1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane

P4S7

CAS12037-82-0

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Identification

CAS Number
12037-82-0
EC Number
234-868-9
UN Number
1339
PubChem CID
518483

Physical-chemical properties

Molecular Formula
P4S7
Molar Mass
348.40 g/mol
IUPAC Name
1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane

Chemical Identifiers

InChI
InChI=1S/P4S7/c5-4-9-1-6-2(10-4)8-3(7-1)11-4
InChI Key
LUGHFUPPCAAIHD-UHFFFAOYSA-N

Overview

1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane (CAS 12037-82-0) is a phosphorus-sulfur compound with a complex tricyclic cage structure and molecular formula P4S7. This specialized organophosphorus compound represents an important member of the phosphorus sulfide family, characterized by its unique tricyclic framework containing four phosphorus atoms and seven sulfur atoms. With a molecular weight of 348.4 g/mol and EC number 234-868-9, this compound exhibits distinctive structural properties that make it valuable in various technical applications. The lambda5 designation indicates the specific oxidation state and coordination geometry of the phosphorus centers within the cage-like structure. The compound belongs to ADR class 4.1, indicating it is classified as a flammable solid requiring appropriate handling precautions during transportation and storage. While it does not carry specific GHS pictograms or signal words under standard classifications, proper safety protocols should be maintained when working with this material, including adequate ventilation and protection from moisture and heat sources. Unlike simpler compounds such as 1,3,5,7-tetrazatricyclo[3.3.1.13,7]decane which features nitrogen atoms in its cage structure, this phosphorus-sulfur variant offers unique reactivity patterns particularly valuable in flame retardant applications and specialized polymer chemistry. The compound finds primary industrial use in the development of advanced flame retardant systems, where its phosphorus-sulfur composition provides effective thermal protection mechanisms. Additionally, it serves as a specialized reagent in organophosphorus synthesis and as an intermediate in the production of technical polymers requiring enhanced fire resistance properties. OYSI maintains reliable supply chains for this technical-grade compound, supporting European manufacturers with consistent quality and regulatory compliance documentation.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1339
ADR Class4.1
Packing GroupII
Tunnel CodeE
Proper Shipping NamePhosphorheptasulfid, frei von gelbem oder weißem Phosphor
Marine PollutantNo

Frequently Asked Questions

What is 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane is an inorganic compound with the molecular formula P4S7 and CAS number 12037-82-0. This phosphorus sulfide compound has a complex tricyclic structure containing four phosphorus atoms and seven sulfur atoms. With a molecular weight of 348.4 g/mol, it belongs to the family of binary phosphorus-sulfur compounds used in various industrial applications requiring specific chemical reactivity properties.

What are the physicochemical properties of 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

P4S7 is typically a yellow to orange crystalline solid at room temperature with a characteristic sulfur-like odor. The compound is insoluble in water but may dissolve in certain organic solvents. It exhibits high thermal stability under normal conditions and has a density higher than water due to its phosphorus and sulfur content. The tricyclic structure gives it unique chemical reactivity, particularly in reactions involving nucleophilic substitution and coordination chemistry applications.

What is 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane used for?

P4S7 is primarily used as a reagent in organic synthesis, particularly for introducing sulfur functionality into organic molecules. It serves as a sulfurizing agent in the preparation of organosulfur compounds and can be used in the synthesis of heterocyclic compounds. The compound also finds applications in materials science for preparing phosphorus-sulfur containing polymers and in specialty chemical manufacturing where controlled sulfur transfer reactions are required for specific product formulations.

How to safely handle 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

P4S7 should be handled with standard laboratory safety equipment including safety glasses, chemical-resistant gloves, and lab coats. Work should be conducted in a well-ventilated area or under a fume hood to avoid inhalation of any dust or vapors. Avoid contact with skin, eyes, and clothing. Use appropriate tools for transferring the material to minimize direct contact. Keep away from heat sources, open flames, and incompatible materials. Always wash hands thoroughly after handling.

How to properly store 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

P4S7 should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly closed and protected from moisture to prevent degradation. Store away from strong oxidizing agents, bases, and metals that might react with the compound. Use appropriate secondary containment and ensure storage areas are equipped with proper ventilation. Check containers regularly for signs of damage or deterioration and maintain proper inventory records.

What to do in case of contact with 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

In case of skin contact with P4S7, immediately remove contaminated clothing and wash the affected area with soap and plenty of water for at least 15 minutes. If eye contact occurs, flush eyes with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately. If ingested, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms develop or persist after exposure.

How to properly dispose of 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

P4S7 waste must be disposed of in accordance with local, regional, and national environmental regulations. The compound should not be disposed of in regular waste streams or sewage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may require neutralization or chemical treatment before disposal. Always consult local environmental authorities for specific disposal requirements and maintain proper documentation of waste disposal activities.

How to transport 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane?

P4S7 is classified under ADR as Class 4.1 (Flammable solids), Packing Group II, indicating it requires special transport considerations. Packages must comply with appropriate UN packaging specifications and be properly labeled with hazard markings. Transport vehicles should be equipped with appropriate safety equipment and drivers must have proper training for hazardous materials transport. Ensure compliance with all applicable transport regulations and maintain proper shipping documentation during transit.

Is 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane subject to special regulations?

P4S7 is not classified as a SVHC (Substance of Very High Concern) under REACH regulation. However, it must comply with standard REACH registration requirements for chemical substances manufactured or imported in the EU above specified tonnage thresholds. Users must follow CLP regulation requirements for classification, labeling, and packaging. Companies should maintain safety data sheets and ensure compliance with occupational health and safety regulations in their respective jurisdictions.

Where to buy 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane in Europe?

P4S7 is available through OYSI, a European distributor specializing in technical chemical products for industrial and research applications. OYSI provides reliable supply chains across Europe with proper documentation and regulatory compliance. Contact OYSI directly for availability, packaging options, and delivery arrangements. As a specialized chemical distributor, OYSI ensures product quality and provides technical support for customers requiring this phosphorus-sulfur compound for their specific applications.

Services for 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane

ADR Consulting for 1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane

1-sulfanylidene-2,4,6,8,9,10-hexathia-1lambda5,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.