Triethylborane

C6H15B

triethylborane

CAS97-94-9
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
97-94-9
EC Number
202-620-9
UN Number
3394
Index Number
005-004-01-3
PubChem CID
7357

Physical-chemical properties

Molecular Formula
C6H15B
Molar Mass
98.00 g/mol
IUPAC Name
triethylborane

Chemical Identifiers

InChI
InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI Key
LALRXNPLTWZJIJ-UHFFFAOYSA-N

Overview

Triethylborane (CAS 97-94-9) is an organoborane compound with pyrophoric properties and strong corrosive characteristics. This colorless liquid represents one of the most important trialkylborane compounds in industrial chemistry, featuring three ethyl groups bonded to a central boron atom. As a highly reactive organometallic compound, triethylborane exhibits spontaneous ignition when exposed to air, classifying it as a pyrophoric liquid under GHS Category 1. The compound's extreme reactivity stems from the electron-deficient nature of boron, which readily forms bonds with oxygen-containing molecules. The substance poses significant safety challenges due to its dual hazard profile. Its pyrophoric nature requires strict handling under inert atmosphere conditions, while its corrosive properties (Skin Corr. 1B) demand appropriate personal protective equipment and containment systems. The ADR Class 4.2 classification reflects its spontaneously combustible nature, necessitating specialized transportation and storage protocols. In industrial applications, triethylborane serves primarily as a polymerization initiator in the production of specialized polymers and as a reducing agent in organic synthesis. The pharmaceutical industry utilizes this compound for selective hydroboration reactions, enabling the synthesis of complex molecular structures. Additionally, it functions as a flame ignition source in advanced propulsion systems due to its reliable pyrophoric characteristics. Like other organometallic compounds such as tripropylalumane, triethylborane requires careful handling expertise and appropriate infrastructure. Its reactivity profile differs significantly from alkali metal derivatives like sodium methanolate, demanding specialized storage under rigorously maintained inert conditions. OYSI provides triethylborane to qualified industrial customers with comprehensive technical support and safety documentation for professional applications.

Safety & Classification

Danger
Classification:

Pyr. Liq. 1; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H250

Catches fire spontaneously if exposed to air.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameTriethylboran, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is triethylborane?

Triethylborane is an organoborane compound with the molecular formula C6H15B and CAS number 97-94-9. This chemical has a molecular weight of 98 g/mol and consists of a boron atom bonded to three ethyl groups. It is classified as a pyrophoric liquid and skin corrosive substance, making it highly reactive and dangerous to handle. Triethylborane is widely used in chemical synthesis and industrial applications requiring precise boron chemistry reactions.

What are the physicochemical properties of triethylborane?

Triethylborane is a colorless, pyrophoric liquid that ignites spontaneously upon contact with air at room temperature. It has a characteristic unpleasant odor and is highly reactive with water and oxygen. The compound is soluble in most organic solvents but reacts violently with protic solvents. Its pyrophoric nature means it must be handled under inert atmosphere conditions to prevent spontaneous combustion and dangerous reactions.

What is triethylborane used for?

Triethylborane is primarily used as a radical initiator in polymerization reactions and as a reducing agent in organic synthesis. It serves as a boron source in semiconductor manufacturing and is employed in hydroboration reactions for alkene functionalization. The compound is also used in specialized chemical research applications requiring precise control of radical chemistry and in the production of advanced materials where boron incorporation is essential.

How to handle triethylborane safely?

Triethylborane must be handled under strict inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or fume hoods with inert gas purging. Due to its pyrophoric and corrosive nature, avoid contact with air, water, and skin. Emergency shower and eyewash stations should be readily accessible during handling operations.

How to store triethylborane correctly?

Triethylborane must be stored in tightly sealed containers under inert atmosphere (nitrogen or argon) in a cool, dry location away from heat sources and ignition sources. Storage areas should be well-ventilated and equipped with appropriate fire suppression systems. The compound should be kept away from oxidizing agents, water, and incompatible materials. Containers must be properly labeled and stored in designated chemical storage areas with restricted access.

What to do in case of contact with triethylborane?

Immediate medical attention is required for any contact with triethylborane due to its corrosive properties. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical care. If inhaled, move to fresh air and provide oxygen if breathing is difficult. Never induce vomiting if ingested.

How to dispose of triethylborane appropriately?

Triethylborane disposal must comply with local and international hazardous waste regulations due to its pyrophoric and corrosive properties. The compound should be carefully quenched under controlled conditions by trained professionals using appropriate inert atmosphere techniques. Disposal must be performed by licensed hazardous waste contractors following proper classification procedures. Never dispose of triethylborane in regular waste streams or pour down drains due to fire and environmental hazards.

How to transport triethylborane?

Triethylborane is classified under ADR Class 4.2 (Substances liable to spontaneous combustion) with Packing Group I, indicating maximum danger level. Transportation requires specialized packaging designed for pyrophoric liquids and must comply with dangerous goods regulations. Vehicles must carry appropriate emergency equipment and documentation. Only trained personnel should handle transportation, and specific routing restrictions may apply depending on local regulations and quantities transported.

Is triethylborane subject to particular regulations?

Triethylborane is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification as a pyrophoric liquid and skin corrosive substance. It carries GHS pictograms GHS02 and GHS05 with the signal word 'Danger'. The compound is not classified as an SVHC substance but requires strict handling protocols due to its hazardous properties and potential workplace exposure risks.

Where to buy triethylborane in Europe?

Triethylborane is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across Europe. As a professional chemical distributor, OYSI ensures proper handling, packaging, and documentation compliance for this hazardous material. Due to the specialized nature and safety requirements of triethylborane, procurement should only be through qualified chemical suppliers with appropriate licensing and safety expertise.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.