[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate

C36H28F12P2S3

CAS74227-35-3
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Warning

Consulting for [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
74227-35-3
EC Number
403-490-8
UN Number
3082
Index Number
016-087-00-3
PubChem CID
498987

Physical-chemical properties

Molecular Formula
C36H28F12P2S3
Molar Mass
846.70 g/mol
IUPAC Name
[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate

Chemical Identifiers

InChI
InChI=1S/C36H28S3.2F6P/c1-5-13-31(14-6-1)38(32-15-7-2-8-16-32)35-25-21-29(22-26-35)37-30-23-27-36(28-24-30)39(33-17-9-3-10-18-33)34-19-11-4-12-20-34;2*1-7(2,3,4,5)6/h1-28H;;/q+2;2*-1
InChI Key
YLVPBWWLXQQGJS-UHFFFAOYSA-N

Overview

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate (CAS 74227-35-3) is an organosulfur photoinitiator compound featuring dual sulfonium centers and hexafluorophosphate counterions for enhanced photopolymerization efficiency. This specialized diaryliodonium salt represents a sophisticated class of cationic photoinitiators designed for UV-cured systems and advanced polymer applications. The compound's molecular structure, characterized by its complex aromatic framework with two diphenylsulfonium groups connected through a sulfur bridge, provides exceptional photochemical activity under UV irradiation. With a molecular weight of 846.7 g/mol and the molecular formula C36H28F12P2S3, this substance demonstrates remarkable stability and efficiency in photoinitiating cationic polymerization processes. From a safety perspective, this compound requires careful handling due to its classification as an eye irritant (Eye Irrit. 2) and skin sensitizer (Skin Sens. 1), warranting appropriate personal protective equipment during use. The material also presents environmental considerations with its acute and chronic aquatic toxicity classification, necessitating proper containment and disposal procedures. The GHS07 and GHS09 pictograms reflect these health and environmental hazards, while its ADR Class 9 designation indicates miscellaneous dangerous goods classification for transport. Primary industrial applications include UV-curable coatings, photopolymer resins for 3D printing, and specialty adhesive formulations where rapid curing and high cross-linking density are essential. Unlike simpler photoinitiators or stabilizers such as triphenyl phosphite, this compound offers superior performance in demanding applications requiring precise control over polymerization kinetics and final material properties. OYSI provides this high-performance photoinitiator to European manufacturers requiring reliable access to specialized UV-curing chemistry solutions.

Safety & Classification

Warning
Classification:

Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameThiobis(4,1-phenylen)-S,S,S',S'-tetraphenyldisulfoniumbishexafluorphosphat + Diphenyl(4-phenylthiophenyl)sulfoniumhexafluorphosphat + Propylencarbonat, Gemisch
Marine PollutantNo

Frequently Asked Questions

What is [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is an organosulfur compound with the molecular formula C36H28F12P2S3 and CAS number 74227-35-3. This chemical substance has a molecular weight of 846.7 g/mol and contains multiple diphenylsulfanium groups linked through sulfur bridges, with hexafluorophosphate counterions providing charge balance in its crystalline structure.

What are the physicochemical properties of [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is a solid compound at room temperature with a molecular weight of 846.7 g/mol. As an ionic compound containing hexafluorophosphate anions, it typically exhibits limited water solubility but may dissolve in polar organic solvents. The presence of multiple aromatic rings and sulfur centers contributes to its stability and distinctive chemical behavior in various reaction conditions.

What is [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate used for?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is primarily used as a photoinitiator in polymer chemistry and UV-curing applications. Its sulfonium salt structure makes it effective for initiating cationic polymerization processes under light exposure. The compound finds applications in coatings, adhesives, and specialty polymer manufacturing where controlled polymerization initiation is required for producing high-performance materials.

How to handle [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate safely?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate should be handled with appropriate personal protective equipment including safety glasses, gloves, and protective clothing. The compound is classified as Eye Irritant Category 2 and Skin Sensitizer Category 1, requiring careful handling to avoid direct contact. Work in well-ventilated areas, avoid dust formation, and wash hands thoroughly after handling to prevent sensitization reactions.

How to store [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate correctly?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate should be stored in a cool, dry place away from light sources to prevent premature activation. Keep containers tightly closed and protect from moisture and heat. Store separately from incompatible materials such as strong oxidizers and bases. Maintain storage temperatures below 25°C and ensure proper ventilation in storage areas to prevent accumulation of any potential vapors.

What to do in case of contact with [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?

In case of eye contact with [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. If irritation persists or allergic reactions develop, consult a physician immediately. Remove person to fresh air if inhalation occurs and seek medical attention if symptoms develop.

How to dispose of [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate appropriately?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate must be disposed of as hazardous waste according to local and national regulations. Due to its aquatic toxicity classification (Aquatic Acute 1, Aquatic Chronic 1), prevent release to waterways and soil. Contact licensed waste disposal companies for proper treatment and disposal. Do not discharge to sewers or environment. Follow all applicable waste management regulations and maintain disposal documentation.

How to transport [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation. Use appropriate packaging that meets UN specifications and ensure proper labeling with hazard markings. Transport vehicles must comply with ADR requirements including proper documentation, emergency procedures, and driver training. Avoid exposure to heat, light, and mechanical shock during transport to maintain product stability.

Is [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate subject to specific regulations?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is subject to REACH regulation requiring registration for import/manufacture in quantities above 1 tonne annually. The substance is classified under CLP regulation with harmonized hazard classifications including eye irritation and skin sensitization. It is not currently listed as an SVHC substance. Users must comply with safety data sheet requirements and implement appropriate risk management measures according to European chemical legislation.

Where to buy [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate in Europe?

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this photoinitiator compound with full regulatory compliance including safety data sheets and proper packaging for industrial customers across Europe. Contact OYSI's technical sales team for availability, specifications, and delivery options tailored to your specific application requirements and quantities needed.

Services for [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate

ADR Consulting for [4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate

[4-(4-diphenylsulfoniophenyl)sulfanylphenyl]-diphenylsulfanium dihexafluorophosphate is a dangerous good. We support you with labeling, packaging, and transport documentation.

Request ADR Advice

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.