1,2,3,4,5-pentachloronaphthalene

C10H3Cl5

CAS1321-64-8
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
1321-64-8
EC Number
215-320-8
UN Number
3077
Index Number
602-041-00-5
PubChem CID
114878

Physical-chemical properties

Molecular Formula
C10H3Cl5
Molar Mass
300.40 g/mol
IUPAC Name
1,2,3,4,5-pentachloronaphthalene

Chemical Identifiers

InChI
InChI=1S/C10H3Cl5/c11-5-3-1-2-4-6(5)8(13)10(15)9(14)7(4)12/h1-3H
InChI Key
JRZKNHITLINYHV-UHFFFAOYSA-N

Overview

1,2,3,4,5-Pentachloronaphthalene (CAS 1321-64-8) is a polychlorinated naphthalene derivative with high chlorine substitution and persistent environmental characteristics. This chlorinated aromatic compound belongs to the family of polychlorinated naphthalenes (PCNs), featuring five chlorine atoms substituted on the naphthalene ring structure. With a molecular formula of C10H3Cl5 and molecular weight of 300.4 g/mol, 1,2,3,4,5-pentachloronaphthalene exhibits significant chemical stability and lipophilic properties typical of highly chlorinated aromatic compounds. The extensive chlorination pattern contributes to its persistence in environmental systems and biological tissues. From a safety perspective, this substance requires careful handling due to its classification under multiple hazard categories. It presents moderate acute toxicity risks through oral and dermal exposure routes, along with potential skin and eye irritation. Of particular concern are its aquatic toxicity properties, classified as both acutely and chronically hazardous to aquatic environments, reflecting the compound's poor biodegradability and bioaccumulation potential. The substance carries Warning signal word with GHS07 and GHS09 pictograms, and falls under ADR Class 9 for transport purposes. Industrial applications of 1,2,3,4,5-pentachloronaphthalene include use as an intermediate in specialty chemical synthesis and as a component in certain industrial formulations requiring high chemical stability. The compound may also find application in research and development activities, particularly in studies involving chlorinated aromatic systems. Unlike simpler compounds such as 2-methylpropyl 2-(oxiran-2-yl)acetate, this heavily chlorinated naphthalene requires specialized handling protocols due to its environmental persistence. OYSI maintains availability of 1,2,3,4,5-pentachloronaphthalene for qualified industrial customers requiring this specialized chlorinated aromatic compound for legitimate technical applications.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NamePentachlornaphthaline, Isomere oder Isomerengemisch
Marine PollutantNo

Frequently Asked Questions

What is 1,2,3,4,5-pentachloronaphthalene?

1,2,3,4,5-pentachloronaphthalene is a polychlorinated aromatic compound derived from naphthalene with five chlorine atoms substituted at positions 1, 2, 3, 4, and 5. With the molecular formula C10H3Cl5 and CAS number 1321-64-8, this substance has a molecular weight of 300.4 g/mol. It belongs to the family of chlorinated naphthalenes, which are synthetic organic compounds used in various industrial applications requiring chemical stability and specific properties.

What are the physicochemical properties of 1,2,3,4,5-pentachloronaphthalene?

1,2,3,4,5-pentachloronaphthalene is typically a solid crystalline substance at room temperature with a characteristic aromatic odor. The high degree of chlorination (five chlorine atoms) makes it relatively non-polar and poorly soluble in water, but soluble in organic solvents such as benzene, toluene, and chlorinated hydrocarbons. Its molecular structure provides thermal stability and resistance to degradation, making it persistent in environmental conditions.

What is 1,2,3,4,5-pentachloronaphthalene used for?

1,2,3,4,5-pentachloronaphthalene is used primarily in industrial applications requiring chemical stability and specific physical properties. It serves as an intermediate in chemical synthesis, particularly in the production of dyes, pigments, and other organic compounds. Its chlorinated structure makes it valuable in applications requiring flame retardancy or chemical resistance. It may also be used in research and analytical chemistry as a reference standard or reagent.

How to handle 1,2,3,4,5-pentachloronaphthalene safely?

1,2,3,4,5-pentachloronaphthalene must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use local exhaust ventilation to minimize inhalation exposure. The substance is classified as Acute Tox. 4, Skin Irrit. 2, and Eye Irrit. 2, requiring careful handling to avoid direct contact and inhalation of dust or vapors.

How to store 1,2,3,4,5-pentachloronaphthalene correctly?

1,2,3,4,5-pentachloronaphthalene should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly sealed to prevent contamination and moisture absorption. Store in original containers with proper labeling showing GHS07 and GHS09 pictograms. Ensure storage areas are equipped with appropriate spill containment measures and access is restricted to authorized personnel due to its hazardous classification.

What to do in case of contact with 1,2,3,4,5-pentachloronaphthalene?

In case of skin contact with 1,2,3,4,5-pentachloronaphthalene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult the safety data sheet for specific emergency procedures.

How to dispose of 1,2,3,4,5-pentachloronaphthalene appropriately?

1,2,3,4,5-pentachloronaphthalene must be disposed of as hazardous waste in accordance with local, national, and EU regulations. Due to its aquatic toxicity classification (Aquatic Acute 1, Aquatic Chronic 1), it cannot be discharged to water systems or regular waste streams. Contact licensed hazardous waste disposal companies for proper treatment, which typically involves high-temperature incineration in authorized facilities. Always consult local environmental authorities for specific disposal requirements.

How to transport 1,2,3,4,5-pentachloronaphthalene?

1,2,3,4,5-pentachloronaphthalene is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers with appropriate labeling and documentation. Transport vehicles must carry proper emergency equipment and drivers require ADR certification. Shipping documents must include the correct UN number, proper shipping name, hazard class, and packing group information according to international dangerous goods regulations.

Is 1,2,3,4,5-pentachloronaphthalene subject to special regulations?

1,2,3,4,5-pentachloronaphthalene is subject to REACH regulation requiring registration for manufacture or import above one tonne per year in the EU. It must be classified and labeled according to CLP regulation with Warning signal word and appropriate GHS pictograms (GHS07, GHS09). While not currently listed as SVHC, its environmental and health hazard profile means it may be subject to additional restrictions or monitoring requirements depending on specific applications and volumes used.

Where to buy 1,2,3,4,5-pentachloronaphthalene in Europe?

1,2,3,4,5-pentachloronaphthalene is available through OYSI, a European distributor specializing in technical chemicals. OYSI provides this substance with proper documentation including safety data sheets, certificates of analysis, and regulatory compliance information required for industrial use. As a specialized chemical distributor, OYSI ensures proper packaging, labeling, and transport according to ADR regulations while maintaining quality standards for professional applications across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.