2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole

C14H8N2S4

CAS120-78-5
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
120-78-5
EC Number
204-424-9
UN Number
3077
Index Number
613-135-00-0
PubChem CID
8447

Physical-chemical properties

Molecular Formula
C14H8N2S4
Molar Mass
332.50 g/mol
IUPAC Name
2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole

Chemical Identifiers

InChI
InChI=1S/C14H8N2S4/c1-3-7-11-9(5-1)15-13(17-11)19-20-14-16-10-6-2-4-8-12(10)18-14/h1-8H
InChI Key
AFZSMODLJJCVPP-UHFFFAOYSA-N

Overview

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole (CAS 120-78-5) is an organic disulfide compound with benzothiazole rings providing excellent accelerating properties for rubber vulcanization. This specialized chemical compound, also identified by EC number 204-424-9, belongs to the benzothiazole disulfide family and serves as a critical component in polymer chemistry applications. With its molecular formula C14H8N2S4 and molecular weight of 332.5 g/mol, this substance exhibits distinctive sulfur-bridged heterocyclic structure that makes it particularly valuable in industrial processes requiring controlled chemical reactions. The compound presents specific safety considerations that require proper handling protocols. Classified under GHS pictograms GHS07 and GHS09 with a "Warning" signal word, it demonstrates skin sensitization properties (Skin Sens. 1) and poses acute and chronic aquatic toxicity risks (Aquatic Acute 1, Aquatic Chronic 1). Transportation falls under ADR Class 9, indicating it requires special handling during shipping and storage. These safety characteristics necessitate appropriate personal protective equipment and environmental containment measures during industrial use. Primary industrial applications include rubber vulcanization acceleration, where it facilitates cross-linking reactions in tire manufacturing and rubber goods production. The compound also finds use in polymer modification processes and as an intermediate in specialty chemical synthesis. Unlike simpler compounds such as 4-cyclopropyl-6-methyl-N-phenylpyrimidin-2-amine, this benzothiazole derivative offers superior thermal stability and processing characteristics in high-temperature applications. OYSI maintains reliable supply chains for this technical grade chemical compound, supporting European manufacturers with consistent quality and regulatory compliance documentation for industrial applications.

Safety & Classification

Warning
Classification:

Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameDi(benzothiazol-2-yl)disulfid
Marine PollutantNo

Frequently Asked Questions

What is 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole is an organic chemical compound with the molecular formula C14H8N2S4 and CAS number 120-78-5. It belongs to the benzothiazole family and features a disulfide bridge connecting two benzothiazole rings. With a molecular weight of 332.5 g/mol, this sulfur-containing compound exhibits distinctive chemical properties due to its heterocyclic structure and disulfide functionality.

What are the physicochemical properties of 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole is typically a solid crystalline compound at room temperature with a yellowish appearance. The compound has a molecular weight of 332.5 g/mol and contains four sulfur atoms within its structure. Due to its aromatic benzothiazole rings and disulfide bridge, it exhibits limited water solubility but may dissolve in organic solvents. The compound's stability is influenced by its disulfide bond characteristics.

What is 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole used for?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole is primarily used as a rubber vulcanization accelerator in the tire and rubber industry. The compound facilitates cross-linking reactions during rubber processing, improving the mechanical properties and durability of rubber products. It may also serve as an intermediate in the synthesis of other benzothiazole derivatives used in various industrial applications, including as antioxidants and chemical processing agents.

How to handle 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole safely?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole requires careful handling due to its skin sensitization properties (Skin Sens. 1). Always wear protective gloves, safety goggles, and appropriate clothing to prevent skin contact. Ensure adequate ventilation in work areas and avoid generating dust. Use respiratory protection if necessary. Handle in accordance with GHS07 pictogram requirements and follow proper industrial hygiene practices to minimize exposure risks during processing and use.

How to store 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole correctly?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed to prevent moisture absorption and contamination. Store away from incompatible materials and ensure proper labeling with GHS07 and GHS09 pictograms. Maintain storage temperature within recommended ranges and implement appropriate containment measures to prevent environmental release due to its aquatic toxicity classification.

What to do in case of contact with 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole?

In case of skin contact with 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush with clean water for 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. Due to its skin sensitization properties, monitor for allergic reactions and seek medical advice if symptoms develop or persist.

How to dispose of 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole appropriately?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole must be disposed of as hazardous waste due to its aquatic toxicity classification (Aquatic Acute 1, Aquatic Chronic 1). Contact licensed waste disposal companies for proper treatment and disposal. Never discharge into sewers, waterways, or soil. Follow local and EU waste regulations, including proper waste classification codes. Ensure containers are properly labeled and transported by authorized waste carriers to approved hazardous waste treatment facilities.

How to transport 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transport purposes. Use appropriate UN-approved packaging and ensure proper labeling with Class 9 hazard labels. Transport documentation must include the correct shipping name and UN number. Vehicles must comply with ADR requirements for Class 9 substances, and drivers need appropriate training for hazardous materials transport within Europe.

Is 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole subject to specific regulations?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole is subject to EU REACH and CLP regulations due to its hazard classification. It is not currently identified as a Substance of Very High Concern (SVHC). Companies must comply with CLP labeling requirements including Warning signal word and GHS07/GHS09 pictograms. Registration obligations under REACH apply for manufacturers and importers above tonnage thresholds. Environmental discharge restrictions may apply due to its aquatic toxicity classification.

Where to buy 2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole in Europe?

2-(1,3-benzothiazol-2-yldisulfanyl)-1,3-benzothiazole is available through OYSI, a specialized European distributor of technical chemical products. OYSI provides reliable supply chains across Europe with proper regulatory compliance and technical support. As an established chemical distributor, OYSI ensures appropriate packaging, labeling, and documentation for safe transport and use. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific industrial requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.