Tris(4-nonylphenyl) phosphite

C45H69O3P

tris(4-nonylphenyl) phosphite

CAS26523-78-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
26523-78-4
EC Number
247-759-6
UN Number
3082
Index Number
015-202-00-4
PubChem CID
76452

Physical-chemical properties

Molecular Formula
C45H69O3P
Molar Mass
689.00 g/mol
IUPAC Name
tris(4-nonylphenyl) phosphite

Chemical Identifiers

InChI
InChI=1S/C45H69O3P/c1-4-7-10-13-16-19-22-25-40-28-34-43(35-29-40)46-49(47-44-36-30-41(31-37-44)26-23-20-17-14-11-8-5-2)48-45-38-32-42(33-39-45)27-24-21-18-15-12-9-6-3/h28-39H,4-27H2,1-3H3
InChI Key
MGMXGCZJYUCMGY-UHFFFAOYSA-N

Overview

Tris(4-nonylphenyl) phosphite (CAS 26523-78-4) is an organophosphorus antioxidant compound featuring three nonylphenyl groups attached to a central phosphite structure. This specialized phosphite ester serves as an important processing stabilizer in polymer chemistry and industrial applications. With its molecular formula C45H69O3P and molecular weight of 689 g/mol, tris(4-nonylphenyl) phosphite belongs to the family of hindered phenolic phosphites that provide excellent thermal and oxidative stability. The compound's structure combines the stabilizing properties of phosphite groups with the steric protection offered by bulky nonylphenyl substituents, making it particularly effective in preventing polymer degradation during high-temperature processing. From a safety perspective, tris(4-nonylphenyl) phosphite requires careful handling due to its classification as a skin sensitizer (Skin Sens. 1) and its potential environmental impact, being classified as both acutely and chronically toxic to aquatic life (Aquatic Acute 1; Aquatic Chronic 1). The compound displays GHS07 and GHS09 pictograms with a "Warning" signal word, indicating the need for appropriate personal protective equipment and environmental precautions during use. Its ADR classification as Class 9 reflects its status as a miscellaneous dangerous substance for transportation purposes. In industrial applications, this phosphite compound finds primary use as a secondary antioxidant in polymer processing, particularly in polyolefins and engineering plastics where it works synergistically with primary antioxidants to extend material lifespan. It also serves in the stabilization of synthetic lubricants and as a processing aid in rubber compounding. Unlike simpler compounds such as butyl(triphenyl)boranuide;tetrabutylazanium, tris(4-nonylphenyl) phosphite offers superior thermal stability for demanding applications. OYSI maintains reliable supply chains for tris(4-nonylphenyl) phosphite to serve the European technical chemical market.

Safety & Classification

Warning
Classification:

Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameTris(nonylphenyl)phosphit
Marine PollutantNo

Frequently Asked Questions

What is tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite is an organophosphorus compound with the molecular formula C45H69O3P and CAS number 26523-78-4. This chemical substance has a molecular weight of 689 g/mol and belongs to the phosphite ester family. It is classified as a skin sensitizer and poses acute and chronic hazards to aquatic environments, requiring careful handling and environmental protection measures during use and disposal.

What are the physicochemical properties of tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite is typically a viscous liquid or solid at room temperature due to its high molecular weight of 689 g/mol. As an organophosphorus compound with long nonylphenyl chains, it exhibits low water solubility but good solubility in organic solvents. The compound's physical state and appearance can vary depending on temperature and purity, with its large molecular structure contributing to its viscous nature.

What is tris(4-nonylphenyl) phosphite used for?

Tris(4-nonylphenyl) phosphite is primarily used as an antioxidant and stabilizer in polymer processing and plastic manufacturing. It serves as a secondary antioxidant, protecting materials from oxidative degradation during processing and extending their service life. The compound is particularly valuable in applications requiring thermal stability and protection against polymer chain scission, making it essential in various industrial polymer formulations and specialty chemical applications.

How to handle tris(4-nonylphenyl) phosphite safely?

Tris(4-nonylphenyl) phosphite requires careful handling due to its skin sensitization properties (Skin Sens. 1). Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin contact. Ensure adequate ventilation in work areas and avoid generating dust or vapors. Follow proper hygiene practices, wash hands thoroughly after handling, and never eat, drink, or smoke in work areas.

How to store tris(4-nonylphenyl) phosphite correctly?

Tris(4-nonylphenyl) phosphite should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and protected from moisture to prevent degradation. Store away from oxidizing agents and incompatible materials. Maintain storage temperatures according to supplier specifications and ensure proper labeling with hazard warnings. Implement appropriate spill containment measures to protect the environment from potential contamination.

What to do in case of contact with tris(4-nonylphenyl) phosphite?

Immediate action is required if contact with tris(4-nonylphenyl) phosphite occurs due to its skin sensitizing properties. For skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, rinse immediately with clean water for 15 minutes. Seek medical attention if irritation persists or if sensitization symptoms develop. Do not induce vomiting if ingested.

How to dispose of tris(4-nonylphenyl) phosphite appropriately?

Tris(4-nonylphenyl) phosphite must be disposed of as hazardous waste due to its aquatic toxicity classification (Aquatic Acute 1; Aquatic Chronic 1). Contact licensed waste disposal contractors specialized in chemical waste management. Never discharge into sewers, waterways, or soil. Small quantities should be absorbed with inert material and placed in appropriate containers. Follow local and national environmental regulations, and maintain proper documentation for waste disposal activities.

How to transport tris(4-nonylphenyl) phosphite?

Tris(4-nonylphenyl) phosphite is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification indicates it requires proper packaging, labeling, and documentation during transport. Use UN-approved packaging and ensure proper hazard labels are affixed. Transport vehicles must carry appropriate emergency equipment and documentation. Follow ADR regulations for loading, segregation, and route restrictions to ensure safe transportation.

Is tris(4-nonylphenyl) phosphite subject to specific regulations?

Tris(4-nonylphenyl) phosphite is subject to REACH regulation as a chemical substance manufactured or imported in the EU. It is classified under CLP regulation with harmonized hazard classifications including skin sensitization and aquatic toxicity. While not currently listed as an SVHC (Substance of Very High Concern), users must comply with safety data sheet requirements, classification and labeling obligations, and environmental protection measures under European chemical legislation.

Where to buy tris(4-nonylphenyl) phosphite in Europe?

Tris(4-nonylphenyl) phosphite is available through OYSI, a specialized European distributor of technical chemicals and industrial raw materials. OYSI provides reliable supply chain solutions across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures product quality, proper packaging, and adherence to transportation regulations for safe delivery to industrial customers throughout European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.