1,1,1-trifluoroethane

C2H3F3

CAS420-46-2

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Identification

CAS Number
420-46-2
EC Number
206-996-5
UN Number
2035
PubChem CID
9868

Physical-chemical properties

Molecular Formula
C2H3F3
Molar Mass
84.04 g/mol
IUPAC Name
1,1,1-trifluoroethane

Chemical Identifiers

InChI
InChI=1S/C2H3F3/c1-2(3,4)5/h1H3
InChI Key
UJPMYEOUBPIPHQ-UHFFFAOYSA-N

Overview

1,1,1-Trifluoroethane (CAS 420-46-2) is a hydrofluorocarbon refrigerant with excellent thermodynamic properties and low toxicity characteristics. This fluorinated hydrocarbon compound, with the molecular formula C2H3F3, represents a significant advancement in refrigeration technology and specialized industrial applications. As a member of the hydrofluorocarbon (HFC) family, 1,1,1-trifluoroethane exhibits exceptional chemical stability and thermal properties that make it valuable across multiple industrial sectors. The compound's molecular structure, featuring three fluorine atoms attached to a single carbon atom, provides unique characteristics including non-flammability and excellent heat transfer capabilities. With a molecular weight of 84.04 g/mol, this colorless gas demonstrates remarkable safety properties, classified under ADR Class 2 for transportation purposes. Unlike more hazardous substances such as nitrous oxide or reactive compounds like iodane, 1,1,1-trifluoroethane presents minimal safety concerns during handling and storage, requiring no specific GHS pictograms or signal words. Its low global warming potential compared to traditional chlorofluorocarbons has positioned it as an environmentally preferred alternative in many applications. The compound finds primary application as a refrigerant in specialized cooling systems, particularly in pharmaceutical and electronics manufacturing where precise temperature control is critical. Additionally, it serves as an effective propellant in aerosol formulations and as a cleaning solvent in precision electronics manufacturing, where its non-conductive properties and rapid evaporation rate prove invaluable. OYSI maintains reliable supply chains for 1,1,1-trifluoroethane, ensuring consistent availability for European industrial customers requiring this specialized fluorocarbon compound.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2035
ADR Class2
Packing Group
Tunnel CodeB/D
Proper Shipping Name1,1,1-Trifluorethan, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is 1,1,1-trifluoroethane?

1,1,1-trifluoroethane is a fluorinated organic compound with the chemical formula C2H3F3 and CAS number 420-46-2. This colorless gas belongs to the hydrofluorocarbon (HFC) family and has a molecular weight of 84.04 g/mol. It is characterized by three fluorine atoms attached to one carbon atom and is commonly used as a refrigerant and propellant. The substance is relatively stable under normal conditions and exhibits low toxicity compared to other halogenated compounds.

What are the physicochemical properties of 1,1,1-trifluoroethane?

1,1,1-trifluoroethane is a colorless gas at room temperature with a faint ethereal odor. It has a boiling point of approximately -47°C and a melting point of around -111°C. The compound has low solubility in water but is soluble in most organic solvents. It exhibits good thermal stability and is non-flammable under normal atmospheric conditions. The substance has a density of about 3.66 kg/m³ at 15°C and atmospheric pressure, making it heavier than air.

What is 1,1,1-trifluoroethane used for?

1,1,1-trifluoroethane is primarily used as a refrigerant in commercial and industrial cooling systems, designated as R-143a. It serves as a propellant in aerosol applications and medical inhalers due to its non-toxic properties. The compound is also utilized in foam blowing applications for insulation materials and as a cleaning solvent in electronics manufacturing. Additionally, it finds use in fire suppression systems and as a component in specialized chemical synthesis processes where fluorinated intermediates are required.

How to handle 1,1,1-trifluoroethane safely?

1,1,1-trifluoroethane should be handled in well-ventilated areas to prevent accumulation of vapors. Use standard personal protective equipment including safety glasses and gloves when handling liquid form. Avoid sources of ignition even though the substance is non-flammable, as it may decompose at high temperatures. Ensure proper grounding of equipment to prevent static electricity buildup. Work in areas equipped with gas detection systems when handling large quantities, and always follow good industrial hygiene practices during use.

How to store 1,1,1-trifluoroethane correctly?

1,1,1-trifluoroethane should be stored in appropriate pressure vessels designed for compressed gases in cool, dry, and well-ventilated areas. Keep containers away from heat sources, direct sunlight, and temperatures above 50°C to prevent excessive pressure buildup. Store cylinders upright and properly secured to prevent falling. Avoid storage near incompatible materials such as strong oxidizers. Ensure storage areas have adequate ventilation and gas detection systems, and maintain temperatures below the critical point to prevent phase changes.

What to do in case of contact with 1,1,1-trifluoroethane?

1,1,1-trifluoroethane exposure typically requires moving the affected person to fresh air immediately if inhalation occurs. For skin contact with liquid form, remove contaminated clothing and flush the affected area with warm water to prevent frostbite. In case of eye contact, flush with clean water for at least 15 minutes and seek medical attention. If large amounts are inhaled and symptoms like dizziness occur, provide oxygen if available and seek immediate medical care. The substance has low acute toxicity but displacement of oxygen should be avoided.

How to dispose of 1,1,1-trifluoroethane appropriately?

1,1,1-trifluoroethane must be disposed of according to local environmental regulations as it is a fluorinated greenhouse gas. Contact licensed waste management companies specialized in handling refrigerant gases for proper recovery and destruction. Do not release the substance directly into the atmosphere due to its global warming potential. Empty containers should be properly degassed and recycled through appropriate metal recycling programs. Always consult with local environmental authorities and follow F-gas regulations for proper disposal procedures and documentation requirements.

How to transport 1,1,1-trifluoroethane?

1,1,1-trifluoroethane is classified under ADR Class 2 as a compressed gas for transportation purposes. It must be transported in DOT-approved pressure vessels with proper labeling indicating compressed gas hazards. Vehicles should be well-ventilated and equipped with appropriate emergency equipment. Transport documents must include proper shipping names, hazard classes, and emergency contact information. Drivers require specific training for hazardous materials transport, and vehicles must comply with routing restrictions and parking regulations applicable to compressed gas transport.

Is 1,1,1-trifluoroethane subject to specific regulations?

1,1,1-trifluoroethane is regulated under various European frameworks including REACH registration requirements and F-gas regulations due to its greenhouse gas properties. It is not classified as an SVHC substance but must comply with CLP classification and labeling requirements. The substance is subject to quotas and phase-down schedules under EU F-gas regulation 517/2014. Companies handling significant quantities must maintain records and report usage. Professional certification may be required for handling in refrigeration applications, and imports/exports require appropriate licensing and documentation.

Where to buy 1,1,1-trifluoroethane in Europe?

1,1,1-trifluoroethane is available through OYSI, a trusted European distributor of specialty chemicals and industrial gases. OYSI provides high-quality 1,1,1-trifluoroethane with proper documentation and regulatory compliance for various industrial applications. As a specialized chemical distributor, OYSI ensures reliable supply chains and technical support for customers across Europe. Contact OYSI directly for specific packaging options, quantities, and delivery arrangements tailored to your industrial requirements. All products come with appropriate safety documentation and regulatory compliance certificates.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.