2,4,6-trinitrophenol
C6H3N3O7
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Identification
- CAS Number
- 88-89-1
- EC Number
- 201-865-9
- UN Number
- 0154
- Index Number
- 609-009-00-X
- PubChem CID
- 6954
Physical-chemical properties
- Molecular Formula
- C6H3N3O7
- Molar Mass
- 229.10 g/mol
- IUPAC Name
- 2,4,6-trinitrophenol
Chemical Identifiers
- InChI
- InChI=1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H
- InChI Key
- OXNIZHLAWKMVMX-UHFFFAOYSA-N
Overview
2,4,6-trinitrophenol (CAS 88-89-1) is a highly explosive nitroaromatic compound with potent detonating properties and significant toxicity concerns. This yellow crystalline substance, also known as picric acid, represents one of the most powerful explosive compounds in industrial chemistry. With the molecular formula C6H3N3O7 and a molecular weight of 229.1 g/mol, 2,4,6-trinitrophenol belongs to the nitrophenol family and exhibits exceptional explosive characteristics that have made it historically significant in both military and civilian applications. The compound's hazard profile is dominated by its explosive properties, classified as Expl. 1.1 under GHS regulations, indicating it poses risks of mass explosion. Additionally, it carries Acute Tox. 3 classifications across multiple exposure routes, requiring strict safety protocols during handling and storage. The presence of both GHS01 (exploding bomb) and GHS06 (skull and crossbones) pictograms emphasizes the dual nature of its dangers - both explosive and toxic. From a chemical perspective, 2,4,6-trinitrophenol shares structural similarities with other nitroaromatic explosives such as 2-methyl-1,3,5-trinitrobenzene, though it maintains unique detonation characteristics. The compound's stability and sensitivity to impact, friction, and heat make it particularly challenging to handle safely. Primary industrial applications include specialized explosive formulations, chemical synthesis intermediates, and laboratory reagent uses where controlled explosive properties are required. The compound also serves specific roles in analytical chemistry and materials testing applications. OYSI maintains strict protocols for the distribution of 2,4,6-trinitrophenol, ensuring compliance with ADR Class 1 transportation requirements and all applicable safety regulations for European customers requiring this specialized explosive compound.
Safety & Classification
Expl. 1.1; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 0154 |
| ADR Class | 1 |
| Packing Group | |
| Tunnel Code | B1000C |
| Proper Shipping Name | Trinitrophenol, trocken, nicht pulverförmig |
| Marine Pollutant | No |
Frequently Asked Questions
What is 2,4,6-trinitrophenol?
2,4,6-trinitrophenol is a highly explosive organic compound with the molecular formula C6H3N3O7 and CAS number 88-89-1. Also known as picric acid, it consists of a phenol molecule substituted with three nitro groups at positions 2, 4, and 6. This yellow crystalline substance has a molecular weight of 229.1 g/mol and is classified as an explosive material with acute toxicity properties, requiring extreme caution in handling and storage.
What are the physicochemical properties of 2,4,6-trinitrophenol?
2,4,6-trinitrophenol appears as bright yellow crystals with a bitter taste and is odorless when pure. It is moderately soluble in water (approximately 1.2% at room temperature) and more soluble in organic solvents like alcohol and ether. The compound has a melting point around 122°C and is highly sensitive to shock, friction, and heat, making it extremely dangerous to handle without proper precautions.
What is 2,4,6-trinitrophenol used for?
2,4,6-trinitrophenol is primarily used in specialized industrial applications including explosive manufacturing, chemical synthesis, and as a laboratory reagent. It serves as an intermediate in the production of certain dyes and pharmaceuticals. Due to its explosive nature and toxicity, its use is heavily restricted and typically limited to controlled industrial processes requiring specific authorization and safety measures.
How to handle 2,4,6-trinitrophenol safely?
2,4,6-trinitrophenol requires extreme safety precautions including explosion-proof equipment, anti-static clothing, and complete personal protective equipment (PPE) including chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in controlled environments away from heat sources, friction, and static electricity. Only trained personnel should handle this substance, and emergency procedures must be readily available due to its explosive and toxic nature.
How to store 2,4,6-trinitrophenol correctly?
2,4,6-trinitrophenol must be stored in specialized explosive storage facilities meeting strict regulatory requirements. Storage areas should be cool, dry, well-ventilated, and isolated from incompatible materials including metals, strong bases, and reducing agents. Containers must be explosion-proof and properly grounded. Regular inspection for crystal formation and degradation is essential, as dry picric acid becomes increasingly sensitive and dangerous over time.
What to do in case of contact with 2,4,6-trinitrophenol?
Immediate medical attention is required for any contact with 2,4,6-trinitrophenol. For skin contact, remove contaminated clothing and rinse affected areas with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, flush with water for 15 minutes while holding eyelids open. Never induce vomiting if ingested. Contact emergency services immediately and provide the safety data sheet to medical personnel.
How to dispose of 2,4,6-trinitrophenol appropriately?
2,4,6-trinitrophenol disposal requires specialized hazardous waste treatment by licensed explosive disposal companies. It cannot be disposed of through normal waste streams due to its explosive and toxic properties. Disposal must comply with local, national, and EU waste regulations for explosive materials. Small quantities may require controlled detonation or specialized chemical neutralization processes performed only by qualified professionals with appropriate permits and safety equipment.
How to transport 2,4,6-trinitrophenol?
2,4,6-trinitrophenol is classified as a Class 1 dangerous good under ADR regulations, requiring specialized explosive transport procedures. Transportation must use authorized carriers with proper explosive transport licenses, appropriate packaging meeting UN specifications, and complete documentation including transport emergency cards. Vehicles must be equipped with explosion-proof features and follow designated routes with restricted quantities per shipment.
Is 2,4,6-trinitrophenol subject to specific regulations?
2,4,6-trinitrophenol is subject to extensive regulations including EU CLP classification as Explosive 1.1 and Acute Toxicity 3, requiring GHS01 and GHS06 pictograms with 'Danger' signal word. It falls under explosive precursor regulations, REACH registration requirements, and may require special licenses for purchase, storage, and use. While not currently listed as SVHC, its handling is strictly controlled under national explosive and chemical safety legislations.
Where to buy 2,4,6-trinitrophenol in Europe?
2,4,6-trinitrophenol is available through specialized chemical distributors like OYSI, which serves the European market with regulated chemical products. Purchase requires proper licensing, end-use declarations, and compliance with explosive material regulations. Buyers must demonstrate legitimate industrial need, appropriate storage facilities, and qualified personnel. Contact OYSI's technical team for availability, regulatory requirements, and specialized handling arrangements for this controlled explosive substance.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.