Cerium

Ce

cerium

CAS7440-45-1

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Identification

CAS Number
7440-45-1
EC Number
231-154-9
UN Number
1383
PubChem CID
23974

Physical-chemical properties

Molecular Formula
Ce
Molar Mass
140.12 g/mol
IUPAC Name
cerium

Chemical Identifiers

InChI
InChI=1S/Ce
InChI Key
GWXLDORMOJMVQZ-UHFFFAOYSA-N

Overview

Cerium (CAS 7440-45-1) is a rare earth metal element with silvery-white appearance and exceptional oxidation resistance properties. Cerium represents one of the most abundant rare earth elements, belonging to the lanthanide series of the periodic table. This soft, ductile metal exhibits remarkable chemical versatility, existing in both trivalent and tetravalent oxidation states, which makes it particularly valuable in various industrial applications. Unlike organometallic compounds such as tripropylalumane or trioctylalumane that are primarily used in specialized synthesis applications, cerium finds widespread use across multiple industries due to its unique electronic configuration and catalytic properties. The metal displays excellent thermal stability and forms a protective oxide layer when exposed to air, preventing further corrosion. Cerium's ability to easily switch between Ce³⁺ and Ce⁴⁺ oxidation states makes it an exceptional catalyst and additive in numerous chemical processes. From a safety perspective, cerium metal is classified under ADR Class 4.2 as a pyrophoric substance, requiring careful handling and storage under inert conditions to prevent spontaneous ignition. Key industrial applications include its use as a catalyst in automotive exhaust systems for emission control, as a polishing agent in glass and optical industries where its abrasive properties provide superior surface finishes, and as an additive in steel production to improve mechanical properties and reduce sulfur content. The electronics industry also utilizes cerium in specialized alloys and as a component in certain types of advanced batteries. OYSI provides high-quality cerium for European industrial customers, supporting diverse applications across automotive, metallurgical, and specialty chemical sectors.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1383
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameCer-Pulver, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is cerium?

Cerium is a rare earth metal belonging to the lanthanide series of elements, with the chemical symbol Ce and atomic number 58. It is the most abundant of the rare earth elements and appears as a silvery-white, soft metal that tarnishes readily in air. Cerium has unique properties including its ability to exist in multiple oxidation states and its pyrophoric nature in finely divided form.

What are the physicochemical properties of cerium?

Cerium is a silvery-white metallic solid at room temperature with a density of 6.77 g/cm³ and melting point of 798°C. It readily oxidizes in air, forming a protective oxide layer, and is relatively soft and malleable. Cerium is insoluble in water but dissolves in dilute acids. The metal exhibits pyrophoric behavior when finely divided, igniting spontaneously in air.

What is cerium used for?

Cerium is primarily used in catalytic converters for automotive exhaust systems due to its oxygen storage capacity. It serves as a polishing agent for glass and optical components, particularly in precision optics manufacturing. Other applications include lighter flints, arc carbons for studio lighting, phosphors in fluorescent lamps, and as an additive in special alloys and steel production.

How to handle cerium safely?

Cerium requires careful handling due to its pyrophoric properties in finely divided form. Use appropriate personal protective equipment including safety glasses, gloves, and protective clothing. Work in well-ventilated areas away from ignition sources and oxidizing materials. Avoid creating dust or fine particles, and handle bulk material with non-sparking tools. Keep fire extinguishing equipment readily available during handling operations.

How to store cerium correctly?

Cerium must be stored in a cool, dry place away from heat sources and ignition sources due to its pyrophoric nature. Keep containers tightly sealed to prevent oxidation and moisture exposure. Store away from strong oxidizing agents and acids. Use appropriate storage containers that prevent mechanical damage and dust generation. Maintain storage areas with adequate ventilation and fire prevention systems.

What to do in case of contact with cerium?

Cerium exposure requires immediate first aid measures depending on the contact type. For skin contact, remove contaminated clothing and wash affected area with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek medical attention. Always consult medical professionals for any exposure incidents.

How to dispose of cerium appropriately?

Cerium disposal must comply with local and European waste regulations as it is classified as hazardous waste. Do not dispose of cerium in regular waste streams or pour down drains. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities should be collected and stored safely until professional disposal can be arranged. Always follow national environmental protection guidelines.

How to transport cerium?

Cerium is classified under ADR Class 4.2 (Substances liable to spontaneous combustion) Packing Group I, indicating high transport risk. It requires specialized packaging meeting UN specifications and proper hazard labeling. Transport must be conducted by certified carriers with appropriate documentation including transport emergency cards. Vehicles must be equipped with suitable fire extinguishing equipment and emergency response materials.

Is cerium subject to specific regulations?

Cerium is regulated under various European frameworks including REACH registration requirements for commercial use. While not classified as SVHC (Substance of Very High Concern), it falls under CLP regulation for hazard communication. Transport is strictly regulated under ADR due to its pyrophoric properties. Industrial users must comply with occupational safety regulations and environmental protection standards for rare earth metals.

Where to buy cerium in Europe?

Cerium is available through specialized chemical distributors across Europe, with OYSI serving as a reliable European supplier for industrial customers. Due to its specialized nature and transport requirements, cerium is typically available through established chemical distribution networks rather than general suppliers. Professional buyers should ensure suppliers provide proper documentation, safety data sheets, and comply with ADR transport regulations for safe delivery.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.