Magnesium ethane

C4H10Mg

magnesium ethane

CAS557-18-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
557-18-6
EC Number
209-159-2
UN Number
3394
Index Number
012-003-00-4
PubChem CID
11183

Physical-chemical properties

Molecular Formula
C4H10Mg
Molar Mass
82.43 g/mol
IUPAC Name
magnesium ethane

Chemical Identifiers

InChI
InChI=1S/2C2H5.Mg/c2*1-2;/h2*1H2,2H3;/q2*-1;+2
InChI Key
DLPASUVGCQPFFO-UHFFFAOYSA-N

Overview

Magnesium ethane (CAS 557-18-6) is an organometallic compound with highly reactive pyrophoric properties and strong water reactivity characteristics. This specialized organometallic reagent represents a significant chemical intermediate in advanced synthetic chemistry applications. With its molecular formula C4H10Mg and molecular weight of 82.43 g/mol, magnesium ethane exhibits exceptional reactivity that demands careful handling protocols and specialized storage conditions. The compound falls under the European classification system as a pyrophoric liquid (Pyr. Liq. 1) and water-reactive substance (Water-react. 1), requiring stringent safety measures during transport and use. The substance's hazard profile includes skin corrosive properties (Skin Corr. 1B), necessitating comprehensive personal protective equipment and engineering controls. Its ADR classification as Class 4.2 reflects its spontaneous combustion potential, while the GHS02 and GHS05 pictograms indicate both fire hazard and corrosive properties. These characteristics place magnesium ethane in a similar reactivity category to other organometallic compounds such as tripropylalumane and sodium methanolate, though each exhibits distinct handling requirements. Industrial applications for magnesium ethane primarily focus on specialized organic synthesis processes, particularly in pharmaceutical intermediate production and advanced materials manufacturing. The compound serves as an effective nucleophilic reagent in carbon-carbon bond formation reactions and finds utility in metal-organic framework synthesis applications. Storage and handling require inert atmosphere conditions, typically under nitrogen or argon, with absolute exclusion of moisture and oxygen. Temperature control remains critical for maintaining product stability and preventing unwanted decomposition reactions. OYSI maintains technical-grade magnesium ethane inventory to support European chemical manufacturing operations, providing comprehensive safety documentation and regulatory compliance support for qualified industrial customers.

Safety & Classification

Danger
Classification:

Pyr. Liq. 1; Water-react. 1; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H250

Catches fire spontaneously if exposed to air.

H260

In contact with water releases flammable gases which may ignite spontaneously.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameDiethylmagnesium, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is magnesium ethane?

Magnesium ethane is an organometallic compound with the molecular formula C4H10Mg and CAS number 557-18-6. This substance belongs to the family of organomagnesium compounds, featuring magnesium atoms bonded to organic ethyl groups. With a molecular weight of 82.43 g/mol, it is classified as a highly hazardous chemical due to its pyrophoric and water-reactive properties. It poses significant safety risks including spontaneous ignition and corrosive effects on skin.

What are the physicochemical properties of magnesium ethane?

Magnesium ethane is a pyrophoric liquid that ignites spontaneously upon contact with air. It reacts violently with water, releasing flammable gases and heat. The compound is highly sensitive to moisture and oxygen, requiring inert atmosphere handling. Due to its organometallic nature, it is typically stored and handled under nitrogen or argon. The substance exhibits corrosive properties and can cause severe chemical burns upon contact with skin or mucous membranes.

What is magnesium ethane used for?

Magnesium ethane is primarily used as a reagent in organic synthesis and as a precursor for various organomagnesium compounds. It serves applications in pharmaceutical intermediate synthesis, polymer chemistry, and specialized chemical manufacturing processes. The compound is utilized in research laboratories for organometallic chemistry studies and catalysis development. Its reactive nature makes it valuable for creating carbon-magnesium bonds in synthetic organic chemistry, particularly in advanced pharmaceutical and fine chemical production.

How to handle magnesium ethane safely?

Magnesium ethane requires strict safety protocols including use of appropriate personal protective equipment: chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted under inert atmosphere in well-ventilated areas or fume hoods. Avoid contact with water, moisture, and air to prevent violent reactions. Keep fire extinguishing equipment nearby but avoid water-based extinguishers. Personnel should be trained in handling pyrophoric and corrosive materials before working with this substance.

How to store magnesium ethane correctly?

Magnesium ethane must be stored under inert atmosphere (nitrogen or argon) in tightly sealed, moisture-proof containers. Storage areas should be cool, dry, and well-ventilated, away from heat sources, ignition sources, and incompatible materials. Keep separated from water, alcohols, acids, and oxidizing agents. Storage facilities should have appropriate fire suppression systems (excluding water-based systems) and emergency response equipment. Regular inspection of container integrity is essential to prevent exposure to air or moisture.

What to do in case of contact with magnesium ethane?

Immediate action is required upon contact with magnesium ethane. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes, then seek immediate medical attention. In case of eye contact, rinse thoroughly with water and get emergency medical care. If inhaled, move to fresh air immediately. For spills, evacuate the area, eliminate ignition sources, and contain using dry sand or inert absorbent materials. Never use water on spills.

How to dispose of magnesium ethane properly?

Magnesium ethane disposal requires specialized hazardous waste procedures due to its pyrophoric and corrosive properties. The substance must be neutralized carefully under controlled conditions by qualified personnel using appropriate quenching agents in inert atmosphere. Disposal should be conducted through licensed hazardous waste contractors familiar with organometallic compounds. All containers and contaminated materials require proper classification and handling according to local and European waste regulations. Never dispose of in regular waste streams or sewers.

How to transport magnesium ethane?

Magnesium ethane is classified under ADR Class 4.2 (substances liable to spontaneous combustion), Packing Group I, indicating highest danger level. Transport requires specialized packaging designed for pyrophoric liquids, with proper labeling including GHS02 and GHS05 pictograms and 'Danger' signal word. Vehicles must comply with ADR regulations for Class 4.2 materials, including appropriate fire suppression systems and trained drivers. Shipping documentation must include proper shipping names, hazard classifications, and emergency response information.

Is magnesium ethane subject to specific regulations?

Magnesium ethane is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification as Pyrophoric Liquid Category 1, Water-reactive Category 1, and Skin Corrosive Category 1B. It requires safety data sheets compliant with current regulations and appropriate hazard labeling. The substance is not currently listed as SVHC (Substance of Very High Concern). Industrial users must implement appropriate risk management measures and may require authorization depending on use patterns and quantities handled.

Where to buy magnesium ethane in Europe?

Magnesium ethane is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous and specialty compounds. As an established chemical supplier, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for organometallic compounds. Due to the specialized nature and safety requirements of magnesium ethane, procurement should only be through qualified distributors who understand the handling, storage, and transportation requirements of pyrophoric materials.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.