Difluoromethane

CH2F2

difluoromethane

CAS75-10-5

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Identification

CAS Number
75-10-5
EC Number
200-839-4
UN Number
3252
PubChem CID
6345

Physical-chemical properties

Molecular Formula
CH2F2
Molar Mass
52.02 g/mol
IUPAC Name
difluoromethane

Chemical Identifiers

InChI
InChI=1S/CH2F2/c2-1-3/h1H2
InChI Key
RWRIWBAIICGTTQ-UHFFFAOYSA-N

Overview

Difluoromethane (CAS 75-10-5) is a colorless fluorinated hydrocarbon gas with low toxicity and excellent thermodynamic properties for refrigeration applications. This halogenated methane derivative, with the molecular formula CH2F2, represents an important member of the hydrofluorocarbon (HFC) family widely used in industrial cooling systems. Also known commercially as R-32, difluoromethane has gained significant attention as an environmentally preferred refrigerant due to its relatively low global warming potential compared to traditional chlorofluorocarbons. With a molecular weight of 52.023 g/mol, this compound exists as a gas under standard conditions and exhibits favorable thermophysical properties that make it particularly suitable for heat transfer applications. The substance demonstrates excellent chemical stability under normal operating conditions while maintaining low flammability characteristics. Its classification under ADR Class 2 reflects its compressed gas nature, requiring appropriate handling procedures and storage conditions. Unlike substances such as nitrous oxide, which finds applications in medical and food industries, difluoromethane is primarily valued for its refrigerant properties and thermal management capabilities. Key industrial applications include use as a refrigerant in air conditioning systems, heat pumps, and commercial refrigeration equipment. The compound also serves as a blowing agent in foam production and as a component in specialized cooling applications where precise temperature control is essential. Additionally, difluoromethane finds use in fire suppression systems where its inert properties and rapid heat absorption make it effective for protecting sensitive electronic equipment. OYSI maintains reliable supply chains for difluoromethane to support European industrial customers requiring consistent quality and delivery for their refrigeration and thermal management applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3252
ADR Class2
Packing Group
Tunnel CodeB/D
Proper Shipping NameDifluormethan, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is difluoromethane?

Difluoromethane is an organofluorine compound with the chemical formula CH2F2 and CAS number 75-10-5. It is a colorless gas at room temperature with a molecular weight of 52.023 g/mol. This compound belongs to the family of hydrofluorocarbons (HFCs) and is characterized by two fluorine atoms bonded to a central carbon atom along with two hydrogen atoms, making it a relatively simple fluorinated methane derivative.

What are the physicochemical properties of difluoromethane?

Difluoromethane is a colorless, odorless gas under standard conditions with a boiling point of approximately -51.6°C and a melting point of -136°C. It has low solubility in water but is soluble in organic solvents. The compound exhibits low toxicity and is non-flammable under normal atmospheric conditions. Its vapor density is approximately 1.8 times that of air, and it has relatively low reactivity due to the strong carbon-fluorine bonds.

What is difluoromethane used for?

Difluoromethane is primarily used as a refrigerant, particularly in automotive air conditioning systems and commercial refrigeration applications. It serves as a replacement for ozone-depleting substances and is commonly used in blended refrigerant mixtures. Additionally, it finds applications as a propellant in aerosol products, as a blowing agent for foam production, and in specialized industrial processes requiring low-temperature applications or inert atmospheres.

How to handle difluoromethane safely?

Difluoromethane should be handled in well-ventilated areas or under exhaust ventilation to prevent accumulation of vapors. Personnel should wear appropriate personal protective equipment including safety glasses and protective clothing. Since it is supplied as a pressurized gas, proper handling of gas cylinders is essential, including securing cylinders upright and using appropriate pressure regulators. Avoid exposure to high temperatures and ensure proper grounding when transferring the material.

How to store difluoromethane correctly?

Difluoromethane should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Gas cylinders must be stored upright, properly secured, and protected from physical damage. Storage areas should be equipped with appropriate ventilation systems and gas detection equipment. The compound should be kept away from incompatible materials and stored according to local regulations for pressurized gases. Regular inspection of storage containers is recommended.

What to do in case of contact with difluoromethane?

Difluoromethane exposure typically occurs through inhalation since it is a gas at room temperature. In case of overexposure, immediately move the affected person to fresh air and ensure they remain calm and warm. If breathing difficulties occur, provide oxygen and seek immediate medical attention. For skin contact with liquid form, remove contaminated clothing and flush the affected area with water. Eye contact should be treated by flushing with water for at least 15 minutes.

How to dispose of difluoromethane appropriately?

Difluoromethane must be disposed of according to local, national, and international environmental regulations due to its classification as a greenhouse gas. Empty cylinders should be returned to the supplier for proper reconditioning or disposal. Any remaining product should be recovered using appropriate refrigerant recovery equipment rather than being vented to the atmosphere. Professional waste disposal companies specializing in fluorinated gases should handle the disposal process to ensure environmental compliance.

How to transport difluoromethane?

Difluoromethane is classified under ADR Class 2 (gases) for transportation purposes. It must be transported in appropriate pressure vessels that meet relevant standards and regulations. Vehicles transporting this material should be properly placarded and equipped with necessary safety equipment. Drivers must hold appropriate dangerous goods training certificates. The compound should be transported with proper documentation including safety data sheets and transport emergency cards following applicable dangerous goods regulations.

Is difluoromethane subject to specific regulations?

Difluoromethane is subject to various regulatory frameworks including REACH registration in Europe and classification under the CLP regulation. It is regulated under the Montreal Protocol and EU F-Gas Regulation due to its global warming potential. The compound is not classified as a SVHC (Substance of Very High Concern) under REACH. Users must comply with reporting requirements for fluorinated greenhouse gases and ensure proper handling, recovery, and disposal according to environmental regulations.

Where to buy difluoromethane in Europe?

Difluoromethane is available through OYSI, a leading European distributor of technical chemicals and specialty gases. OYSI provides reliable supply chains across Europe with proper documentation, quality assurance, and regulatory compliance support. As a specialized chemical distributor, OYSI ensures that difluoromethane is supplied in appropriate packaging with complete safety data sheets and technical support. Contact OYSI directly for pricing, availability, and delivery options specific to your location and requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.