2-amino-5-(4-aminophenyl)benzenesulfonic acid

C12H12N2O3S

CAS2051-89-0

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Identification

CAS Number
2051-89-0
EC Number
218-132-4
UN Number
2585
PubChem CID
16326

Physical-chemical properties

Molecular Formula
C12H12N2O3S
Molar Mass
264.30 g/mol
IUPAC Name
2-amino-5-(4-aminophenyl)benzenesulfonic acid

Chemical Identifiers

InChI
InChI=1S/C12H12N2O3S/c13-10-4-1-8(2-5-10)9-3-6-11(14)12(7-9)18(15,16)17/h1-7H,13-14H2,(H,15,16,17)
InChI Key
FGQDYDZVRHQDIN-UHFFFAOYSA-N

Overview

2-amino-5-(4-aminophenyl)benzenesulfonic acid (CAS 2051-89-0) is an aromatic organic compound featuring dual amino groups and sulfonic acid functionality for versatile chemical applications. This bifunctional aromatic compound represents an important intermediate in organic synthesis, characterized by its unique molecular structure containing both amine and sulfonic acid moieties. With the molecular formula C12H12N2O3S and a molecular weight of 264.3 g/mol, this substance exhibits excellent solubility in polar solvents due to its hydrophilic sulfonic acid group combined with the electron-donating properties of its amino substituents. The compound's structure features a benzene ring system with strategically positioned functional groups that enable diverse chemical transformations. The presence of two amino groups - one on the main benzene ring and another on the attached phenyl substituent - provides multiple reactive sites for further derivatization. This structural arrangement makes it particularly valuable in applications requiring selective functionalization or coupling reactions. From a safety perspective, the substance is classified under ADR Class 8, indicating corrosive properties typical of sulfonic acid derivatives. Proper handling procedures should include appropriate personal protective equipment and adequate ventilation to prevent exposure to dust or vapors. Primary industrial applications include its use as an intermediate in dye manufacturing, pharmaceutical synthesis, and specialty chemical production. The compound's reactivity profile makes it suitable for coupling reactions and condensation processes. It shares certain synthetic pathways with related compounds such as benzene-1,4-dicarbonyl chloride, which is also utilized in similar aromatic substitution chemistry. OYSI provides reliable access to 2-amino-5-(4-aminophenyl)benzenesulfonic acid for European industrial customers requiring high-quality chemical intermediates.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2585
ADR Class8
Packing GroupIII
Tunnel CodeE
Proper Shipping NameBenzidin-3-sulfonsäure, freie Schwefelsäure <= 5 %, fest
Marine PollutantNo

Frequently Asked Questions

What is 2-amino-5-(4-aminophenyl)benzenesulfonic acid?

2-amino-5-(4-aminophenyl)benzenesulfonic acid is an aromatic organic compound with the molecular formula C12H12N2O3S and CAS number 2051-89-0. This sulfonic acid derivative contains two amino groups and has a molecular weight of 264.3 g/mol. It belongs to the class of aminobenzenesulfonic acids and is characterized by its biphenyl structure with sulfonic and amino functional groups that provide specific chemical reactivity for various industrial applications.

What are the physicochemical properties of 2-amino-5-(4-aminophenyl)benzenesulfonic acid?

2-amino-5-(4-aminophenyl)benzenesulfonic acid is a solid compound at room temperature with a molecular weight of 264.3 g/mol. The presence of sulfonic acid and amino groups makes it highly polar and typically water-soluble. The compound exhibits typical aromatic characteristics due to its biphenyl structure. Its physicochemical behavior is influenced by the ionizable sulfonic acid group and the basic amino groups, which can affect solubility and stability under different pH conditions.

What is 2-amino-5-(4-aminophenyl)benzenesulfonic acid used for?

2-amino-5-(4-aminophenyl)benzenesulfonic acid is primarily used as an intermediate in the synthesis of dyes and pigments due to its aromatic structure with reactive amino groups. It serves as a building block in the production of azo dyes and other colorants for textile, printing, and coating industries. The compound may also find applications in pharmaceutical intermediates and specialty chemical synthesis where its specific functional group arrangement provides desired chemical properties for further derivatization.

How to handle 2-amino-5-(4-aminophenyl)benzenesulfonic acid safely?

2-amino-5-(4-aminophenyl)benzenesulfonic acid should be handled using standard laboratory safety practices including wearing appropriate personal protective equipment such as safety glasses, gloves, and lab coats. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation of dust particles. Avoid skin and eye contact, and prevent ingestion. Use proper handling techniques to minimize dust generation and ensure good hygiene practices including thorough handwashing after handling the material.

How to store 2-amino-5-(4-aminophenyl)benzenesulfonic acid properly?

2-amino-5-(4-aminophenyl)benzenesulfonic acid should be stored in a cool, dry, and well-ventilated area away from direct sunlight and heat sources. Keep the material in tightly sealed containers to prevent moisture absorption and contamination. Store away from strong oxidizing agents and incompatible materials. Maintain storage temperatures within recommended ranges and ensure proper labeling of containers. Regular inspection of storage conditions and container integrity helps maintain product quality and workplace safety.

What to do in case of contact with 2-amino-5-(4-aminophenyl)benzenesulfonic acid?

In case of skin contact with 2-amino-5-(4-aminophenyl)benzenesulfonic acid, immediately wash the affected area with plenty of soap and water for at least 15 minutes. For eye contact, flush thoroughly with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical advice if respiratory irritation occurs. In case of ingestion, rinse mouth with water and seek immediate medical attention. Always consult a physician if symptoms persist or worsen.

How to dispose of 2-amino-5-(4-aminophenyl)benzenesulfonic acid appropriately?

2-amino-5-(4-aminophenyl)benzenesulfonic acid waste must be disposed of according to local, national, and international environmental regulations. The material should not be discharged into sewers or waterways without proper treatment. Contact licensed waste disposal companies for proper handling and treatment of chemical waste. Consider recovery or recycling options where feasible. Ensure proper classification and documentation of waste streams according to applicable waste codes and regulations before disposal.

How to transport 2-amino-5-(4-aminophenyl)benzenesulfonic acid?

2-amino-5-(4-aminophenyl)benzenesulfonic acid is classified under ADR Class 8 (corrosive substances), Packing Group III for transport purposes. This classification requires appropriate packaging, labeling, and documentation according to dangerous goods regulations. Use UN-approved packaging suitable for corrosive materials and ensure proper hazard labels are affixed. Transport vehicles must comply with ADR requirements including equipment and driver training. Shipping documentation must include proper shipping names and classification codes.

Is 2-amino-5-(4-aminophenyl)benzenesulfonic acid subject to specific regulations?

2-amino-5-(4-aminophenyl)benzenesulfonic acid is subject to standard chemical regulations including REACH registration requirements in Europe for manufacture, import, or use above specified tonnage thresholds. The substance is not currently listed as a SVHC (Substance of Very High Concern) under REACH. Compliance with CLP regulation for classification, labeling, and packaging is required. Users must follow workplace safety regulations and environmental protection laws applicable in their jurisdiction for handling and use of chemical substances.

Where to buy 2-amino-5-(4-aminophenyl)benzenesulfonic acid in Europe?

2-amino-5-(4-aminophenyl)benzenesulfonic acid is available through OYSI, a leading European distributor of specialty chemicals and intermediates. OYSI provides reliable supply chains across Europe with proper documentation and regulatory compliance support. As a professional chemical distributor, OYSI ensures product quality, appropriate packaging, and technical support for industrial customers. Contact OYSI directly for availability, specifications, and pricing information to meet your specific application requirements and delivery needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.