Zinc bis(N,N-diethylcarbamodithioate)

C10H20N2S4Zn

zinc bis(N,N-diethylcarbamodithioate)

CAS14324-55-1
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
14324-55-1
EC Number
238-270-9
UN Number
3077
Index Number
006-082-00-4
PubChem CID
26633

Physical-chemical properties

Molecular Formula
C10H20N2S4Zn
Molar Mass
361.90 g/mol
IUPAC Name
zinc bis(N,N-diethylcarbamodithioate)

Chemical Identifiers

InChI
InChI=1S/2C5H11NS2.Zn/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2
InChI Key
RKQOSDAEEGPRER-UHFFFAOYSA-L

Overview

Zinc bis(N,N-diethylcarbamodithioate) (CAS 14324-55-1) is an organozinc dithiocarbamate compound with accelerating properties and antimicrobial activity. This zinc-based dithiocarbamate represents a significant class of organometallic compounds widely utilized in industrial applications requiring controlled chemical acceleration and biocidal properties. With the molecular formula C10H20N2S4Zn and a molecular weight of 361.9 g/mol, this compound demonstrates the characteristic coordination chemistry of zinc with sulfur-containing ligands. The bis-structure indicates that two diethylcarbamodithioate ligands coordinate to a central zinc atom, forming a stable complex that exhibits both the reactivity of the organic ligands and the catalytic properties of the metal center. From a safety perspective, zinc bis(N,N-diethylcarbamodithioate) requires careful handling due to its classification under multiple hazard categories. The compound exhibits acute toxicity (Category 4), skin and eye irritation properties, skin sensitization potential, and specific target organ toxicity. Environmental considerations are particularly important, as it demonstrates acute aquatic toxicity, necessitating proper containment and disposal protocols. The GHS07 and GHS09 pictograms reflect these health and environmental hazards, while its ADR Class 9 classification indicates it as a miscellaneous dangerous substance for transport purposes. Industrial applications primarily center on rubber vulcanization acceleration, where it functions as an ultra-accelerator in sulfur vulcanization systems. The compound also finds use in specialized antimicrobial formulations and as a catalyst in certain polymerization processes. Unlike simpler compounds such as triphenyl phosphite, this organozinc complex offers both catalytic metal activity and organic functionality in a single molecule. OYSI maintains reliable supply chains for zinc bis(N,N-diethylcarbamodithioate) to support European industrial customers requiring consistent quality and regulatory compliance.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Ch...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameZinkbis(diethyldithiocarbamat)
Marine PollutantNo

Frequently Asked Questions

What is zinc bis(N,N-diethylcarbamodithioate)?

Zinc bis(N,N-diethylcarbamodithioate) is an organometallic compound with the molecular formula C10H20N2S4Zn and CAS number 14324-55-1. This zinc-based dithiocarbamate has a molecular weight of 361.9 g/mol and belongs to the family of metal carbamates. It is primarily used as an accelerator in rubber vulcanization processes and exhibits moderate toxicity with skin and eye irritation properties.

What are the physicochemical properties of zinc bis(N,N-diethylcarbamodithioate)?

Zinc bis(N,N-diethylcarbamodithioate) typically appears as a white to off-white crystalline powder with a characteristic sulfur-like odor. It has limited water solubility but dissolves well in organic solvents such as acetone and chloroform. The compound is stable under normal conditions but may decompose when exposed to strong acids or high temperatures, releasing potentially harmful sulfur compounds.

What is zinc bis(N,N-diethylcarbamodithioate) used for?

Zinc bis(N,N-diethylcarbamodithioate) is primarily used as a vulcanization accelerator in the rubber industry for manufacturing tires, seals, gaskets, and other rubber products. It facilitates the cross-linking process during rubber curing, improving the final product's mechanical properties. Additionally, it finds applications in the production of latex products and serves as an intermediate in certain chemical synthesis processes.

How to handle zinc bis(N,N-diethylcarbamodithioate) safely?

Safe handling of zinc bis(N,N-diethylcarbamodithioate) requires appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its skin and eye irritation properties. Ensure adequate ventilation to prevent inhalation exposure. Avoid direct skin contact and use in well-ventilated areas. Workers should be trained on proper handling procedures and emergency response protocols.

How to store zinc bis(N,N-diethylcarbamodithioate) correctly?

Zinc bis(N,N-diethylcarbamodithioate) should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly sealed and store away from strong acids, oxidizing agents, and incompatible materials. Maintain storage temperatures below 25°C and ensure proper segregation from food, feed, and drinking water. Use appropriate containment measures to prevent environmental release.

What to do in case of contact with zinc bis(N,N-diethylcarbamodithioate)?

In case of skin contact with zinc bis(N,N-diethylcarbamodithioate), immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move to fresh air immediately. Seek medical attention if irritation persists or symptoms develop.

How to dispose of zinc bis(N,N-diethylcarbamodithioate) appropriately?

Disposal of zinc bis(N,N-diethylcarbamodithioate) must comply with local and national waste regulations due to its environmental hazard classification. The material should be treated as hazardous waste and disposed of through licensed waste management facilities. Never discharge into sewers, water courses, or onto the ground. Collect spillages and contaminated materials in appropriate containers for proper disposal through authorized chemical waste handlers.

How to transport zinc bis(N,N-diethylcarbamodithioate)?

Zinc bis(N,N-diethylcarbamodithioate) is classified as ADR Class 9 (Miscellaneous Dangerous Substances), Packing Group III for transport purposes. It requires appropriate packaging, labeling, and documentation according to dangerous goods regulations. Shipments must include proper shipping names, hazard labels, and safety data sheets. Transport vehicles should be equipped with appropriate emergency equipment and drivers must have proper training for hazardous materials transport.

Is zinc bis(N,N-diethylcarbamodithioate) subject to particular regulations?

Zinc bis(N,N-diethylcarbamodithioate) is subject to REACH regulation requiring registration for manufacturing or importing above one tonne annually. It is classified under CLP regulation with hazard pictograms GHS07 and GHS09, requiring appropriate labeling and safety data sheets. While not currently listed as SVHC, it requires compliance with chemical safety assessments and may be subject to additional national restrictions in some European countries.

Where to buy zinc bis(N,N-diethylcarbamodithioate) in Europe?

Zinc bis(N,N-diethylcarbamodithioate) is available through OYSI, a European distributor of technical chemicals serving various industrial sectors. OYSI provides this product with complete regulatory documentation, safety data sheets, and technical support to ensure compliance with European regulations. Contact OYSI directly for product specifications, availability, and delivery options tailored to your specific industrial requirements across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.