Zinc bis(N,N-dibutylcarbamodithioate)

C18H36N2S4Zn

zinc bis(N,N-dibutylcarbamodithioate)

CAS136-23-2
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
136-23-2
EC Number
205-232-8
UN Number
3077
Index Number
006-081-00-9
PubChem CID
5284483

Physical-chemical properties

Molecular Formula
C18H36N2S4Zn
Molar Mass
474.10 g/mol
IUPAC Name
zinc bis(N,N-dibutylcarbamodithioate)

Chemical Identifiers

InChI
InChI=1S/2C9H19NS2.Zn/c2*1-3-5-7-10(9(11)12)8-6-4-2;/h2*3-8H2,1-2H3,(H,11,12);/q;;+2/p-2
InChI Key
BOXSVZNGTQTENJ-UHFFFAOYSA-L

Overview

Zinc bis(N,N-dibutylcarbamodithioate) (CAS 136-23-2) is an organosulfur zinc compound with accelerating properties and antimicrobial characteristics. This zinc-based carbamodithioate compound serves as a crucial intermediate in various industrial applications, particularly valued for its dual functionality as both a vulcanization accelerator and biocide. With the molecular formula C18H36N2S4Zn and a molecular weight of 474.1 g/mol, this organometallic compound belongs to the dithiocarbamate family, which are widely recognized for their effectiveness in rubber processing and agricultural applications. The compound exhibits moderate hazard characteristics, classified under GHS pictograms GHS07 and GHS09, indicating health and environmental concerns that require proper handling protocols. It presents skin and eye irritation potential, skin sensitization properties, and specific target organ toxicity. Environmental precautions are particularly important due to its acute and chronic aquatic toxicity classification, necessitating controlled use and disposal procedures. Safety considerations include appropriate personal protective equipment during handling, adequate ventilation systems, and compliance with ADR Class 9 transportation requirements. The compound's dithiocarbamate structure relates it to other organosulfur compounds like S-methyl 1,2,3-benzothiadiazole-7-carbothioate, though each serves distinct industrial purposes. Primary industrial applications include rubber vulcanization acceleration in tire manufacturing and industrial rubber goods production, where it enhances cross-linking efficiency and final product durability. Additionally, it functions as an antimicrobial agent in specialized formulations, contributing to preservation and protection in various industrial processes. OYSI maintains reliable supply chains for zinc bis(N,N-dibutylcarbamodithioate), supporting European manufacturers with consistent product quality and comprehensive technical documentation for safe and effective implementation.

Safety & Classification

Warning
Classification:

STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameZinkbis(dibutyldithiocarbamat)
Marine PollutantNo

Frequently Asked Questions

What is zinc bis(N,N-dibutylcarbamodithioate)?

Zinc bis(N,N-dibutylcarbamodithioate) is an organozinc compound with the molecular formula C18H36N2S4Zn and CAS number 136-23-2. This chemical substance has a molecular weight of 474.1 g/mol and belongs to the carbamodithioate family. It is classified as a hazardous substance with multiple safety concerns including skin and eye irritation, skin sensitization, and aquatic toxicity, requiring careful handling in industrial applications.

What are the physicochemical properties of zinc bis(N,N-dibutylcarbamodithioate)?

Zinc bis(N,N-dibutylcarbamodithioate) is typically a solid compound at room temperature with characteristic organosulfur properties. As an organozinc complex containing sulfur and nitrogen atoms, it exhibits limited water solubility due to its organic dibutyl groups. The compound's molecular structure includes zinc coordinated to carbamodithioate ligands, giving it specific thermal and chemical stability properties relevant for its industrial applications.

What is zinc bis(N,N-dibutylcarbamodithioate) used for?

Zinc bis(N,N-dibutylcarbamodithioate) is primarily used as an accelerator and activator in rubber vulcanization processes. It serves as a catalyst in the cross-linking of rubber polymers, improving the mechanical properties and durability of rubber products. The compound is also utilized in the production of tires, rubber seals, gaskets, and other elastomeric materials where controlled vulcanization is essential for achieving desired performance characteristics.

How to handle zinc bis(N,N-dibutylcarbamodithioate) safely?

Zinc bis(N,N-dibutylcarbamodithioate) requires careful handling due to its skin and eye irritation properties and skin sensitization potential. Wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation in work areas and avoid direct skin contact. The compound carries GHS07 and GHS09 pictograms with a 'Warning' signal word, indicating moderate health hazards and environmental concerns requiring standard industrial safety protocols.

How to store zinc bis(N,N-dibutylcarbamodithioate) correctly?

Zinc bis(N,N-dibutylcarbamodithioate) should be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly closed and protect from moisture and direct sunlight. Due to its aquatic toxicity classification, prevent environmental release during storage. Store away from oxidizing agents and strong acids. Maintain proper labeling with GHS07 and GHS09 pictograms and ensure storage areas comply with local chemical storage regulations for hazardous substances.

What to do in case of contact with zinc bis(N,N-dibutylcarbamodithioate)?

Zinc bis(N,N-dibutylcarbamodithioate) contact requires immediate first aid measures due to its irritant properties. For skin contact, remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15 minutes and remove contact lenses if present. If inhaled, move to fresh air. Seek medical attention if irritation persists or develops, especially considering the substance's skin sensitization potential.

How to dispose of zinc bis(N,N-dibutylcarbamodithioate) properly?

Zinc bis(N,N-dibutylcarbamodithioate) disposal must follow hazardous waste regulations due to its environmental toxicity classification (Aquatic Acute 1; Aquatic Chronic 1). Never discharge into sewers, waterways, or soil. Contact licensed waste disposal companies specialized in hazardous chemical waste. The compound requires treatment at authorized facilities capable of handling organometallic compounds. Follow local and EU waste regulations including proper waste classification codes and documentation for hazardous waste disposal.

How to transport zinc bis(N,N-dibutylcarbamodithioate)?

Zinc bis(N,N-dibutylcarbamodithioate) is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification requires specific packaging, labeling, and documentation according to ADR regulations. Use appropriate UN-specification packaging and ensure proper hazard labels are affixed. Transport vehicles must comply with ADR requirements for Class 9 substances. Drivers need appropriate ADR training certificates, and transport documents must include proper shipping names and hazard information.

Is zinc bis(N,N-dibutylcarbamodithioate) subject to specific regulations?

Zinc bis(N,N-dibutylcarbamodithioate) is subject to REACH regulation requiring registration for manufacture or import above one tonne per year. The substance is not currently listed as SVHC (Substance of Very High Concern). It falls under CLP regulation requiring classification as STOT SE 3, Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1, and aquatic toxicity categories. Users must comply with safety data sheet requirements and workplace exposure limits where established by national authorities.

Where to buy zinc bis(N,N-dibutylcarbamodithioate) in Europe?

Zinc bis(N,N-dibutylcarbamodithioate) is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this compound to industrial customers across Europe with proper documentation including safety data sheets and certificates of analysis. As a professional chemical distributor, OYSI ensures compliance with REACH and CLP regulations, proper packaging according to ADR Class 9 requirements, and technical support for safe handling and application in rubber processing industries.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.