Benzenesulfonic acid
C6H6O3S
benzenesulfonic acid
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Identification
- CAS Number
- 98-11-3
- EC Number
- 202-638-7
- UN Number
- 2585
- PubChem CID
- 7371
Physical-chemical properties
- Molecular Formula
- C6H6O3S
- Molar Mass
- 158.18 g/mol
- IUPAC Name
- benzenesulfonic acid
Chemical Identifiers
- InChI
- InChI=1S/C6H6O3S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H,7,8,9)
- InChI Key
- SRSXLGNVWSONIS-UHFFFAOYSA-N
Overview
Benzenesulfonic acid (CAS 98-11-3) is an aromatic sulfonic acid featuring a benzene ring directly bonded to a sulfonic acid group, exhibiting strong acidic properties and high water solubility. This fundamental aromatic compound represents one of the most important sulfonic acids in industrial chemistry, serving as a key intermediate in numerous chemical synthesis processes. The molecule consists of a benzene ring substituted with a sulfonic acid group (-SO₃H), which imparts strong acidic characteristics with a pKa value significantly lower than common carboxylic acids. This structural arrangement makes benzenesulfonic acid highly polar and readily soluble in water, while maintaining stability under various reaction conditions. As a member of the sulfonic acid family, benzenesulfonic acid shares certain properties with related aromatic compounds, though it differs significantly from halogenated derivatives such as 4-methoxybenzoyl chloride in terms of reactivity and handling requirements. The compound typically appears as a colorless to pale yellow liquid or crystalline solid, depending on concentration and temperature conditions. From a safety perspective, benzenesulfonic acid is classified under ADR Class 8 as a corrosive substance, requiring appropriate handling protocols to prevent skin and eye contact. While it does not carry specific GHS pictogram requirements, proper storage in corrosion-resistant containers and adequate ventilation remain essential safety considerations. The compound finds extensive application in the production of detergents and surfactants, where it serves as a precursor for sodium benzenesulfonate and related cleaning agents. Additionally, it functions as a catalyst in various organic synthesis reactions, particularly in esterification and alkylation processes. The pharmaceutical industry also utilizes benzenesulfonic acid as an intermediate in drug synthesis and as a counterion in salt formation. OYSI maintains reliable supply chains for benzenesulfonic acid to support diverse industrial applications across European markets.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 2585 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Benzensulfonsäure, freie Schwefelsäure <= 5 %, flüssig* |
| Marine Pollutant | No |
Frequently Asked Questions
What is benzenesulfonic acid?
Benzenesulfonic acid is an aromatic sulfonic acid with the chemical formula C6H6O3S and CAS number 98-11-3. This organic compound consists of a benzene ring with a sulfonic acid group (-SO3H) attached, giving it both aromatic and acidic properties. With a molecular weight of 158.18 g/mol, it serves as an important intermediate in chemical synthesis and industrial applications.
What are the physicochemical properties of benzenesulfonic acid?
Benzenesulfonic acid is a colorless to light yellow crystalline solid at room temperature with a characteristic acidic odor. It is highly soluble in water and polar solvents due to its sulfonic acid group, which makes it a strong acid. The compound is hygroscopic, meaning it readily absorbs moisture from air, and has good thermal stability under normal conditions.
What is benzenesulfonic acid used for?
Benzenesulfonic acid is primarily used as an intermediate in the production of detergents, pharmaceuticals, and dyes. It serves as a catalyst in various chemical reactions, particularly in esterification and polymerization processes. The compound is also utilized in the manufacture of phenol, resorcinol, and other aromatic compounds through sulfonation reactions in the chemical industry.
How to handle benzenesulfonic acid safely?
Benzenesulfonic acid requires standard laboratory safety precautions during handling. Wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation. Avoid direct skin and eye contact, and ensure proper grounding when transferring the material to prevent static discharge.
How to store benzenesulfonic acid correctly?
Benzenesulfonic acid should be stored in a cool, dry place away from heat sources and direct sunlight. Keep containers tightly sealed to prevent moisture absorption due to its hygroscopic nature. Store away from incompatible materials such as strong bases, oxidizing agents, and metals. Use corrosion-resistant containers and ensure proper ventilation in storage areas.
What to do in case of contact with benzenesulfonic acid?
Benzenesulfonic acid contact requires immediate action depending on exposure type. For skin contact, immediately flush with plenty of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse thoroughly with water and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention.
How to dispose of benzenesulfonic acid appropriately?
Benzenesulfonic acid disposal must comply with local and national waste management regulations. The compound should be treated as chemical waste and disposed of through licensed waste management facilities. Small quantities can be neutralized carefully with appropriate bases before disposal, but this should only be done by trained personnel following proper safety protocols and regulatory guidelines.
How to transport benzenesulfonic acid?
Benzenesulfonic acid is classified under ADR Class 8 (corrosive substances) with Packaging Group III for transportation purposes. This classification requires appropriate corrosive substance packaging and labeling during transport. Proper documentation, including transport documents and safety data sheets, must accompany shipments. Carriers must comply with ADR regulations for corrosive materials handling and emergency procedures.
Is benzenesulfonic acid subject to specific regulations?
Benzenesulfonic acid is subject to standard chemical regulations including REACH registration requirements in Europe and CLP classification obligations. The substance is not classified as SVHC (Substance of Very High Concern) and currently has no specific harmonized classification under CLP. Standard industrial chemical handling, storage, and workplace safety regulations apply to its use and distribution.
Where to buy benzenesulfonic acid in Europe?
Benzenesulfonic acid is available through OYSI, a European distributor specializing in technical chemicals and industrial raw materials. OYSI provides reliable supply chains across Europe with proper documentation and regulatory compliance. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements to meet your specific industrial or research requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.