[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate
C36H28F12P2S3
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Identification
- CAS Number
- 74227-35-3
- EC Number
- 403-490-8
- UN Number
- 3082
- Index Number
- 016-087-00-3
- PubChem CID
- 498987
Physical-chemical properties
- Molecular Formula
- C36H28F12P2S3
- Molar Mass
- 846.70 g/mol
- IUPAC Name
- [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate
Chemical Identifiers
- InChI
- InChI=1S/C36H28S3.2F6P/c1-5-13-31(14-6-1)38(32-15-7-2-8-16-32)35-25-21-29(22-26-35)37-30-23-27-36(28-24-30)39(33-17-9-3-10-18-33)34-19-11-4-12-20-34;2*1-7(2,3,4,5)6/h1-28H;;/q+2;2*-1
- InChI Key
- YLVPBWWLXQQGJS-UHFFFAOYSA-N
Overview
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate (CAS 74227-35-3) is an organosulfur photoinitiator compound featuring dual sulfonium salt functionality for enhanced polymerization efficiency. This specialized chemical compound represents a sophisticated photoinitiator system designed for advanced polymer applications. With its molecular formula C36H28F12P2S3 and molecular weight of 846.7 g/mol, this diaryliodonium salt demonstrates exceptional performance in UV-curing technologies. The compound's unique bis-sulfonium structure provides superior reactivity compared to conventional single-center photoinitiators, enabling efficient polymerization under various light conditions. The substance exhibits moderate hazard classifications requiring appropriate handling protocols. It presents eye irritation potential (Eye Irrit. 2) and skin sensitization properties (Skin Sens. 1), necessitating personal protective equipment during use. Environmental considerations are significant, with acute and chronic aquatic toxicity classifications (Aquatic Acute 1; Aquatic Chronic 1) requiring careful waste management and containment procedures. The compound falls under ADR Class 9 for transportation, indicating miscellaneous dangerous goods classification with appropriate shipping requirements. Industrial applications primarily focus on high-performance UV-curing formulations for coatings, adhesives, and electronic materials. The compound excels in applications requiring rapid cure rates and excellent surface properties, particularly in demanding environments where conventional photoinitiators may be insufficient. Unlike simpler compounds such as triphenyl phosphite, this advanced photoinitiator provides superior performance in thick-film applications and shadow-cure situations. The dual-functionality design enables effective polymerization of both radical and cationic systems, making it valuable for hybrid formulations and specialty applications requiring precise control over cure characteristics. OYSI maintains reliable supply chains for this specialized photoinitiator, supporting European industrial customers with consistent quality and technical expertise.
Safety & Classification
Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3082 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Thiobis(4,1-phenylen)-S,S,S',S'-tetraphenyldisulfoniumbishexafluorphosphat + Diphenyl(4-phenylthiophenyl)sulfoniumhexafluorphosphat + Propylencarbonat, Gemisch |
| Marine Pollutant | No |
Frequently Asked Questions
What is [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is a specialized organosulfur compound with the molecular formula C36H28F12P2S3 and CAS number 74227-35-3. This divalent sulfonium salt contains multiple phenyl rings and hexafluorophosphate counterions, giving it a molecular weight of 846.7 g/mol. It is classified as a hazardous substance with eye irritation, skin sensitization, and aquatic toxicity properties.
What are the physicochemical properties of [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is a complex organosulfur compound with a molecular weight of 846.7 g/mol. As a sulfonium salt containing multiple aromatic rings and fluorinated phosphate groups, it typically appears as a solid at room temperature. The presence of both hydrophobic phenyl groups and ionic centers affects its solubility characteristics, making it more soluble in polar organic solvents than in water.
What is [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate used for?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is primarily used as a photoinitiator in industrial applications. This sulfonium salt compound is particularly valuable in UV-curing systems, photopolymerization processes, and advanced materials manufacturing. Its unique molecular structure makes it suitable for specialized chemical synthesis, coatings, adhesives, and electronic materials where controlled photochemical reactions are required.
How to handle [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate safely?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate requires careful handling due to its eye irritation and skin sensitization properties. Essential personal protective equipment includes safety goggles, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation. Avoid direct contact with skin and eyes, and wash hands thoroughly after handling. Emergency eyewash stations should be readily accessible.
How to store [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate correctly?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly closed and protected from moisture. As a photoinitiator compound, it should be stored in light-resistant containers to prevent premature activation. Store away from incompatible materials and ensure proper labeling. Maintain storage temperature below 25°C and check container integrity regularly.
What to do in case of contact with [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?
In case of contact with [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate, immediate action is required due to its irritant properties. For eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. For skin contact, wash thoroughly with soap and water, remove contaminated clothing. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek medical attention immediately.
How to dispose of [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate appropriately?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate must be disposed of according to local and national hazardous waste regulations due to its aquatic toxicity classification. This compound cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper handling and disposal. Never discharge into sewers, waterways, or soil. Maintain detailed disposal records as required by environmental regulations.
How to transport [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation. This classification requires specific packaging, labeling, and documentation procedures. Packages must be properly marked with UN identification numbers and hazard labels. Transportation vehicles require appropriate placarding and drivers need ADR certification. Shipping documents must include proper shipping names and emergency response information.
Is [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate subject to specific regulations?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is subject to European REACH and CLP regulations, requiring registration and classification compliance. It is not currently identified as a Substance of Very High Concern (SVHC). Companies must maintain safety data sheets, implement risk management measures, and ensure proper worker training. The compound's aquatic toxicity classification may trigger additional environmental reporting requirements and restrictions on discharge to water systems.
Where to buy [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate in Europe?
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is available through OYSI, a European distributor of specialty chemical products. OYSI provides comprehensive technical support, regulatory compliance documentation, and reliable supply chain management across Europe. As a specialized photoinitiator compound, it requires expert handling and knowledge of applications. Contact OYSI's technical team for product specifications, safety data sheets, and application guidance to ensure proper selection and use.
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[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.