Dioctylalumanylium iodide
C16H34AlI
dioctylalumanylium iodide
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Identification
- CAS Number
- 7585-14-0
- EC Number
- 408-190-0
- UN Number
- 3394
- Index Number
- 013-008-00-4
- PubChem CID
- 21923582
Physical-chemical properties
- Molecular Formula
- C16H34AlI
- Molar Mass
- 380.33 g/mol
- IUPAC Name
- dioctylalumanylium iodide
Chemical Identifiers
- InChI
- InChI=1S/2C8H17.Al.HI/c2*1-3-5-7-8-6-4-2;;/h2*1,3-8H2,2H3;;1H/q;;+1;/p-1
- InChI Key
- AGQPHHBPENBBIO-UHFFFAOYSA-M
Overview
Dioctylalumanylium iodide (CAS 7585-14-0) is an organoaluminum compound with pyrophoric properties and strong corrosive characteristics. This specialized organoaluminum chemical represents an important class of metalorganic compounds widely utilized in industrial applications requiring reactive aluminum-carbon bonds. With the molecular formula C16H34AlI and a molecular weight of 380.33 g/mol, dioctylalumanylium iodide exhibits distinctive chemical properties that make it valuable for specific synthetic processes and catalytic applications. The compound's classification as a pyrophoric liquid (Pyr. Liq. 1) indicates its tendency to ignite spontaneously upon contact with air, requiring careful handling protocols and specialized storage conditions. Its corrosive nature (Skin Corr. 1B) demands appropriate personal protective equipment and containment measures during handling. The aquatic toxicity classifications (Aquatic Acute 1; Aquatic Chronic 1) reflect its potential environmental impact, necessitating proper waste management procedures. Safety considerations are paramount when working with dioctylalumanylium iodide, as indicated by the GHS02, GHS05, and GHS09 pictograms representing fire hazard, corrosion, and environmental danger respectively. The ADR class 4.2 classification requires specialized transportation protocols for self-heating substances. Like other reactive organometallic compounds such as tripropylalumane, this material demands inert atmosphere handling to prevent unwanted reactions with moisture or oxygen. Primary industrial applications include catalytic processes in organic synthesis, polymerization reactions, and specialized chemical manufacturing where controlled aluminum insertion is required. The compound serves as an important reagent in advanced materials synthesis and pharmaceutical intermediate production. OYSI maintains reliable supply chains for dioctylalumanylium iodide, ensuring consistent availability for European industrial customers requiring this specialized organoaluminum compound.
Safety & Classification
Pyr. Liq. 1; Skin Corr. 1B; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Dioctylaluminiumiodid, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is dioctylalumanylium iodide?
Dioctylalumanylium iodide is an organometallic compound with the chemical formula C16H34AlI and CAS number 7585-14-0. This aluminum-based chemical has a molecular weight of 380.33 g/mol and belongs to the class of pyrophoric liquids, meaning it can spontaneously ignite upon contact with air. It is classified as a highly hazardous substance requiring specialized handling procedures due to its corrosive and environmentally dangerous properties.
What are the physicochemical properties of dioctylalumanylium iodide?
Dioctylalumanylium iodide is a pyrophoric liquid that exhibits extreme reactivity with air and moisture. As an organometallic compound containing aluminum and iodine, it demonstrates corrosive properties and requires inert atmosphere storage. The substance poses significant environmental hazards to aquatic ecosystems. Its pyrophoric nature means it can spontaneously combust when exposed to atmospheric conditions, making proper containment essential for safe handling.
What is dioctylalumanylium iodide used for?
Dioctylalumanylium iodide is primarily used as a specialized reagent in organometallic synthesis and catalytic applications. Its unique aluminum-iodine structure makes it valuable in advanced chemical processes requiring precise reactivity control. The compound finds applications in research laboratories and specialized industrial processes where its specific chemical properties are essential. Due to its hazardous nature, its use is typically restricted to professional settings with appropriate safety infrastructure.
How to safely handle dioctylalumanylium iodide?
Dioctylalumanylium iodide requires handling under strict inert atmosphere conditions due to its pyrophoric nature. Personnel must wear full protective equipment including chemical-resistant gloves, face shields, and protective clothing. All operations must be conducted in well-ventilated areas or fume hoods with fire suppression systems readily available. Contact with air, moisture, and incompatible materials must be prevented at all times to avoid spontaneous ignition or violent reactions.
How to store dioctylalumanylium iodide correctly?
Dioctylalumanylium iodide must be stored under inert gas atmosphere in tightly sealed, compatible containers away from sources of ignition, heat, and moisture. Storage areas should be equipped with appropriate fire suppression systems and maintained at stable temperatures. The substance must be kept separate from oxidizing agents, water, alcohols, and other reactive materials. Storage facilities should comply with regulations for pyrophoric liquids and have emergency response procedures in place.
What to do in case of contact with dioctylalumanylium iodide?
Immediate action is required for any contact with dioctylalumanylium iodide due to its corrosive nature. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes while seeking immediate medical attention. In case of eye contact, rinse thoroughly with water and obtain emergency medical care. For inhalation exposure, move to fresh air immediately and seek medical assistance. Never delay medical treatment for any exposure incident.
How to properly dispose of dioctylalumanylium iodide?
Dioctylalumanylium iodide disposal requires specialized hazardous waste management procedures due to its pyrophoric and corrosive properties. The substance must be neutralized by trained professionals using appropriate quenching agents under controlled conditions. Disposal must comply with local and EU waste regulations for dangerous substances. Only licensed hazardous waste disposal companies should handle the final disposal process. Never attempt disposal through normal waste streams or discharge into the environment.
How to transport dioctylalumanylium iodide?
Dioctylalumanylium iodide is classified under ADR Class 4.2 (substances liable to spontaneous combustion) with Packing Group I, indicating maximum danger level. Transportation requires specialized containers meeting UN specifications for pyrophoric liquids, proper labeling with GHS02, GHS05, and GHS09 pictograms, and documentation indicating 'Danger' signal word. Only certified dangerous goods transporters should handle shipment, following strict ADR regulations for pyrophoric substances throughout the transport chain.
Is dioctylalumanylium iodide subject to specific regulations?
Dioctylalumanylium iodide is subject to comprehensive EU chemical regulations including REACH registration requirements and CLP classification as Pyr. Liq. 1, Skin Corr. 1B, Aquatic Acute 1, and Aquatic Chronic 1. While not currently listed as a SVHC, it requires strict compliance with occupational safety directives and environmental protection regulations. Users must implement appropriate risk management measures and may need special permits for handling, storage, and use depending on local authorities.
Where to buy dioctylalumanylium iodide in Europe?
Dioctylalumanylium iodide is available through OYSI, a specialized European distributor of technical chemicals with expertise in handling dangerous substances. As a professional chemical supplier, OYSI ensures proper packaging, documentation, and regulatory compliance for this highly hazardous material. Due to the substance's dangerous properties, procurement typically requires verification of proper handling facilities and qualified personnel. Contact OYSI directly for availability, technical specifications, and regulatory requirements for your specific application.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.