Disodium;sulfanide

HNa2S+

disodium;sulfanide

CAS1313-82-2
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1313-82-2
EC Number
215-211-5
UN Number
1849
Index Number
016-009-00-8
PubChem CID
237873

Physical-chemical properties

Molecular Formula
HNa2S+
Molar Mass
79.06 g/mol
IUPAC Name
disodium;sulfanide

Chemical Identifiers

InChI
InChI=1S/2Na.H2S/h;;1H2/q2*+1;/p-1
InChI Key
VDQVEACBQKUUSU-UHFFFAOYSA-M

Overview

Disodium sulfanide (CAS 1313-82-2) is an inorganic sodium salt compound with highly corrosive properties and acute toxicity characteristics. This chemical substance, also identified by EC number 215-211-5, presents as a sodium sulfide compound with the molecular formula HNa2S+ and a molecular weight of 79.06 g/mol. The compound exhibits significant hazardous properties that require careful handling and storage protocols in industrial applications. Its classification under multiple danger categories including Acute Toxicity 3 and 4, Skin Corrosion 1B, and Aquatic Acute 1 demonstrates the serious safety considerations associated with this material. The substance displays strong corrosive characteristics, capable of causing severe skin burns and eye damage upon contact. Its acute toxicity profile necessitates stringent safety measures during handling, transport, and storage. The ADR Class 8 classification identifies it as a corrosive substance for transportation purposes, requiring specialized packaging and documentation. Environmental considerations are equally important, as the compound poses acute hazards to aquatic life, demanding careful waste management and containment procedures. Industrial applications of disodium sulfanide typically include chemical synthesis processes, metal processing operations, and specialized manufacturing applications where its reactive properties are utilized. The compound serves important functions in certain metallurgical processes and can be employed in chemical production alongside other sulfur-containing compounds. Unlike more complex molecules such as 2-chloro-5-(chloromethyl)-1,3-thiazole used in pharmaceutical synthesis, disodium sulfanide provides fundamental chemical reactivity for industrial processes. OYSI maintains professional-grade supplies of disodium sulfanide for qualified industrial customers throughout Europe, ensuring proper documentation, safety data sheets, and regulatory compliance for all shipments of this controlled chemical substance.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Acute Tox. 4 *; Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H311

Toxic in contact with skin.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1849
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameNatriumsulfid, hydratisiert, Kristallwasser >= 30 %, fest
Marine PollutantNo

Frequently Asked Questions

What is disodium sulfanide?

Disodium sulfanide is an inorganic chemical compound with the molecular formula HNa2S+ and CAS number 1313-82-2. This substance has a molecular weight of 79.06 g/mol and is classified as a hazardous material due to its acute toxicity and corrosive properties. It is commonly used in various industrial applications and requires careful handling due to its dangerous classification under GHS regulations.

What are the physicochemical properties of disodium sulfanide?

Disodium sulfanide is an inorganic salt with a molecular mass of 79.06 g/mol and chemical formula HNa2S+. As a sodium sulfide compound, it typically appears as a crystalline solid at room temperature and is highly soluble in water. The substance exhibits strong alkaline properties and can release hydrogen sulfide gas under certain conditions, contributing to its hazardous nature.

What is disodium sulfanide used for?

Disodium sulfanide is primarily used in industrial applications including metal processing, leather tanning, and textile manufacturing. It serves as a reducing agent in chemical synthesis, a precipitating agent for heavy metals in water treatment, and as an intermediate in the production of sulfur dyes. The compound is also utilized in mining operations for ore flotation and in the paper industry for pulping processes.

How to handle disodium sulfanide safely?

Disodium sulfanide requires strict safety measures due to its Acute Tox. 3, Acute Tox. 4, and Skin Corr. 1B classifications. Personnel must wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid direct contact with skin, eyes, and respiratory system, and ensure emergency shower and eyewash stations are readily accessible.

How to store disodium sulfanide correctly?

Disodium sulfanide must be stored in a cool, dry, and well-ventilated area away from incompatible materials such as acids and oxidizing agents. The substance should be kept in tightly sealed containers to prevent moisture absorption and contamination. Storage areas must be equipped with appropriate spill containment measures and should be separated from food, feed, and drinking water supplies according to chemical storage regulations.

What to do in case of contact with disodium sulfanide?

Disodium sulfanide exposure requires immediate action due to its corrosive properties. In case of skin contact, immediately remove contaminated clothing and rinse affected area with copious amounts of water for at least 15 minutes. For eye contact, flush thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Always consult a physician after any exposure incident.

How to dispose of disodium sulfanide appropriately?

Disodium sulfanide disposal must comply with local and international hazardous waste regulations due to its toxic and corrosive nature. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal facilities. Small quantities may be neutralized following approved procedures, but large amounts must be collected and disposed of professionally. Always consult local environmental authorities for specific disposal requirements.

How to transport disodium sulfanide?

Disodium sulfanide is classified as ADR Class 8 (Corrosive substances) Group II for transportation purposes. The substance must be packaged in UN-approved containers with appropriate hazard labels including GHS06, GHS05, and GHS09 pictograms. Transport documents must include the proper shipping name, UN number, and emergency response information. Only trained personnel should handle transportation, and vehicles must be equipped with appropriate spill response materials.

Is disodium sulfanide subject to particular regulations?

Disodium sulfanide is subject to multiple regulatory frameworks including REACH registration requirements in Europe and CLP classification obligations. The substance carries a 'Danger' signal word and must be labeled with specific GHS pictograms (GHS06, GHS05, GHS09). While not currently listed as a SVHC (Substance of Very High Concern), it requires compliance with occupational exposure limits and environmental discharge restrictions due to its Aquatic Acute 1 classification.

Where to buy disodium sulfanide in Europe?

Disodium sulfanide is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides this substance with full regulatory compliance documentation including safety data sheets and certificates of analysis. As an established chemical distributor, OYSI ensures proper packaging, labeling, and transportation according to ADR regulations while maintaining high quality standards for industrial customers across Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.