4-[(4-aminophenyl)diazenyl]-3-methylaniline

C13H14N4

CAS43151-99-1
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for 4-[(4-aminophenyl)diazenyl]-3-methylaniline

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Identification

CAS Number
43151-99-1
EC Number
407-590-2
UN Number
2811
Index Number
611-046-00-1
PubChem CID
176021

Physical-chemical properties

Molecular Formula
C13H14N4
Molar Mass
226.28 g/mol
IUPAC Name
4-[(4-aminophenyl)diazenyl]-3-methylaniline

Chemical Identifiers

InChI
InChI=1S/C13H14N4/c1-9-8-11(15)4-7-13(9)17-16-12-5-2-10(14)3-6-12/h2-8H,14-15H2,1H3
InChI Key
UOABMKNOHFGBSD-UHFFFAOYSA-N

Overview

4-[(4-aminophenyl)diazenyl]-3-methylaniline (CAS 43151-99-1) is an azo compound featuring two amino groups and exhibiting significant biological activity. This aromatic azo compound, also known by its EC number 407-590-2, represents an important class of organic chemicals characterized by the presence of a diazenyl bridge (-N=N-) connecting two aromatic rings. With a molecular formula of C13H14N4 and molecular weight of 226.28 g/mol, this substance displays the typical structural features of aminoazo compounds, incorporating both amino functional groups and the characteristic azo linkage that defines this chemical family. The compound presents significant safety considerations due to its hazard classification profile. It carries acute toxicity warnings (Acute Tox. 3), skin sensitization potential (Skin Sens. 1), and specific target organ toxicity concerns (STOT RE 2). Environmental impact is also notable, with classifications for both acute and chronic aquatic toxicity. These properties necessitate careful handling protocols and appropriate personal protective equipment during industrial processing. From a structural perspective, this compound shares similarities with other aminoaniline derivatives such as N-methylaniline, though its diazenyl bridge provides distinct chemical properties. The presence of the methyl substituent and dual amino groups influences both its reactivity patterns and potential applications compared to simpler aromatic amines. Industrial applications typically focus on intermediate chemistry for dye synthesis, pharmaceutical precursors, and specialized chemical manufacturing processes. The compound's azo structure makes it particularly relevant in colorant chemistry and as a building block for more complex organic molecules. Research applications may include studies of azo compound behavior and synthetic methodology development. OYSI maintains technical-grade supplies of 4-[(4-aminophenyl)diazenyl]-3-methylaniline to support European industrial and research requirements, ensuring consistent quality and regulatory compliance.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; STOT RE 2 *; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H301

Toxic if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2811
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping Name4,4'-Diamino-2-methylazobenzen
Marine PollutantNo

Frequently Asked Questions

What is 4-[(4-aminophenyl)diazenyl]-3-methylaniline?

4-[(4-aminophenyl)diazenyl]-3-methylaniline is an aromatic azo compound with the molecular formula C13H14N4 and CAS number 43151-99-1. This chemical substance has a molecular weight of 226.28 g/mol and belongs to the diazenyl aniline family. It is classified as a hazardous substance due to its acute toxicity, skin sensitization properties, and environmental toxicity to aquatic organisms.

What are the physicochemical properties of 4-[(4-aminophenyl)diazenyl]-3-methylaniline?

4-[(4-aminophenyl)diazenyl]-3-methylaniline is an organic compound with a molecular mass of 226.28 g/mol and molecular formula C13H14N4. As an aromatic azo compound containing amino groups, it typically appears as a colored solid due to its extended conjugated system. The presence of amino groups suggests potential solubility in polar solvents, though specific physical data should be confirmed through technical documentation.

What is 4-[(4-aminophenyl)diazenyl]-3-methylaniline used for?

4-[(4-aminophenyl)diazenyl]-3-methylaniline is primarily used as an intermediate in chemical synthesis and dye manufacturing processes. Its azo structure makes it valuable in the production of colorants and pigments for various industrial applications. The compound may also serve as a building block for pharmaceutical intermediates or specialty chemicals requiring aromatic amino-azo functionalities in research and development applications.

How to handle 4-[(4-aminophenyl)diazenyl]-3-methylaniline safely?

4-[(4-aminophenyl)diazenyl]-3-methylaniline requires careful handling due to its Acute Tox. 3 and Skin Sens. 1 classifications. Essential protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin contact. Work in well-ventilated areas or use local exhaust ventilation. Avoid inhalation, ingestion, and skin contact. Wash hands thoroughly after handling and ensure emergency eyewash and shower facilities are readily accessible.

How to store 4-[(4-aminophenyl)diazenyl]-3-methylaniline correctly?

4-[(4-aminophenyl)diazenyl]-3-methylaniline should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers upright and properly labeled according to GHS requirements. Store separately from incompatible materials such as strong oxidizers and acids. Ensure storage area is equipped with appropriate spill containment measures and access is restricted to authorized personnel only.

What to do in case of contact with 4-[(4-aminophenyl)diazenyl]-3-methylaniline?

Immediate action is required upon contact with 4-[(4-aminophenyl)diazenyl]-3-methylaniline due to its toxicity and sensitization potential. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15 minutes. If inhaled, move to fresh air. Seek immediate medical attention for all exposure incidents and provide safety data sheet to medical personnel.

How to dispose of 4-[(4-aminophenyl)diazenyl]-3-methylaniline appropriately?

4-[(4-aminophenyl)diazenyl]-3-methylaniline must be disposed of as hazardous waste according to local and national regulations due to its toxicity and environmental classification. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never dispose of down drains or with regular waste. Small quantities may require incineration at authorized facilities with appropriate emission controls. Maintain disposal records as required by applicable waste management regulations.

How to transport 4-[(4-aminophenyl)diazenyl]-3-methylaniline?

4-[(4-aminophenyl)diazenyl]-3-methylaniline is classified under ADR Class 6.1, Packing Group III for transportation of toxic substances. Transport requires appropriate UN-specification packaging with proper labeling including GHS06, GHS08, and GHS09 pictograms. Shipping documents must include the correct technical name, UN number, and hazard class. Vehicle placarding and driver training according to dangerous goods transport regulations are mandatory for commercial transport.

Is 4-[(4-aminophenyl)diazenyl]-3-methylaniline subject to specific regulations?

4-[(4-aminophenyl)diazenyl]-3-methylaniline is subject to REACH regulation requiring registration for manufacture or import above one tonne annually. CLP regulation mandates classification as Acute Tox. 3, STOT RE 2, Skin Sens. 1, and Aquatic toxicity categories. The substance is not currently listed as SVHC under REACH. National occupational exposure limits may apply, and specific restrictions could exist depending on intended use and local legislation.

Where to buy 4-[(4-aminophenyl)diazenyl]-3-methylaniline in Europe?

4-[(4-aminophenyl)diazenyl]-3-methylaniline is available through OYSI, a specialized European distributor of technical chemicals and intermediates. OYSI provides professional-grade chemicals with appropriate documentation including safety data sheets and certificates of analysis. Contact OYSI directly for availability, packaging options, and technical support. As a controlled substance, purchase may require demonstration of legitimate professional use and adherence to applicable regulatory requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.