Tris(4-nonylphenyl) phosphite

C45H69O3P

tris(4-nonylphenyl) phosphite

CAS26523-78-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
26523-78-4
EC Number
247-759-6
UN Number
3082
Index Number
015-202-00-4
PubChem CID
76452

Physical-chemical properties

Molecular Formula
C45H69O3P
Molar Mass
689.00 g/mol
IUPAC Name
tris(4-nonylphenyl) phosphite

Chemical Identifiers

InChI
InChI=1S/C45H69O3P/c1-4-7-10-13-16-19-22-25-40-28-34-43(35-29-40)46-49(47-44-36-30-41(31-37-44)26-23-20-17-14-11-8-5-2)48-45-38-32-42(33-39-45)27-24-21-18-15-12-9-6-3/h28-39H,4-27H2,1-3H3
InChI Key
MGMXGCZJYUCMGY-UHFFFAOYSA-N

Overview

Tris(4-nonylphenyl) phosphite (CAS 26523-78-4) is an organophosphorus antioxidant compound with excellent thermal stability and processing protection properties. This specialized phosphite ester serves as a crucial secondary antioxidant in polymer processing and stabilization applications. With its molecular formula C45H69O3P and molecular weight of 689 g/mol, tris(4-nonylphenyl) phosphite exhibits superior performance in preventing polymer degradation during high-temperature processing conditions. The compound's unique structure, featuring three nonylphenyl groups attached to a central phosphite core, provides enhanced compatibility with various polymer matrices while delivering effective antioxidant protection. The substance carries specific safety considerations, classified under GHS pictograms GHS07 and GHS09 with a "Warning" signal word. It presents skin sensitization properties (Skin Sens. 1) and poses environmental concerns due to its aquatic toxicity classification (Aquatic Acute 1; Aquatic Chronic 1). Proper handling protocols must be implemented to ensure worker safety and environmental protection during storage, processing, and application. Primary industrial applications include polymer stabilization in polyolefins, PVC processing, and rubber manufacturing, where it works synergistically with primary antioxidants to extend product lifetime and maintain material properties. The compound is particularly valued in automotive plastics, packaging materials, and industrial polymer applications requiring long-term thermal stability. Unlike simpler organophosphorus compounds such as butyl(triphenyl)boranuide;tetrabutylazanium, this phosphite offers superior processing stability in demanding applications. OYSI maintains reliable supply chains for tris(4-nonylphenyl) phosphite, ensuring consistent availability for European industrial customers requiring high-quality polymer stabilization solutions.

Safety & Classification

Warning
Classification:

Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameTris(nonylphenyl)phosphit
Marine PollutantNo

Frequently Asked Questions

What is tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite is an organophosphorus compound with the molecular formula C45H69O3P and CAS number 26523-78-4. This chemical compound has a molecular weight of 689 g/mol and belongs to the phosphite ester family. It is classified as a skin sensitizer and poses acute and chronic aquatic toxicity risks, requiring careful handling and environmental protection measures during use.

What are the physicochemical properties of tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite is a complex organic phosphite ester with a high molecular weight of 689 g/mol. As a phosphite compound, it typically exists as a liquid or viscous material at room temperature. The compound contains three nonylphenyl groups attached to a central phosphite structure, giving it significant hydrophobic characteristics and limited water solubility due to its large organic substituents.

What is tris(4-nonylphenyl) phosphite used for?

Tris(4-nonylphenyl) phosphite is primarily used as an antioxidant and stabilizer in polymer processing and plastic manufacturing. It serves as a secondary antioxidant that works synergistically with primary antioxidants to prevent polymer degradation during processing and end-use. The compound is particularly effective in protecting polymers from thermal and oxidative degradation, extending the service life of plastic products and maintaining their mechanical properties.

How to handle tris(4-nonylphenyl) phosphite safely?

Tris(4-nonylphenyl) phosphite must be handled with appropriate personal protective equipment due to its skin sensitization properties. Wear chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Ensure adequate ventilation in work areas and avoid generating dust or vapors. The compound requires warning labeling with GHS07 and GHS09 pictograms, indicating health and environmental hazards.

How to store tris(4-nonylphenyl) phosphite correctly?

Tris(4-nonylphenyl) phosphite should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers away from incompatible materials such as strong oxidizing agents and acids. Store in original packaging with proper hazard labeling intact. Maintain storage temperatures according to supplier specifications to prevent degradation and ensure product stability over time.

What to do in case of contact with tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite contact requires immediate first aid due to its skin sensitization properties. In case of skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes. If irritation develops or persists, seek medical attention promptly and provide the safety data sheet to medical personnel.

How to dispose of tris(4-nonylphenyl) phosphite appropriately?

Tris(4-nonylphenyl) phosphite must be disposed of as hazardous waste due to its environmental classification as aquatic acute and chronic toxic. Do not discharge to sewers, waterways, or soil. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Follow local and national environmental regulations for hazardous chemical waste. Contaminated packaging should also be treated as hazardous waste and disposed of accordingly.

How to transport tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite is classified as ADR Class 9 (miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification indicates it presents a relatively lower degree of danger during transport but still requires proper packaging, labeling, and documentation. Shipments must comply with dangerous goods regulations, including appropriate packaging specifications, hazard labels, and transport documentation according to ADR requirements.

Is tris(4-nonylphenyl) phosphite subject to specific regulations?

Tris(4-nonylphenyl) phosphite is subject to REACH regulation in Europe and must be registered for commercial use. Under CLP regulation, it requires classification and labeling as Skin Sens. 1, Aquatic Acute 1, and Aquatic Chronic 1 with warning signal word. The substance is not currently listed as SVHC (Substance of Very High Concern), but its environmental toxicity requires compliance with environmental protection regulations and proper risk management measures.

Where to buy tris(4-nonylphenyl) phosphite in Europe?

Tris(4-nonylphenyl) phosphite is available through OYSI, a specialized European distributor of technical chemicals and industrial raw materials. OYSI provides this phosphite antioxidant to polymer manufacturers, plastic processors, and other industrial users across Europe. As a professional chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for hazardous chemicals like tris(4-nonylphenyl) phosphite throughout the European market.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.