Dipotassium;sulfide

K2S

dipotassium;sulfide

CAS1312-73-8
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1312-73-8
EC Number
215-197-0
UN Number
1382
Index Number
016-006-00-1
PubChem CID
162263

Physical-chemical properties

Molecular Formula
K2S
Molar Mass
110.26 g/mol
IUPAC Name
dipotassium;sulfide

Chemical Identifiers

InChI
InChI=1S/2K.S/q2*+1;-2
InChI Key
DPLVEEXVKBWGHE-UHFFFAOYSA-N

Overview

Dipotassium sulfide (CAS 1312-73-8) is an inorganic salt with highly alkaline properties and significant reactivity with water and acids. This white to yellowish crystalline compound, with the molecular formula K2S and a molecular weight of 110.26 g/mol, represents one of the most reactive sulfur-containing potassium compounds used in industrial applications. Dipotassium sulfide demonstrates exceptional solubility in water, forming strongly alkaline solutions that can reach pH values above 12. The compound's hygroscopic nature means it readily absorbs moisture from air, often appearing as a deliquescent solid under ambient conditions. From a safety perspective, dipotassium sulfide presents significant hazards requiring careful handling protocols. Classified as Skin Corr. 1B under GHS regulations, it causes severe skin burns and eye damage upon contact. The compound also carries an Aquatic Acute 1 classification, indicating high toxicity to aquatic life. Its ADR Class 4.2 designation reflects its potential for spontaneous heating and combustion under certain conditions, particularly when exposed to moisture or acids, which can generate toxic hydrogen sulfide gas. Industrial applications of dipotassium sulfide center primarily around its role as a reducing agent and sulfur source in chemical synthesis. The compound serves as a crucial intermediate in the production of organic sulfur compounds and finds use in metallurgical processes for ore treatment and metal recovery. In the leather industry, it functions as a depilatory agent, while its reducing properties make it valuable in certain photographic chemical formulations. Unlike related compounds such as potassium sulfane, dipotassium sulfide offers superior stability and handling characteristics for large-scale industrial operations. OYSI maintains reliable supply chains for dipotassium sulfide to support diverse European industrial requirements.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1382
ADR Class4.2
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameKaliumsulfid, wasserfrei, fest
Marine PollutantNo

Frequently Asked Questions

What is dipotassium sulfide?

Dipotassium sulfide is an inorganic chemical compound with the molecular formula K2S and CAS number 1312-73-8. It has a molecular weight of 110.26 g/mol and belongs to the family of alkali metal sulfides. This compound is classified as a corrosive substance (Skin Corr. 1B) and poses acute aquatic toxicity hazards (Aquatic Acute 1), requiring careful handling and storage procedures in industrial applications.

What are the physicochemical properties of dipotassium sulfide?

Dipotassium sulfide appears as a white to yellowish crystalline solid at room temperature. It is highly hygroscopic, readily absorbing moisture from air, and exhibits excellent solubility in water, forming strongly alkaline solutions. The compound is sensitive to air and moisture, decomposing gradually when exposed to atmospheric conditions. It has a characteristic sulfide odor and demonstrates typical ionic compound properties with high melting point characteristics.

What is dipotassium sulfide used for?

Dipotassium sulfide serves primarily as a chemical intermediate in various industrial processes. It is used in the production of other sulfur-containing compounds, as a reducing agent in metallurgical applications, and in certain specialized chemical syntheses. The compound finds applications in the preparation of sulfide-based materials and can be utilized in research laboratories for specific analytical procedures requiring sulfide ions.

How to handle dipotassium sulfide safely?

Dipotassium sulfide requires strict safety protocols due to its corrosive nature (Skin Corr. 1B classification). Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid contact with skin, eyes, and clothing, and ensure emergency eyewash stations and safety showers are readily accessible during handling operations.

How to store dipotassium sulfide correctly?

Dipotassium sulfide must be stored in tightly sealed, moisture-proof containers away from humid conditions due to its hygroscopic nature. Keep containers in cool, dry, well-ventilated areas away from incompatible materials such as acids, oxidizing agents, and moisture sources. Storage areas should be equipped with appropriate spill containment measures and maintained at stable temperatures to prevent degradation and ensure product integrity.

What to do in case of contact with dipotassium sulfide?

Immediate action is required due to dipotassium sulfide's corrosive properties. For skin contact, immediately remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If ingested, do not induce vomiting and seek urgent medical care. Always consult the safety data sheet for complete first aid procedures.

How to dispose of dipotassium sulfide appropriately?

Dipotassium sulfide disposal must comply with local, national, and EU waste regulations due to its hazardous classification. The compound cannot be disposed of through regular waste streams and requires treatment as hazardous chemical waste. Contact authorized waste disposal companies specialized in handling corrosive and environmentally hazardous materials. Neutralization procedures should only be performed by trained professionals following established protocols for sulfide-containing compounds.

How to transport dipotassium sulfide?

Dipotassium sulfide is classified under ADR Class 4.2 (substances liable to spontaneous combustion), Packing Group II, indicating moderate danger level during transport. Packages must comply with UN packaging requirements and bear appropriate hazard labels including GHS05 (corrosion) and GHS09 (environmental hazard) pictograms. Transportation requires proper documentation, trained personnel, and adherence to dangerous goods regulations for road transport within Europe.

Is dipotassium sulfide subject to particular regulations?

Dipotassium sulfide falls under European CLP regulation requiring hazard classification and labeling with 'Danger' signal word and specific pictograms (GHS05, GHS09). The substance is not currently listed as SVHC under REACH regulation. However, its corrosive and aquatic toxicity properties subject it to standard chemical safety requirements, workplace exposure limits, and environmental protection measures mandated by EU chemical legislation.

Where to buy dipotassium sulfide in Europe?

Dipotassium sulfide is available through OYSI, a specialized European distributor of technical chemicals. As an established chemical supplier, OYSI provides this compound to industrial customers, research institutions, and professional users across Europe. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements. Ensure your application complies with regulatory requirements and that proper handling facilities are in place before ordering.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.