Sodium N-methylcarbamodithioate
C2H4NNaS2
sodium N-methylcarbamodithioate
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Identification
- CAS Number
- 137-42-8
- EC Number
- 205-293-0
- UN Number
- 2923
- Index Number
- 006-013-00-8
- PubChem CID
- 5366415
Physical-chemical properties
- Molecular Formula
- C2H4NNaS2
- Molar Mass
- 129.18 g/mol
- IUPAC Name
- sodium N-methylcarbamodithioate
Chemical Identifiers
- InChI
- InChI=1S/C2H5NS2.Na/c1-3-2(4)5;/h1H3,(H2,3,4,5);/q;+1/p-1
- InChI Key
- AFCCDDWKHLHPDF-UHFFFAOYSA-M
Overview
Sodium N-methylcarbamodithioate (CAS 137-42-8) is an organosulfur dithiocarbamate compound with corrosive properties and acute toxicity characteristics. This chemical substance, also known by its IUPAC designation sodium N-methylcarbamodithioate, belongs to the dithiocarbamate family of compounds characterized by their sulfur-containing functional groups. With a molecular formula of C2H4NNaS2 and molecular weight of 129.18 g/mol, this sodium salt exhibits distinctive chemical properties that make it valuable in various industrial applications while requiring careful handling due to its hazardous nature. The compound presents significant safety considerations, classified under multiple hazard categories including Acute Toxicity 4, Skin Corrosion 1B, and Skin Sensitization 1. Its corrosive properties necessitate appropriate personal protective equipment and containment measures during handling and storage. The substance also demonstrates acute and chronic aquatic toxicity, requiring environmental precautions. Transportation falls under ADR Class 8, reflecting its corrosive classification, with GHS pictograms GHS07, GHS05, and GHS09 indicating health hazards, corrosivity, and environmental dangers respectively. Industrial applications primarily center around its role as a chemical intermediate and reagent in organic synthesis processes. The compound finds use in agricultural chemical manufacturing and serves as a precursor in the production of specialized chemical formulations. Its reactivity profile makes it particularly suitable for applications requiring sulfur-containing moieties, similar to other organosulfur compounds like [5-(sulfanylmethyl)-1,4-dithian-2-yl]methanethiol, though with distinct chemical behavior patterns. OYSI maintains availability of sodium N-methylcarbamodithioate for qualified industrial customers, ensuring compliance with all relevant European chemical regulations and safety standards.
Safety & Classification
Acute Tox. 4 *; Skin Corr. 1B; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2923 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Metam-natrium (ISO) |
| Marine Pollutant | No |
Frequently Asked Questions
What is sodium N-methylcarbamodithioate?
Sodium N-methylcarbamodithioate is an organosulfur chemical compound with the molecular formula C2H4NNaS2 and CAS number 137-42-8. This sodium salt of N-methylcarbamodithioic acid has a molecular weight of 129.18 g/mol and belongs to the dithiocarbamate family of chemicals. It is classified as a hazardous substance requiring careful handling due to its corrosive properties and potential health effects.
What are the physicochemical properties of sodium N-methylcarbamodithioate?
Sodium N-methylcarbamodithioate is typically a crystalline solid at room temperature with good water solubility due to its ionic sodium salt structure. The compound exhibits hygroscopic properties and may have a characteristic sulfur-like odor. Its dithiocarbamate structure makes it chemically reactive, particularly susceptible to decomposition under acidic conditions or elevated temperatures, which can release toxic gases.
What is sodium N-methylcarbamodithioate used for?
Sodium N-methylcarbamodithioate is primarily used as a biocide and preservative in industrial applications, particularly in metalworking fluids, cooling systems, and water treatment processes. It serves as an effective antimicrobial agent against bacteria and fungi. The compound is also utilized in rubber vulcanization processes and as an intermediate in the synthesis of other chemical compounds in specialized industrial applications.
How to handle sodium N-methylcarbamodithioate safely?
Sodium N-methylcarbamodithioate requires strict safety measures due to its corrosive and sensitizing properties. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent inhalation exposure. Avoid skin and eye contact completely. Work in well-ventilated areas or under fume hoods, and have emergency eyewash stations readily available.
How to store sodium N-methylcarbamodithioate correctly?
Sodium N-methylcarbamodithioate must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep separated from acids, strong oxidizers, and incompatible materials to prevent dangerous reactions. Store in original labeled containers with proper hazard identification. Maintain storage temperature below 25°C and protect from moisture to prevent decomposition and maintain product stability.
What to do in case of contact with sodium N-methylcarbamodithioate?
Immediate action is required for any contact with sodium N-methylcarbamodithioate due to its corrosive nature. For skin contact, immediately remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. For eye contact, rinse continuously with water and seek immediate medical attention. If inhaled, move to fresh air immediately. In all cases of exposure, contact emergency medical services promptly.
How to dispose of sodium N-methylcarbamodithioate appropriately?
Sodium N-methylcarbamodithioate disposal must comply with local and European waste regulations due to its hazardous classification. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper handling. Never discharge into sewers, water bodies, or soil. Containers must be completely emptied and treated as hazardous waste unless properly decontaminated.
How to transport sodium N-methylcarbamodithioate?
Sodium N-methylcarbamodithioate is classified under ADR Class 8 (Corrosive substances), Packing Group II, requiring specialized transport procedures. Packages must bear appropriate hazard labels including corrosive substance markings. Transport vehicles need proper documentation, emergency response information, and drivers must have ADR certification. Use approved packaging materials resistant to corrosion and ensure proper segregation from incompatible substances during transport.
Is sodium N-methylcarbamodithioate subject to specific regulations?
Sodium N-methylcarbamodithioate is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification as a corrosive and sensitizing substance. It carries aquatic toxicity classifications requiring environmental protection measures. While not currently listed as an SVHC, users must comply with occupational exposure limits, worker protection requirements, and environmental discharge restrictions. Regular safety data sheet updates are mandatory.
Where to buy sodium N-methylcarbamodithioate in Europe?
Sodium N-methylcarbamodithioate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this regulated substance to qualified industrial customers with proper documentation and safety data sheets. As a professional chemical distributor, OYSI ensures compliance with European regulations and provides technical support for safe handling and application guidance to authorized users across European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.