3-triethoxysilylpropan-1-amine
C9H23NO3Si
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Identification
- CAS Number
- 919-30-2
- EC Number
- 213-048-4
- UN Number
- 3267
- Index Number
- 612-108-00-0
- PubChem CID
- 13521
Physical-chemical properties
- Molecular Formula
- C9H23NO3Si
- Molar Mass
- 221.37 g/mol
- IUPAC Name
- 3-triethoxysilylpropan-1-amine
Chemical Identifiers
- InChI
- InChI=1S/C9H23NO3Si/c1-4-11-14(12-5-2,13-6-3)9-7-8-10/h4-10H2,1-3H3
- InChI Key
- WYTZZXDRDKSJID-UHFFFAOYSA-N
Overview
3-triethoxysilylpropan-1-amine (CAS 919-30-2) is an organosilane coupling agent with both amine and silane functionalities for surface modification applications. This bifunctional organosilane compound serves as a crucial intermediary in industrial chemistry, bridging organic and inorganic materials through its unique dual reactive nature. The molecule features a propylamine chain connected to a triethoxysilyl group, enabling it to form covalent bonds with both organic polymers and inorganic substrates such as glass, metals, and mineral fillers. With the molecular formula C9H23NO3Si and a molecular weight of 221.37 g/mol, this clear to pale yellow liquid demonstrates excellent hydrolytic stability under controlled conditions. The compound exhibits significant safety considerations due to its corrosive properties, classified as Skin Corr. 1B and Acute Tox. 4 under GHS guidelines. Proper handling requires appropriate personal protective equipment and adherence to ADR Class 8 transportation regulations. Unlike simpler compounds such as phenylmethanamine, this organosilane requires specialized storage conditions to prevent premature hydrolysis and maintain product integrity. Primary industrial applications include adhesion promotion in composite materials, surface treatment of glass fibers for reinforced plastics, and as a coupling agent in sealants and coatings formulations. The amine functionality provides excellent reactivity with epoxy resins, polyurethanes, and other polymer systems, while the silane portion ensures strong bonding to inorganic surfaces. Additional uses encompass primer formulations for metal substrates and as a key component in hybrid organic-inorganic materials. OYSI maintains reliable supply chains for 3-triethoxysilylpropan-1-amine across European markets, supporting diverse industrial applications with consistent quality standards.
Safety & Classification
Acute Tox. 4 *; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3267 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | 3-(Triethoxysilyl)propan-1-amin |
| Marine Pollutant | No |
Frequently Asked Questions
What is 3-triethoxysilylpropan-1-amine?
3-triethoxysilylpropan-1-amine is an organosilane coupling agent with the molecular formula C9H23NO3Si and CAS number 919-30-2. This aminosilane compound features both amino and triethoxysilyl functional groups, making it valuable for surface modification and adhesion promotion. With a molecular weight of 221.37 g/mol, it serves as a bridge between organic and inorganic materials in various industrial applications.
What are the physicochemical properties of 3-triethoxysilylpropan-1-amine?
3-triethoxysilylpropan-1-amine is typically a clear to pale yellow liquid at room temperature with a characteristic amine odor. The compound is moisture-sensitive and readily hydrolyzes in the presence of water, forming silanol groups. It is soluble in most organic solvents including alcohols and hydrocarbons but reacts with water. The molecular structure contains both hydrolyzable ethoxy groups and a basic amino functionality.
What is 3-triethoxysilylpropan-1-amine used for?
3-triethoxysilylpropan-1-amine is primarily used as a coupling agent and surface modifier in composite materials, adhesives, and sealants. It enhances adhesion between organic polymers and inorganic substrates like glass, metals, and fillers. Common applications include fiber glass reinforcement, paint formulations, primer systems, and as a surface treatment for mineral fillers in rubber and plastic compounds to improve mechanical properties and durability.
How to handle 3-triethoxysilylpropan-1-amine safely?
3-triethoxysilylpropan-1-amine requires careful handling due to its corrosive nature (Skin Corr. 1B) and acute toxicity (Acute Tox. 4). Essential PPE includes chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or use local exhaust ventilation. Avoid skin and eye contact, and prevent inhalation of vapors. Keep away from moisture and incompatible materials during handling operations.
How to store 3-triethoxysilylpropan-1-amine correctly?
3-triethoxysilylpropan-1-amine must be stored in tightly sealed containers in a cool, dry place away from moisture and heat sources. Keep containers in well-ventilated areas away from incompatible materials such as strong acids, bases, and oxidizing agents. Store in original containers with proper labeling and ensure temperature stability. Protect from direct sunlight and maintain storage areas with appropriate spill containment measures.
What to do in case of contact with 3-triethoxysilylpropan-1-amine?
3-triethoxysilylpropan-1-amine contact requires immediate action due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush with plenty of water for at least 15 minutes. For eye contact, rinse immediately with water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air and seek medical advice. Never induce vomiting if swallowed and seek immediate medical attention.
How to dispose of 3-triethoxysilylpropan-1-amine properly?
3-triethoxysilylpropan-1-amine disposal must comply with local and national hazardous waste regulations as it is classified as dangerous goods. The waste should be collected by licensed hazardous waste disposal companies and cannot be disposed of with regular waste. Containers should be completely emptied and may require special treatment. Consider recycling or recovery options where available, and maintain proper documentation of disposal activities as required by law.
How to transport 3-triethoxysilylpropan-1-amine?
3-triethoxysilylpropan-1-amine is classified as ADR Class 8 (corrosive substances), Packing Group II, requiring specific transport protocols. Packages must meet UN specification standards and display appropriate hazard labels including GHS05 and GHS07 pictograms. Transport vehicles need proper placarding and emergency equipment. Drivers require ADR training certification, and shipping documentation must include proper shipping names, hazard classifications, and emergency response information.
Is 3-triethoxysilylpropan-1-amine subject to specific regulations?
3-triethoxysilylpropan-1-amine is subject to REACH regulation requiring registration for manufacture or import above 1 tonne annually in the EU. CLP regulation mandates specific labeling with 'Danger' signal word and appropriate pictograms (GHS05, GHS07). It is not currently listed as an SVHC substance. Users must comply with occupational safety regulations, maintain safety data sheets, and follow workplace exposure limits where established by national authorities.
Where to buy 3-triethoxysilylpropan-1-amine in Europe?
3-triethoxysilylpropan-1-amine is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides reliable supply chains, technical support, and regulatory compliance assistance for professional users. The compound is typically available in various packaging sizes to meet different application requirements, with proper documentation including certificates of analysis and safety data sheets for safe industrial use.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.