Sodium N-methylcarbamodithioate
C2H4NNaS2
sodium N-methylcarbamodithioate
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Identification
- CAS Number
- 137-42-8
- EC Number
- 205-293-0
- UN Number
- 2923
- Index Number
- 006-013-00-8
- PubChem CID
- 5366415
Physical-chemical properties
- Molecular Formula
- C2H4NNaS2
- Molar Mass
- 129.18 g/mol
- IUPAC Name
- sodium N-methylcarbamodithioate
Chemical Identifiers
- InChI
- InChI=1S/C2H5NS2.Na/c1-3-2(4)5;/h1H3,(H2,3,4,5);/q;+1/p-1
- InChI Key
- AFCCDDWKHLHPDF-UHFFFAOYSA-M
Overview
Sodium N-methylcarbamodithioate (CAS 137-42-8) is an organosulfur chemical compound with corrosive properties and industrial applications as a metal complexing agent. This sodium salt of N-methylcarbamodithioic acid represents an important class of dithiocarbamate compounds widely utilized in industrial chemistry. With the molecular formula C2H4NNaS2 and a molar mass of 129.18 g/mol, this crystalline compound exhibits distinctive chemical reactivity due to its dual sulfur functionality and methylcarbamate structure. The compound is classified under EC number 205-293-0 and requires careful handling protocols due to its hazardous properties. Safety considerations are paramount when working with sodium N-methylcarbamodithioate, as it carries multiple hazard classifications including acute toxicity (Category 4), skin corrosion (Category 1B), skin sensitization, and significant aquatic toxicity. The compound displays GHS pictograms for health hazard (GHS07), corrosion (GHS05), and environmental danger (GHS09), with "Danger" as the signal word. Transportation falls under ADR Class 8, reflecting its corrosive nature. Primary industrial applications include metal ion precipitation and extraction processes, where its chelating properties prove valuable in hydrometallurgy and wastewater treatment. The compound also finds use in analytical chemistry for metal determination and as an intermediate in specialized chemical synthesis. Unlike structurally different compounds such as 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate, sodium N-methylcarbamodithioate's sulfur-based functionality makes it particularly effective for heavy metal complexation applications. OYSI maintains reliable supply chains for sodium N-methylcarbamodithioate to serve European industrial customers requiring this specialized chemical compound.
Safety & Classification
Acute Tox. 4 *; Skin Corr. 1B; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2923 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Metam-natrium (ISO) |
| Marine Pollutant | No |
Frequently Asked Questions
What is sodium N-methylcarbamodithioate?
Sodium N-methylcarbamodithioate is an organosulfur chemical compound with the molecular formula C2H4NNaS2 and CAS number 137-42-8. This sodium salt derivative contains dithiocarbamate functional groups and has a molecular weight of 129.18 g/mol. It is classified as a hazardous substance with corrosive properties to skin, acute toxicity potential, and significant environmental impact on aquatic ecosystems, requiring careful handling and storage protocols in industrial applications.
What are the physicochemical properties of sodium N-methylcarbamodithioate?
Sodium N-methylcarbamodithioate is typically a crystalline solid at room temperature with good water solubility due to its sodium salt nature. The compound exhibits hygroscopic properties and may decompose upon exposure to moisture and heat. Its dithiocarbamate structure contributes to its reactivity with metal ions and oxidizing agents. The substance requires protection from light and air exposure to maintain stability and prevent degradation of its active functional groups.
What is sodium N-methylcarbamodithioate used for?
Sodium N-methylcarbamodithioate is primarily used as a metal precipitation agent in water treatment processes and as an intermediate in chemical synthesis. It serves as a chelating agent for heavy metal removal from industrial wastewater and finds applications in analytical chemistry for metal detection and quantification. The compound is also utilized in rubber vulcanization processes and as a precursor for manufacturing other dithiocarbamate derivatives used in various industrial applications.
How to handle sodium N-methylcarbamodithioate safely?
Sodium N-methylcarbamodithioate must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its Skin Corr. 1B classification. Work should be conducted in well-ventilated areas or under fume extraction systems to prevent inhalation exposure. Avoid skin and eye contact, and prevent ingestion. Use non-sparking tools and equipment, and ensure emergency eyewash stations and safety showers are readily accessible in work areas.
How to store sodium N-methylcarbamodithioate correctly?
Sodium N-methylcarbamodithioate should be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep separated from strong oxidizing agents, acids, and incompatible materials to prevent dangerous reactions. Storage areas must be equipped with appropriate spill containment measures and should comply with local regulations for corrosive substances. Regular inspection of container integrity is essential to prevent leaks and contamination.
What to do in case of contact with sodium N-methylcarbamodithioate?
Skin contact with sodium N-methylcarbamodithioate requires immediate removal of contaminated clothing and thorough washing of affected areas with plenty of water for at least 15 minutes due to its corrosive nature. For eye contact, flush immediately with water for 15-20 minutes and seek medical attention. If ingested, do not induce vomiting and seek immediate medical care. In case of inhalation, move to fresh air and provide respiratory support if needed while obtaining medical assistance.
How to dispose of sodium N-methylcarbamodithioate properly?
Sodium N-methylcarbamodithioate waste must be disposed of through licensed hazardous waste disposal facilities in accordance with local and EU waste regulations. The substance cannot be disposed of in regular waste streams due to its corrosive properties and environmental toxicity. Neutralization or chemical treatment may be required before disposal, and waste containers must be properly labeled and documented. Consult local environmental authorities for specific disposal requirements and approved waste management contractors.
How to transport sodium N-methylcarbamodithioate?
Sodium N-methylcarbamodithioate is classified as ADR Class 8 (corrosive substances), Packing Group II, requiring specialized transport procedures and packaging. Shipments must use UN-approved containers with appropriate hazard labels and documentation. Transport vehicles must carry emergency response information and spill containment materials. Drivers require ADR certification for dangerous goods transport, and shipping documentation must include proper shipping names, hazard classifications, and emergency contact information for regulatory compliance.
Is sodium N-methylcarbamodithioate subject to specific regulations?
Sodium N-methylcarbamodithioate is subject to EU REACH regulation requiring registration for commercial use and CLP regulation for classification and labeling with GHS pictograms (GHS07, GHS05, GHS09). The substance requires safety data sheets and may have workplace exposure limits. Its aquatic toxicity classification subjects it to environmental discharge restrictions. While not currently listed as SVHC under REACH, users must comply with occupational health regulations and environmental protection requirements in their respective jurisdictions.
Where to buy sodium N-methylcarbamodithioate in Europe?
Sodium N-methylcarbamodithioate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides regulatory compliant supply with proper documentation including safety data sheets, certificates of analysis, and transport documentation. As a professional chemical distributor, OYSI ensures product quality, regulatory compliance, and reliable supply chain management for industrial applications requiring this specialized dithiocarbamate compound throughout European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.