1,4-bis(ethenoxymethyl)cyclohexane

C12H20O2

CAS17351-75-6
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
17351-75-6
EC Number
413-370-7
UN Number
3082
Index Number
603-148-00-X
PubChem CID
3437285

Physical-chemical properties

Molecular Formula
C12H20O2
Molar Mass
196.29 g/mol
IUPAC Name
1,4-bis(ethenoxymethyl)cyclohexane

Chemical Identifiers

InChI
InChI=1S/C12H20O2/c1-3-13-9-11-5-7-12(8-6-11)10-14-4-2/h3-4,11-12H,1-2,5-10H2
InChI Key
DQNSRQYYCSXZDF-UHFFFAOYSA-N

Overview

1,4-bis(ethenoxymethyl)cyclohexane (CAS 17351-75-6) is a cyclic divinyl ether compound with bifunctional crosslinking properties and skin sensitization potential. This specialized chemical compound belongs to the divinyl ether family and features a cyclohexane ring structure with two ethenoxymethyl substituents positioned at the 1,4-positions. With its molecular formula C12H20O2 and molecular weight of 196.29 g/mol, this substance exhibits unique chemical reactivity due to its dual vinyl ether functionality. The compound's structure enables it to participate in various polymerization reactions and crosslinking processes, making it valuable in advanced material applications. From a safety perspective, 1,4-bis(ethenoxymethyl)cyclohexane is classified as a skin sensitizer (Skin Sens. 1) and poses chronic aquatic toxicity concerns (Aquatic Chronic 2). The substance carries a "Warning" signal word and is associated with GHS07 and GHS09 pictograms, indicating both health and environmental hazards. Transport classification under ADR Class 9 designates it as a miscellaneous dangerous substance requiring appropriate handling precautions during shipping and storage. Industrial applications of this compound primarily focus on polymer chemistry and materials science. It serves as a crosslinking agent in specialized resin systems, contributing to enhanced mechanical properties and chemical resistance. The compound also finds use in coating formulations where controlled polymerization is essential, and in the production of advanced composite materials requiring precise molecular architecture. Unlike simpler compounds such as ethyl 6,8-dichlorooctanoate, this divinyl ether offers unique bifunctional reactivity patterns. OYSI provides reliable access to 1,4-bis(ethenoxymethyl)cyclohexane for qualified industrial customers across Europe, ensuring consistent quality and comprehensive technical support.

Safety & Classification

Warning
Classification:

Skin Sens. 1; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H317

May cause an allergic skin reaction.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping Name1,4-Bis[(vinyloxy)methyl]cyclohexan
Marine PollutantNo

Frequently Asked Questions

What is 1,4-bis(ethenoxymethyl)cyclohexane?

1,4-bis(ethenoxymethyl)cyclohexane is an organic chemical compound with the molecular formula C12H20O2 and CAS number 17351-75-6. This cyclohexane derivative features two ethenoxymethyl functional groups attached to the 1,4-positions of the cyclohexane ring. With a molecular weight of 196.29 g/mol, it belongs to the class of vinyl ethers and is classified as a skin sensitizer with chronic aquatic toxicity properties.

What are the physicochemical properties of 1,4-bis(ethenoxymethyl)cyclohexane?

1,4-bis(ethenoxymethyl)cyclohexane is a liquid organic compound at room temperature with a molecular weight of 196.29 g/mol. As a vinyl ether derivative, it typically exhibits low water solubility but good solubility in organic solvents. The compound contains reactive vinyl ether groups that make it susceptible to polymerization reactions. Its cyclohexane backbone provides structural stability while the ethenoxymethyl groups contribute to its chemical reactivity.

What is 1,4-bis(ethenoxymethyl)cyclohexane used for?

1,4-bis(ethenoxymethyl)cyclohexane is primarily used as a crosslinking agent and reactive diluent in polymer chemistry and materials science. Its dual vinyl ether functionality makes it valuable for UV-curable coatings, adhesives, and composite materials. The compound serves as a building block for specialty polymers and can be used in photopolymerization processes. It may also find applications in the synthesis of advanced materials requiring controlled crosslinking density.

How to handle 1,4-bis(ethenoxymethyl)cyclohexane safely?

1,4-bis(ethenoxymethyl)cyclohexane requires careful handling due to its skin sensitization properties (Skin Sens. 1). Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to minimize inhalation exposure. Avoid direct skin and eye contact. Use proper grounding procedures when transferring the material to prevent static electricity buildup, and keep away from heat sources and UV light.

How to store 1,4-bis(ethenoxymethyl)cyclohexane correctly?

1,4-bis(ethenoxymethyl)cyclohexane should be stored in a cool, dry, well-ventilated area away from direct sunlight and UV radiation sources. Keep containers tightly closed and protected from light to prevent unwanted polymerization. Store away from heat sources, ignition sources, and incompatible materials such as strong oxidizers and acids. Maintain storage temperatures below 25°C and consider adding polymerization inhibitors for long-term storage. Ensure proper labeling and inventory rotation.

What to do in case of contact with 1,4-bis(ethenoxymethyl)cyclohexane?

In case of skin contact with 1,4-bis(ethenoxymethyl)cyclohexane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Due to its skin sensitization properties, seek medical attention if irritation develops or persists. Do not induce vomiting if accidentally ingested and seek immediate medical advice.

How to dispose of 1,4-bis(ethenoxymethyl)cyclohexane appropriately?

1,4-bis(ethenoxymethyl)cyclohexane must be disposed of in accordance with local, national, and international waste regulations. As a chemical classified under GHS07 and GHS09, it requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper handling and incineration at authorized facilities. Do not discharge into sewers, waterways, or soil due to its aquatic chronic toxicity (Aquatic Chronic 2). Maintain detailed waste disposal records for regulatory compliance.

How to transport 1,4-bis(ethenoxymethyl)cyclohexane?

1,4-bis(ethenoxymethyl)cyclohexane is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transport purposes. It requires appropriate UN-specification packaging and proper shipping documentation including dangerous goods declarations. Vehicles must carry appropriate placards and emergency response information. Drivers need ADR training certification for transporting this material. Ensure packages are properly labeled with GHS pictograms (GHS07, GHS09) and hazard information during transport.

Is 1,4-bis(ethenoxymethyl)cyclohexane subject to specific regulations?

1,4-bis(ethenoxymethyl)cyclohexane is subject to various European chemical regulations including REACH registration requirements and CLP classification as Skin Sens. 1 and Aquatic Chronic 2. It is not currently listed as a Substance of Very High Concern (SVHC). Companies using this substance must comply with safety data sheet requirements, worker exposure limits, and environmental discharge restrictions. Users must implement appropriate risk management measures and may need to notify authorities depending on usage quantities and applications.

Where to buy 1,4-bis(ethenoxymethyl)cyclohexane in Europe?

1,4-bis(ethenoxymethyl)cyclohexane is available through OYSI, a specialized European distributor of technical chemicals and industrial raw materials. OYSI provides reliable supply chains across Europe with comprehensive technical support and regulatory documentation. As an established chemical distributor, OYSI ensures product quality, proper packaging, and compliance with European chemical regulations including REACH and CLP requirements. Contact OYSI directly for availability, technical specifications, and distribution throughout European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.