1,3,5-trinitrobenzene

C6H3N3O6

CAS99-35-4
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
99-35-4
EC Number
202-752-7
UN Number
0214
Index Number
609-005-00-8
PubChem CID
7434

Physical-chemical properties

Molecular Formula
C6H3N3O6
Molar Mass
213.10 g/mol
IUPAC Name
1,3,5-trinitrobenzene

Chemical Identifiers

InChI
InChI=1S/C6H3N3O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H
InChI Key
UATJOMSPNYCXIX-UHFFFAOYSA-N

Overview

1,3,5-Trinitrobenzene (CAS 99-35-4) is a nitroaromatic explosive compound with high detonation sensitivity and significant toxicity properties. This symmetric trinitro compound represents one of the most hazardous nitroaromatic explosives in industrial chemistry. With its molecular formula C6H3N3O6 and molecular weight of 213.1 g/mol, 1,3,5-trinitrobenzene exhibits exceptional explosive characteristics that demand stringent safety protocols throughout handling, storage, and transportation. The compound's classification as Explosive 1.1 under ADR regulations reflects its mass explosion hazard potential, while multiple acute toxicity classifications underscore the severe health risks associated with exposure through inhalation, dermal contact, or ingestion. The substance's comprehensive hazard profile includes specific target organ toxicity following repeated exposure and significant aquatic toxicity, requiring specialized containment and waste management procedures. Related compounds in this chemical family, such as 2-methyl-1,3,5-trinitrobenzene, share similar explosive properties but may exhibit different sensitivity thresholds and handling requirements. Primary industrial applications include specialized explosive formulations for mining operations, controlled demolition projects, and military ordnance manufacturing. The compound also serves as an intermediate in the synthesis of other energetic materials and finds limited use in analytical chemistry as a reference standard for explosive residue analysis. Due to its extreme hazard classification, all applications require extensive safety infrastructure and trained personnel operating under strict regulatory oversight. OYSI maintains specialized capabilities for handling and distributing 1,3,5-trinitrobenzene to qualified industrial customers with appropriate explosive handling licenses and safety certifications throughout Europe.

Safety & Classification

Danger
Classification:

Expl. 1.1; Acute Tox. 2 *; Acute Tox. 1; Acute Tox. 2 *; STOT RE 2; Aquatic Acute 1; Aquatic Chro...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H330

Fatal if inhaled.

H310

Fatal in contact with skin.

H300

Fatal if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Fatal

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number0214
ADR Class1
Packing Group
Tunnel CodeB1000C
Proper Shipping NameTrinitrobenzen, trocken, nicht pulverförmig
Marine PollutantNo

Frequently Asked Questions

What is 1,3,5-trinitrobenzene?

1,3,5-trinitrobenzene is a highly explosive organic compound with the molecular formula C6H3N3O6 and CAS number 99-35-4. This aromatic nitro compound consists of a benzene ring with three nitro groups (-NO2) positioned symmetrically at the 1, 3, and 5 positions. It has a molecular weight of 213.1 g/mol and is classified as an extremely dangerous explosive material requiring specialized handling and storage procedures.

What are the physicochemical properties of 1,3,5-trinitrobenzene?

1,3,5-trinitrobenzene is a pale yellow crystalline solid at room temperature with a melting point around 122°C. The compound is relatively stable under normal conditions but becomes highly explosive when subjected to heat, shock, or friction. It has limited solubility in water but dissolves readily in organic solvents such as acetone and benzene. The substance exhibits high density and forms needle-like crystals when pure.

What is 1,3,5-trinitrobenzene used for?

1,3,5-trinitrobenzene is primarily used as an explosive material in military and industrial applications, including demolition work and mining operations. It serves as an intermediate in the synthesis of other explosive compounds and specialized chemicals. The substance is also utilized in research laboratories for analytical purposes and as a reference standard. Due to its extreme hazard classification, its use is strictly regulated and limited to authorized professionals with proper training.

How to handle 1,3,5-trinitrobenzene safely?

1,3,5-trinitrobenzene requires extreme caution during handling due to its explosive nature and high toxicity. Personnel must wear full protective equipment including explosion-proof clothing, safety goggles, and respiratory protection. Work should be conducted in specialized facilities with explosion-proof equipment and proper ventilation. Avoid any sources of ignition, heat, friction, or shock. Only trained and authorized personnel should handle this substance following strict safety protocols and emergency procedures.

How to store 1,3,5-trinitrobenzene correctly?

1,3,5-trinitrobenzene must be stored in specialized explosive storage facilities that comply with strict safety regulations. The storage area should be cool, dry, and well-ventilated, away from any sources of heat, sparks, or incompatible materials. Containers must be explosion-proof and properly labeled. The substance should be kept separate from oxidizing agents, reducing agents, and organic materials. Regular inspection and temperature monitoring are essential for safe storage.

What to do in case of contact with 1,3,5-trinitrobenzene?

1,3,5-trinitrobenzene exposure requires immediate emergency response due to its acute toxicity. In case of skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting. Seek immediate medical attention in all cases and provide the safety data sheet to medical personnel.

How to dispose of 1,3,5-trinitrobenzene appropriately?

1,3,5-trinitrobenzene disposal must be conducted by specialized hazardous waste disposal companies licensed to handle explosive materials. The substance cannot be disposed of through normal waste channels due to its explosive and toxic properties. Disposal methods typically involve controlled detonation or specialized incineration under strict safety conditions. All disposal activities must comply with local and international regulations governing explosive waste materials and require proper documentation and permits.

How to transport 1,3,5-trinitrobenzene?

1,3,5-trinitrobenzene is classified as ADR Class 1 dangerous goods, requiring specialized transport procedures for explosive materials. Transportation must be conducted by certified carriers with proper explosive transport licenses and equipment. The substance requires specific packaging, labeling with GHS01, GHS06, GHS08, and GHS09 pictograms, and documentation. Vehicles must be equipped with appropriate safety equipment, and drivers must have specialized training for explosive materials transport.

Is 1,3,5-trinitrobenzene subject to particular regulations?

1,3,5-trinitrobenzene is subject to extensive regulations under REACH, CLP, and explosive materials legislation. The substance requires registration and authorization for use, with strict controls on manufacturing, import, and distribution. It falls under multiple hazard classifications including explosive, acute toxicity, and environmental hazards. Users must comply with occupational safety regulations, environmental protection laws, and specific explosive materials handling requirements. Regular reporting and monitoring may be mandatory.

Where to buy 1,3,5-trinitrobenzene in Europe?

1,3,5-trinitrobenzene can be sourced through OYSI, a European distributor of specialized chemical products with expertise in hazardous materials supply. Due to the explosive and highly toxic nature of this substance, purchases require proper authorization, licenses, and compliance verification. OYSI ensures regulatory compliance and provides technical support for safe handling and transport. Customers must demonstrate legitimate use and proper safety infrastructure before procurement of this controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.