Benzenesulfonic acid
C6H6O3S
benzenesulfonic acid
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Identification
- CAS Number
- 98-11-3
- EC Number
- 202-638-7
- UN Number
- 2585
- PubChem CID
- 7371
Physical-chemical properties
- Molecular Formula
- C6H6O3S
- Molar Mass
- 158.18 g/mol
- IUPAC Name
- benzenesulfonic acid
Chemical Identifiers
- InChI
- InChI=1S/C6H6O3S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H,7,8,9)
- InChI Key
- SRSXLGNVWSONIS-UHFFFAOYSA-N
Overview
Benzenesulfonic acid (CAS 98-11-3) is an aromatic sulfonic acid with strong acidic properties and high water solubility, serving as a key intermediate in industrial chemical synthesis. This fundamental organic compound represents one of the most important sulfonic acids in industrial chemistry, characterized by a benzene ring directly bonded to a sulfonic acid group (-SO3H). With the molecular formula C6H6O3S and a molecular weight of 158.18 g/mol, benzenesulfonic acid exhibits exceptional stability and reactivity that makes it invaluable across numerous chemical processes. The compound appears as a colorless to pale yellow crystalline solid or viscous liquid, depending on concentration and temperature conditions. Benzenesulfonic acid demonstrates remarkable water solubility due to its ionic character, forming stable aqueous solutions with strong acidic properties. Its sulfonic acid functionality provides excellent thermal stability compared to other organic acids, while maintaining high chemical reactivity for sulfonation reactions. The compound's aromatic structure allows for various substitution reactions, making it a versatile building block in organic synthesis. Unlike simpler compounds such as 4-methoxybenzoyl chloride, benzenesulfonic acid offers unique sulfonic functionality that enables specific industrial applications requiring both aromatic character and strong acidic properties. Primary industrial applications include its use as a catalyst in polymerization reactions, particularly in phenolic resin production, where its acidic properties facilitate crosslinking processes. The compound serves as an essential intermediate in pharmaceutical synthesis and acts as a sulfonating agent in detergent manufacturing. Additionally, benzenesulfonic acid functions as an electrolyte additive in electroplating processes, where its conductive properties and chemical stability prove advantageous. OYSI supplies high-quality benzenesulfonic acid to meet diverse industrial requirements across European markets, ensuring consistent product specifications for demanding technical applications.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 2585 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Benzensulfonsäure, freie Schwefelsäure <= 5 %, flüssig* |
| Marine Pollutant | No |
Frequently Asked Questions
What is benzenesulfonic acid?
Benzenesulfonic acid is an aromatic sulfonic acid compound with the molecular formula C6H6O3S and CAS number 98-11-3. This organic chemical features a benzene ring directly bonded to a sulfonic acid group (-SO3H), making it the simplest aromatic sulfonic acid. With a molecular weight of 158.18 g/mol, it serves as an important intermediate in chemical synthesis and industrial processes.
What are the physicochemical properties of benzenesulfonic acid?
Benzenesulfonic acid is a colorless to light yellow crystalline solid at room temperature with a characteristic acidic odor. It exhibits excellent water solubility due to its sulfonic acid group, forming strongly acidic aqueous solutions. The compound is hygroscopic, readily absorbing moisture from air, and demonstrates high thermal stability. It shows limited solubility in non-polar organic solvents but dissolves well in polar solvents.
What is benzenesulfonic acid used for?
Benzenesulfonic acid is primarily used as a chemical intermediate in the production of detergents, surfactants, and pharmaceutical compounds. It serves as a key building block for synthesizing phenol through alkali fusion and acts as a catalyst in various organic reactions. The compound is also utilized in electroplating processes, as a corrosion inhibitor, and in the manufacturing of dyes and specialty chemicals.
How to handle benzenesulfonic acid safely?
Benzenesulfonic acid should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use local exhaust ventilation to avoid inhalation of vapors or dust. Avoid contact with strong bases and oxidizing agents. Always wash hands thoroughly after handling and ensure emergency eyewash stations are accessible.
How to store benzenesulfonic acid correctly?
Benzenesulfonic acid should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep the material separated from strong bases, metals, and oxidizing agents to prevent incompatible reactions. Use corrosion-resistant containers such as glass or suitable plastic materials. Maintain storage temperatures below 25°C and protect from moisture to prevent degradation.
What to do in case of contact with benzenesulfonic acid?
In case of skin contact with benzenesulfonic acid, immediately remove contaminated clothing and rinse the affected area with plenty of water for at least 15 minutes. For eye contact, flush eyes immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical advice if breathing difficulties occur. In case of ingestion, do not induce vomiting and seek immediate medical attention.
How to dispose of benzenesulfonic acid properly?
Benzenesulfonic acid disposal must comply with local, national, and international waste regulations. The material should be collected in suitable containers and disposed of through licensed waste management companies specializing in chemical waste treatment. Small quantities may be neutralized carefully with appropriate bases before disposal, but this should only be done by trained personnel. Never dispose of the substance down drains or into the environment.
How to transport benzenesulfonic acid?
Benzenesulfonic acid is classified under ADR as Class 8 (corrosive substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers suitable for corrosive materials and properly labeled with appropriate hazard markings. Transport vehicles must carry emergency response information and drivers should be trained in handling hazardous materials. Ensure compliance with all applicable transportation regulations for corrosive substances.
Is benzenesulfonic acid subject to specific regulations?
Benzenesulfonic acid is subject to standard chemical regulations including REACH registration requirements in the European Union. While it is not classified as a Substance of Very High Concern (SVHC), it must comply with CLP regulation for classification, labeling, and packaging. Users must follow occupational safety standards, environmental protection laws, and maintain safety data sheets. Regular monitoring of regulatory updates is recommended for compliance.
Where to buy benzenesulfonic acid in Europe?
Benzenesulfonic acid is available through OYSI, a reliable European distributor of technical chemicals serving industrial customers across Europe. OYSI provides quality chemical products with proper documentation and regulatory compliance support. Contact OYSI directly for pricing, availability, technical specifications, and delivery options tailored to your specific requirements. They offer professional service and expertise in chemical distribution throughout European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.