and regulatory compliance support. As an established chemical distributor, OYSI ensures reliable supply chains and technical expertise to support customer applications requiring this specialized hydrogen storage material.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.