4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide

C12H14N4O5S2

CAS80-51-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
80-51-3
EC Number
201-286-1
UN Number
3226
Index Number
607-758-00-7
PubChem CID
6649

Physical-chemical properties

Molecular Formula
C12H14N4O5S2
Molar Mass
358.40 g/mol
IUPAC Name
4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide

Chemical Identifiers

InChI
InChI=1S/C12H14N4O5S2/c13-15-22(17,18)11-5-1-9(2-6-11)21-10-3-7-12(8-4-10)23(19,20)16-14/h1-8,15-16H,13-14H2
InChI Key
NBOCQTNZUPTTEI-UHFFFAOYSA-N

Overview

4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide (CAS 80-51-3) is an organic sulfonohydrazide compound with self-reactive properties and environmental hazard characteristics. This specialized chemical compound, with the molecular formula C12H14N4O5S2 and a molecular weight of 358.4 g/mol, belongs to the family of sulfonohydrazides known for their unique reactive properties. The compound features a distinctive diphenyl ether backbone substituted with two sulfonohydrazide functional groups, which contribute to its self-reactive nature and chemical versatility. Its European classification number EC 201-286-1 facilitates regulatory compliance across European markets. The substance exhibits significant safety considerations due to its self-reactive classification (Self-react. D), requiring careful handling protocols and appropriate storage conditions. The presence of GHS02 and GHS09 pictograms indicates both fire hazard and environmental danger, while its ADR Class 4.1 classification designates it as a flammable solid requiring specialized transportation procedures. The compound demonstrates acute and chronic aquatic toxicity, necessitating environmental protection measures during handling and disposal. Industrial applications typically leverage the compound's reactive sulfonohydrazide groups for specialized chemical synthesis and manufacturing processes. The chemical industry commonly employs this substance in the production of specialized polymers and as an intermediate in pharmaceutical synthesis. Additionally, it finds application in advanced materials development where controlled reactivity is essential. While structurally distinct from compounds like copper bis(N-cyclohexyl-N-oxidonitrous amide) or bis(3,5-ditert-butyl-2-hydroxybenzoic acid);zinc, this sulfonohydrazide shares certain reactive characteristics that make it valuable in similar industrial applications requiring controlled chemical reactivity. OYSI provides reliable access to 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide with comprehensive technical support and regulatory documentation for European industrial customers.

Safety & Classification

Danger
Classification:

Self-react. D; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H242

Heating may cause a fire.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number3226
ADR Class4.1
Packing Group
Tunnel CodeD
Proper Shipping NameDiphenyloxid-4,4'-disulfonylhydrazid, Konz. = 100 %
Marine PollutantNo

Frequently Asked Questions

What is 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide?

4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide is an organic chemical compound with CAS number 80-51-3 and molecular formula C12H14N4O5S2. This substance has a molecular weight of 358.4 g/mol and belongs to the class of sulfonohydrazide compounds. It is classified as a self-reactive substance with significant environmental hazards, requiring careful handling and storage protocols in industrial applications.

What are the physicochemical properties of 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide?

4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide is a solid organic compound with a molecular weight of 358.4 g/mol. The substance contains sulfonohydrazide functional groups connected through a phenoxy bridge, giving it specific chemical reactivity patterns. Its self-reactive nature (Class D) indicates moderate thermal sensitivity, requiring controlled temperature conditions during handling and storage to prevent decomposition reactions.

What is 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide used for?

4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide is primarily used as a chemical intermediate in pharmaceutical and fine chemical synthesis. Its sulfonohydrazide structure makes it valuable in the production of specialized organic compounds and as a reagent in chemical research applications. The compound's reactive properties allow it to participate in various chemical transformations, particularly in the development of pharmaceutical intermediates and specialty chemicals.

How to handle 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide safely?

Safe handling requires appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its 'Danger' signal word classification. Work in well-ventilated areas or under fume extraction to prevent inhalation exposure. Avoid sources of ignition, heat, and friction due to its self-reactive properties (GHS02 pictogram). Ground all equipment to prevent static discharge and implement strict temperature control during processing operations.

How to store 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide correctly?

Proper storage requires cool, dry conditions away from heat sources, direct sunlight, and ignition sources due to its self-reactive classification (Self-react. D). Store in original, tightly sealed containers in a well-ventilated area with temperature control. Keep separate from incompatible materials including strong oxidizers and reducing agents. Implement regular temperature monitoring and ensure storage areas have appropriate fire suppression systems designed for chemical hazards.

What to do in case of contact with 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide?

Immediate first aid measures include removing contaminated clothing and flushing affected skin areas with plenty of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. For ingestion, do not induce vomiting and seek immediate medical care. Always consult the safety data sheet for specific first aid protocols.

How to dispose of 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide appropriately?

Disposal must comply with local and national waste regulations as hazardous chemical waste due to its self-reactive and environmental hazard classifications. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Do not discharge into sewers or waterways due to its aquatic toxicity (Aquatic Acute 1, Aquatic Chronic 1). Neutralization or incineration at authorized facilities may be required, following specific protocols for self-reactive substances.

How to transport 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide?

Transportation falls under ADR Class 4.1 (flammable solids) due to its self-reactive properties, requiring specialized packaging and documentation. Use UN-approved packaging suitable for self-reactive substances with appropriate labeling including GHS02 and GHS09 pictograms. Transport vehicles must comply with ADR regulations for Class 4.1 materials, including proper segregation from incompatible substances and temperature control measures during transit.

Is 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide subject to specific regulations?

Yes, the substance is subject to multiple regulatory frameworks including REACH registration requirements for European markets and CLP classification as Self-react. D with environmental hazards. It requires specific labeling with 'Danger' signal word and appropriate pictograms (GHS02, GHS09). The compound is not currently listed as an SVHC (Substance of Very High Concern), but its environmental classification requires compliance with aquatic protection regulations.

Where to buy 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide in Europe?

OYSI serves as a reliable European distributor for 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide, offering technical support and regulatory compliance assistance. As a specialized chemical distributor, OYSI provides appropriate packaging, documentation, and safety data sheets required for this self-reactive substance. Contact OYSI directly for availability, technical specifications, and delivery options across European markets, ensuring full compliance with transportation and handling regulations.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.