4-methylpentan-2-ol

C6H14O

CAS108-11-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
108-11-2
EC Number
203-551-7
UN Number
2053
Index Number
603-008-00-8
PubChem CID
7910

Physical-chemical properties

Molecular Formula
C6H14O
Molar Mass
102.17 g/mol
IUPAC Name
4-methylpentan-2-ol

Chemical Identifiers

InChI
InChI=1S/C6H14O/c1-5(2)4-6(3)7/h5-7H,4H2,1-3H3
InChI Key
WVYWICLMDOOCFB-UHFFFAOYSA-N

Overview

4-methylpentan-2-ol (CAS 108-11-2) is a secondary alcohol featuring a branched six-carbon chain structure with characteristic flammable properties and moderate volatility. This branched secondary alcohol belongs to the family of aliphatic alcohols and serves as an important intermediate in various chemical processes. With its molecular formula C6H14O and molecular weight of 102.17 g/mol, 4-methylpentan-2-ol exhibits typical alcohol functionality while maintaining unique properties due to its specific branched structure. The compound is classified under the European CLP regulation with hazard classes including Flammable Liquid Category 3 and Specific Target Organ Toxicity Single Exposure Category 3, requiring appropriate handling precautions as indicated by the warning signal word and associated GHS pictograms GHS02 and GHS07. The substance's chemical structure influences its physical properties, including its solubility characteristics and boiling point, making it suitable for specific industrial applications where controlled volatility is desired. Like other alcohols in this category, including related compounds such as 1-methoxypropan-2-ol, it demonstrates good compatibility with various organic systems while maintaining relatively stable chemical behavior under normal storage conditions. In industrial applications, 4-methylpentan-2-ol finds primary use as a solvent in coating formulations, where its moderate evaporation rate provides favorable application properties. It also serves as a chemical intermediate in the synthesis of esters and other organic compounds, and functions effectively in cleaning formulations where controlled solvency is required. The compound's ADR Class 3 classification necessitates proper transportation and storage protocols to ensure safe handling throughout the supply chain. OYSI maintains reliable availability of 4-methylpentan-2-ol to support European industrial customers' technical requirements.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; STOT SE 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H335

May cause respiratory irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2053
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping NameMethylisobutylcarbinol
Marine PollutantNo

Frequently Asked Questions

What is 4-methylpentan-2-ol?

4-methylpentan-2-ol is a branched secondary alcohol with the molecular formula C6H14O and CAS number 108-11-2. This organic compound has a molecular weight of 102.17 g/mol and belongs to the class of aliphatic alcohols. It is classified as a flammable liquid (Category 3) and may cause specific target organ toxicity following single exposure (Category 3), requiring careful handling in industrial applications.

What are the physicochemical properties of 4-methylpentan-2-ol?

4-methylpentan-2-ol is a colorless liquid at room temperature with a characteristic alcohol odor. As a secondary alcohol with moderate chain length, it exhibits limited water solubility but is miscible with most organic solvents. The compound has a relatively low flash point, contributing to its flammable liquid classification. Its branched structure affects its boiling point and volatility compared to linear alcohols of similar molecular weight.

What is 4-methylpentan-2-ol used for?

4-methylpentan-2-ol serves as an intermediate in organic synthesis and chemical manufacturing processes. It is commonly used as a solvent for various industrial applications, particularly in the production of esters, ethers, and other organic compounds. The compound also finds applications in the formulation of specialty chemicals, coatings, and as a processing aid in polymer production due to its solvent properties and chemical reactivity.

How to handle 4-methylpentan-2-ol safely?

Safe handling of 4-methylpentan-2-ol requires appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas or use local exhaust ventilation to prevent vapor accumulation. Keep away from ignition sources, heat, and sparks due to its flammable nature. Avoid skin and eye contact, and prevent inhalation of vapors. Use non-sparking tools and ensure proper grounding of equipment.

How to store 4-methylpentan-2-ol correctly?

4-methylpentan-2-ol should be stored in a cool, dry, well-ventilated area away from heat sources and ignition points. Use tightly sealed containers made of compatible materials and store in designated flammable liquid storage areas. Keep containers upright and protect from physical damage. Maintain storage temperatures below 25°C when possible and ensure adequate separation from incompatible materials such as strong oxidizing agents and acids.

What to do in case of contact with 4-methylpentan-2-ol?

In case of skin contact with 4-methylpentan-2-ol, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air and monitor breathing. If swallowed, do not induce vomiting and seek immediate medical attention.

How to dispose of 4-methylpentan-2-ol appropriately?

4-methylpentan-2-ol must be disposed of according to local and national hazardous waste regulations. The compound cannot be disposed of in regular waste streams due to its flammable properties. Contact licensed waste disposal companies for proper collection and treatment. Small quantities may be suitable for solvent recovery or incineration at authorized facilities. Always consult local environmental authorities for specific disposal requirements and maintain proper waste documentation.

How to transport 4-methylpentan-2-ol?

4-methylpentan-2-ol is classified under ADR Class 3 (Flammable Liquids), Packing Group III for transportation purposes. It must be transported in UN-approved packaging suitable for flammable liquids and properly labeled with appropriate hazard placards. Vehicles must comply with ADR requirements for Class 3 substances, including proper ventilation, fire extinguishing equipment, and driver certification. Shipping documentation must include proper shipping names and emergency response information.

Is 4-methylpentan-2-ol subject to specific regulations?

4-methylpentan-2-ol is subject to REACH regulation in Europe and must be registered for commercial use above specified tonnage thresholds. It is classified under CLP regulation with hazard classes Flam. Liq. 3 and STOT SE 3, requiring appropriate labeling with GHS02 and GHS07 pictograms. The substance is not currently listed as an SVHC (Substance of Very High Concern) but users must comply with occupational exposure limits and safety data sheet requirements.

Where to buy 4-methylpentan-2-ol in Europe?

4-methylpentan-2-ol is available through OYSI, a reliable European distributor of specialty chemicals and industrial solvents. OYSI provides high-quality chemical products with full regulatory compliance including proper documentation, safety data sheets, and technical support. As an established European supplier, OYSI ensures reliable supply chains and maintains inventory to meet customer demand across various industrial sectors requiring this specialized alcohol compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.