Triethylborane
C6H15B
triethylborane
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Identification
- CAS Number
- 97-94-9
- EC Number
- 202-620-9
- UN Number
- 3394
- Index Number
- 005-004-01-3
- PubChem CID
- 7357
Physical-chemical properties
- Molecular Formula
- C6H15B
- Molar Mass
- 98.00 g/mol
- IUPAC Name
- triethylborane
Chemical Identifiers
- InChI
- InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
- InChI Key
- LALRXNPLTWZJIJ-UHFFFAOYSA-N
Overview
Triethylborane (CAS 97-94-9) is an organoborane compound with pyrophoric properties and strong reactivity toward moisture and oxygen. This colorless liquid represents one of the most important trialkylborane compounds in industrial chemistry, characterized by its exceptional reactivity and specialized applications. With the molecular formula C6H15B and a molecular weight of 98 g/mol, triethylborane exhibits unique chemical properties that make it both valuable and hazardous in industrial processes. The compound is classified as a pyrophoric liquid (Pyr. Liq. 1) and skin corrosive substance (Skin Corr. 1B), requiring stringent safety protocols during handling and storage. Its pyrophoric nature means it ignites spontaneously upon contact with air at temperatures below 54°C, necessitating inert atmosphere conditions throughout its lifecycle. The ADR transport classification 4.2 reflects these inherent fire hazards, while GHS pictograms GHS02 and GHS05 warn of both flammability and corrosive properties. Triethylborane finds primary applications as a polymerization initiator in the production of specialized polymers, where its controlled reactivity enables precise chain initiation processes. It also serves as a reducing agent in organic synthesis and as a catalyst component in various chemical transformations. Unlike related organometallic compounds such as tripropylalumane, triethylborane offers unique selectivity profiles in synthetic applications. The compound's extreme sensitivity to moisture and oxygen demands specialized storage under nitrogen or argon atmospheres, with rigorous exclusion of air and water. Safety protocols must address both its corrosive effects on skin and respiratory tissues, as well as fire prevention measures. OYSI provides technical-grade triethylborane to qualified industrial customers with appropriate handling capabilities and safety infrastructure.
Safety & Classification
Pyr. Liq. 1; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Triethylboran, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is triethylborane?
Triethylborane is an organoborane compound with the molecular formula C6H15B and CAS number 97-94-9. This chemical consists of a boron atom bonded to three ethyl groups, giving it a molecular weight of 98 g/mol. It appears as a colorless liquid that is highly pyrophoric, meaning it spontaneously ignites in air at room temperature. Triethylborane is classified as a highly hazardous substance due to its extreme flammability and corrosive properties.
What are the physicochemical properties of triethylborane?
Triethylborane is a colorless, volatile liquid with a molecular weight of 98 g/mol. The compound is extremely air-sensitive and pyrophoric, igniting spontaneously upon contact with oxygen. It has a characteristic pungent odor and is soluble in organic solvents but reacts violently with water and alcohols. The substance has a low boiling point and high vapor pressure, making it highly volatile under normal conditions.
What is triethylborane used for?
Triethylborane is primarily used as a radical initiator in polymerization reactions, particularly in the production of specialized polymers and plastics. It serves as a catalyst in organic synthesis, especially in hydroboration reactions and as a reducing agent. The compound is also utilized in semiconductor manufacturing processes and as a dopant source for boron in electronic materials. Additionally, it finds applications in research laboratories for specialized chemical transformations.
How to handle triethylborane safely?
Triethylborane must be handled under inert atmosphere conditions using proper personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. All work should be conducted in a well-ventilated area or fume hood away from ignition sources. Use only non-sparking tools and ensure fire extinguishing equipment is readily available. Personnel must be trained in pyrophoric liquid handling procedures and emergency response protocols before working with this substance.
How to store triethylborane correctly?
Triethylborane must be stored under inert gas atmosphere in tightly sealed containers away from air, moisture, and heat sources. Storage areas should be cool, dry, and well-ventilated with appropriate fire suppression systems. The substance is incompatible with water, alcohols, oxidizing agents, and acids. Containers should be made of suitable materials and properly labeled according to GHS requirements with appropriate hazard pictogrammes GHS02 and GHS05.
What to do in case of contact with triethylborane?
Triethylborane contact requires immediate emergency response due to its corrosive nature. In case of skin contact, immediately remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. For eye contact, rinse immediately with water and seek medical attention. If inhaled, move person to fresh air and provide oxygen if breathing is difficult. Do not use water on spilled material due to violent reaction risk.
How to dispose of triethylborane appropriately?
Triethylborane disposal must be conducted by licensed hazardous waste disposal companies following strict regulatory guidelines. The substance cannot be disposed of through normal waste streams due to its pyrophoric and corrosive properties. Small quantities should be carefully quenched under controlled conditions by trained professionals. All disposal activities must comply with local environmental regulations and proper documentation must be maintained throughout the disposal process.
How to transport triethylborane?
Triethylborane is classified under ADR Class 4.2 (Spontaneously Combustible Substances) Packing Group I, indicating maximum danger level. Transportation requires specialized packaging, proper labeling with danger placards, and compliance with dangerous goods regulations. Only authorized carriers trained in hazardous materials transport can handle shipments. Vehicles must be equipped with appropriate safety equipment and emergency response materials during transport.
Is triethylborane subject to specific regulations?
Triethylborane is subject to comprehensive chemical safety regulations including REACH registration, CLP classification requirements, and dangerous goods transport regulations. The substance is classified as Pyr. Liq. 1 and Skin Corr. 1B under CLP regulation. It requires safety data sheets, proper labeling with danger signal word, and compliance with occupational exposure limits. The compound is not currently listed as a Substance of Very High Concern (SVHC) under REACH.
Where to buy triethylborane in Europe?
Triethylborane is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI can provide this highly specialized organoborane compound to qualified industrial and research customers. Due to the substance's hazardous nature, purchases typically require proper safety documentation, trained personnel, and appropriate storage facilities. Contact OYSI directly for availability, technical specifications, and regulatory compliance support for your specific application requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.