Ammonia, anhydrous

H3N

ammonia, anhydrous

CAS7664-41-7
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7664-41-7
EC Number
231-635-3
UN Number
1005
Index Number
007-001-00-5
PubChem CID
222

Physical-chemical properties

Molecular Formula
H3N
Molar Mass
17.03 g/mol
IUPAC Name
ammonia, anhydrous

Chemical Identifiers

InChI
InChI=1S/H3N/h1H3
InChI Key
QGZKDVFQNNGYKY-UHFFFAOYSA-N

Overview

Ammonia, anhydrous (CAS 7664-41-7) is a colorless compressed gas with a characteristic pungent odor and high alkalinity. This compressed gas represents one of the most widely produced and utilized industrial chemicals globally, serving as a fundamental building block in numerous manufacturing processes. Unlike aqueous ammonia solutions, the anhydrous form contains no water, making it particularly valuable for applications requiring pure ammonia or where water presence would be detrimental to the process. The substance exhibits significant hazardous properties that require careful handling and storage protocols. As a flammable gas with acute toxicity characteristics, anhydrous ammonia poses serious risks to personnel and equipment. Its highly corrosive nature can cause severe chemical burns to skin and respiratory tissues upon contact or inhalation. The compound also presents environmental concerns due to its acute aquatic toxicity, necessitating appropriate containment measures to prevent environmental release. Key physical properties include its gaseous state under normal conditions, high solubility in water, and tendency to form explosive mixtures with air under specific concentration ranges. Storage typically requires pressurized vessels due to its gaseous nature at ambient temperature. Unlike other toxic gases such as phosphane, anhydrous ammonia has the advantage of easy detection due to its distinctive odor, though this should never replace proper gas detection equipment in industrial settings. Primary industrial applications include fertilizer production, where it serves as a nitrogen source, refrigeration systems as an efficient cooling medium, and chemical synthesis processes for producing various nitrogen-containing compounds. The pharmaceutical and plastics industries also utilize anhydrous ammonia in specialized manufacturing processes. OYSI provides reliable access to high-quality anhydrous ammonia for European industrial customers requiring this essential chemical building block.

Safety & Classification

Danger
Classification:

Flam. Gas 2; Press. Gas; Acute Tox. 3 *; Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H221

Flammable gas.

H331

Toxic if inhaled.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1005
ADR Class2
ADR Labels2.3, 8
Tunnel CodeC/D
Proper Shipping NameAMMONIAK, WASSERFREI
Marine PollutantNo

Frequently Asked Questions

What is anhydrous ammonia?

Anhydrous ammonia is a colorless gas composed of nitrogen and hydrogen (H3N) with a molecular weight of 17.031 g/mol. This compressed gas contains no water, hence the term 'anhydrous'. It has a characteristic pungent odor and is highly soluble in water, forming ammonium hydroxide. Anhydrous ammonia is classified as a hazardous substance due to its flammability, toxicity, and corrosive properties, requiring careful handling and storage procedures in industrial applications.

What are the physicochemical properties of anhydrous ammonia?

Anhydrous ammonia is a colorless gas at room temperature with a sharp, penetrating odor detectable at very low concentrations. It has a boiling point of -33.3°C and is extremely soluble in water, alcohol, and ether. The gas is lighter than air with a density of 0.73 kg/m³ at 15°C. It can be liquefied under pressure and becomes corrosive when dissolved in water, forming alkaline solutions that can cause severe chemical burns.

What is anhydrous ammonia used for?

Anhydrous ammonia is primarily used as a nitrogen fertilizer in agriculture, providing essential nutrients for crop growth. Industrial applications include refrigeration systems, manufacturing of plastics, explosives, and synthetic fibers. It serves as a precursor for producing nitric acid, urea, and other nitrogen compounds. Additionally, it's used in water treatment processes, metal cleaning, and as a pH adjuster in various chemical processes across pharmaceutical and food industries.

How to handle anhydrous ammonia safely?

Anhydrous ammonia requires strict safety protocols including respiratory protection, chemical-resistant gloves, and full-face shields or goggles. Work in well-ventilated areas or use local exhaust ventilation to prevent inhalation. Avoid contact with skin, eyes, and clothing as it causes severe chemical burns. Use only approved equipment rated for ammonia service. Emergency eyewash stations and safety showers must be readily accessible. Never work alone when handling this substance.

How to store anhydrous ammonia correctly?

Anhydrous ammonia must be stored in approved pressure vessels designed for ammonia service, away from heat sources and incompatible materials like acids, halogens, and oxidizing agents. Storage areas require adequate ventilation, leak detection systems, and temperature control. Keep containers upright, properly labeled, and inspect regularly for corrosion or damage. Storage facilities must comply with local fire codes and be equipped with appropriate emergency response equipment including water spray systems.

What to do in case of contact with anhydrous ammonia?

Immediate removal from exposure is critical for anhydrous ammonia contact. For skin contact, flush immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. For eye exposure, rinse continuously with water and seek immediate medical attention. If inhaled, move to fresh air immediately and provide artificial respiration if breathing has stopped. Never induce vomiting if ingested. Seek immediate medical attention in all cases of exposure.

How to dispose of anhydrous ammonia properly?

Anhydrous ammonia disposal must comply with local environmental regulations as it's classified as hazardous waste. Small quantities can be neutralized with dilute acid under controlled conditions by trained personnel. Large quantities require professional hazardous waste disposal services. Never release directly to atmosphere, sewers, or water bodies due to environmental toxicity. Empty containers must be properly purged and may require special disposal procedures. Contact local authorities for specific disposal requirements.

How to transport anhydrous ammonia?

Anhydrous ammonia is classified under ADR Class 2 (gases) for transportation, requiring specialized pressure vessels and trained personnel. Vehicles must display appropriate hazard placards and carry emergency response information. Drivers need hazardous materials certification and proper routing through designated areas. Transportation equipment must meet specific design standards for ammonia service. Emergency response equipment including water supplies and neutralizing agents should be readily available during transport.

Is anhydrous ammonia subject to specific regulations?

Anhydrous ammonia is subject to extensive regulations including CLP classification with GHS pictograms (GHS04, GHS05, GHS06, GHS09) and 'Danger' signal word. REACH registration requirements apply for commercial use in Europe. Workplace exposure limits, emergency planning requirements under Seveso III directive, and specific storage regulations govern its use. Transportation is regulated under ADR, and environmental discharge limits apply. Users must maintain safety data sheets and implement risk management measures according to regulatory requirements.

Where to buy anhydrous ammonia in Europe?

Anhydrous ammonia is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides quality anhydrous ammonia with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures proper packaging, labeling, and transportation according to European regulations. Contact OYSI directly for availability, specifications, and delivery options tailored to your industrial application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.