2-dodecylbenzenesulfonic acid
C18H30O3S
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Identification
- CAS Number
- 27176-87-0
- EC Number
- 248-289-4
- UN Number
- 2586
- PubChem CID
- 25457
Physical-chemical properties
- Molecular Formula
- C18H30O3S
- Molar Mass
- 326.50 g/mol
- IUPAC Name
- 2-dodecylbenzenesulfonic acid
Chemical Identifiers
- InChI
- InChI=1S/C18H30O3S/c1-2-3-4-5-6-7-8-9-10-11-14-17-15-12-13-16-18(17)22(19,20)21/h12-13,15-16H,2-11,14H2,1H3,(H,19,20,21)
- InChI Key
- WBIQQQGBSDOWNP-UHFFFAOYSA-N
Overview
2-dodecylbenzenesulfonic acid (CAS 27176-87-0) is an organic sulfonic acid with a long alkyl chain providing surfactant properties and industrial cleaning applications. This aromatic sulfonic acid compound features a benzene ring substituted with both a twelve-carbon alkyl chain (dodecyl group) and a sulfonic acid functional group. The molecular structure combines the hydrophobic properties of the long alkyl chain with the hydrophilic characteristics of the sulfonic acid group, creating an amphiphilic molecule with significant industrial utility. With its molecular formula C18H30O3S and molecular weight of 326.5 g/mol, this compound exhibits excellent solubility characteristics and surface-active properties that make it valuable across various industrial sectors. The compound's safety profile indicates it is classified under ADR Class 8, designating it as a corrosive substance requiring appropriate handling precautions during transport and storage. Like other members of the benzenesulfonic acid family, it shares certain chemical reactivity patterns with related aromatic compounds, though its extended alkyl chain distinguishes it from simpler derivatives such as those used in the synthesis of compounds like 4-methoxybenzoyl chloride or benzene-1,4-dicarbonyl chloride. Primary industrial applications include its use as a surfactant in cleaning formulations, where its amphiphilic nature provides excellent detergency properties. It also serves as an intermediate in the production of various specialty chemicals and finds application in textile processing operations where its surface-active properties enhance fabric treatment processes. The compound's stability and effectiveness in both aqueous and non-aqueous systems make it particularly valuable for formulators developing industrial cleaning products and specialty chemical applications. OYSI supplies 2-dodecylbenzenesulfonic acid to meet the demanding requirements of European industrial customers across multiple sectors.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 2586 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Dodecylbenzensulfonsäure, freie Schwefelsäure <= 5 % |
| Marine Pollutant | No |
Frequently Asked Questions
What is 2-dodecylbenzenesulfonic acid?
2-dodecylbenzenesulfonic acid is an organic sulfonic acid compound with the molecular formula C18H30O3S and a molecular weight of 326.5 g/mol. It belongs to the family of alkylbenzenesulfonic acids, characterized by a benzene ring substituted with a dodecyl chain (12-carbon alkyl group) and a sulfonic acid group. This surfactant molecule combines hydrophobic alkyl chains with hydrophilic sulfonic acid functionality, making it valuable in various industrial applications requiring surface-active properties.
What are the physicochemical properties of 2-dodecylbenzenesulfonic acid?
2-dodecylbenzenesulfonic acid typically appears as a viscous liquid or semi-solid at room temperature, ranging from colorless to pale yellow. It exhibits characteristic sulfonic acid odor and demonstrates excellent solubility in polar solvents like water and alcohols due to its ionic sulfonic acid group. The compound shows typical surfactant behavior with both hydrophilic and lipophilic properties. Its molecular structure with the long dodecyl chain provides effective surface tension reduction capabilities in aqueous solutions.
What is 2-dodecylbenzenesulfonic acid used for?
2-dodecylbenzenesulfonic acid serves primarily as a surfactant and intermediate in detergent manufacturing, particularly for producing household and industrial cleaning products. It functions as an emulsifier in various formulations, helping to mix oil and water phases. The compound finds applications in textile processing, leather treatment, and as a catalyst in certain chemical reactions. Its surface-active properties make it valuable in personal care products, degreasing agents, and specialized industrial cleaning formulations.
How to handle 2-dodecylbenzenesulfonic acid safely?
2-dodecylbenzenesulfonic acid should be handled using standard chemical safety protocols including wearing appropriate personal protective equipment such as chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or use local exhaust ventilation to minimize vapor exposure. Avoid direct skin and eye contact, and prevent inhalation of vapors. Use non-sparking tools and equipment when transferring the material, and ensure proper grounding to prevent static electricity buildup during handling operations.
How to store 2-dodecylbenzenesulfonic acid correctly?
2-dodecylbenzenesulfonic acid should be stored in tightly closed containers made of compatible materials such as polyethylene or glass, away from direct sunlight and heat sources. Maintain storage temperatures in a cool, dry area to prevent degradation and maintain product stability. Keep containers sealed when not in use to prevent moisture absorption and contamination. Store away from incompatible materials including strong bases, oxidizing agents, and metals that may react with the acidic nature of the compound.
What to do in case of contact with 2-dodecylbenzenesulfonic acid?
In case of skin contact with 2-dodecylbenzenesulfonic acid, immediately remove contaminated clothing and rinse the affected area thoroughly with plenty of water for at least 15 minutes. For eye contact, flush eyes immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and monitor breathing. If ingested, rinse mouth with water and seek immediate medical attention. Do not induce vomiting unless directed by medical personnel.
How to dispose of 2-dodecylbenzenesulfonic acid appropriately?
2-dodecylbenzenesulfonic acid disposal must comply with local, national, and EU waste regulations including the Waste Framework Directive. The material should be collected by licensed waste disposal companies and treated at authorized facilities capable of handling acidic chemical waste. Small quantities may be neutralized carefully with appropriate bases before disposal, following proper safety procedures. Container disposal should follow local regulations for chemical packaging waste, ensuring complete emptying and proper labeling of residual contents.
How to transport 2-dodecylbenzenesulfonic acid?
2-dodecylbenzenesulfonic acid is classified under ADR as Class 8 (Corrosive substances), Packing Group III, indicating it requires specific transport regulations for corrosive materials. Packages must be properly labeled with appropriate hazard markings and conform to UN packaging standards for corrosive liquids. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR training certification, and transport must follow designated routes with restrictions on tunnel categories and parking locations as specified in ADR regulations.
Is 2-dodecylbenzenesulfonic acid subject to particular regulations?
2-dodecylbenzenesulfonic acid falls under REACH regulation requiring registration for manufacture or import above one tonne per year in the EU. The substance is not classified as SVHC (Substance of Very High Concern) and does not appear on restriction lists under REACH Annex XVII. It must comply with CLP regulation for classification and labeling requirements. Users must follow occupational safety regulations including workplace exposure limits where established, and ensure proper risk assessments are conducted for industrial applications.
Where to buy 2-dodecylbenzenesulfonic acid in Europe?
2-dodecylbenzenesulfonic acid is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides reliable supply chains for chemical intermediates and surfactants with appropriate documentation including safety data sheets and certificates of analysis. As a professional chemical distributor, OYSI ensures compliance with European regulations including REACH registration requirements and provides technical support for industrial applications requiring 2-dodecylbenzenesulfonic acid in various industries including detergents, textiles, and specialty chemicals.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.